Results 101 to 110 of about 119,652 (298)

Atomically precise metal cluster enzymes for pathological tissue regeneration

open access: yesBMEMat, EarlyView.
Schematic illustration of atomically precise metal cluster enzymes (MCEs) for pathological tissue regeneration. Atomically precise MCEs can modulate biological processes, such as attenuation of inflammatory responses, eradication of bacterial pathogens, regulation of angiogenesis, and promotion of cell development.
Ziqiang Xiong   +11 more
wiley   +1 more source

DBFOX-Ph/metal complexes: Evaluation as catalysts for enantioselective fluorination of 3-(2-arylacetyl)-2-thiazolidinones

open access: yesBeilstein Journal of Organic Chemistry, 2008
We examined the catalytic enantioselective fluorination of 3-(2-arylacetyl)-2-thiazolidinones 1 with N-fluorobenzenesulfonimide (NFSI) by DBFOX-Ph/metal complexes under a variety of conditions.
Takehisa Ishimaru   +5 more
doaj   +1 more source

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

open access: yesChemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Pd(II)‐Catalyzed Strategies for the β‐Arylation of α‐Amino Acids: An Overview

open access: yesChemistry – A European Journal, EarlyView.
The graphical abstract summarizes the review “Pd(II)‐Catalyzed Strategies for the β‐Arylation of α‐Amino Acids: An Overview”, highlighting representative Pd(II)‐catalyzed methods for the β‐arylation of α‐amino acids. Key mechanistic features, substrate diversity, and synthetic relevance of these transformations are showcased. Abstract Metal‐catalyzed C─
Davide Illuminati   +4 more
wiley   +1 more source

Urea Derivative Catalyzed Enantioselective Hydroxyalkylation of Hydroxyindoles with Isatins

open access: yesMolecules, 2019
The enantioselective transformations of indoles preferentially take place in the more-reactive azole ring. However, the methods for the enantioselective functionalization of the indole benzene ring are scarce.
Hao Wu   +3 more
doaj   +1 more source

Metal Nanoparticles on Halloysite Applied in Stereoselective Hydrogenation of Tetrasubstituted Alkenes

open access: yesChemistry – A European Journal, EarlyView.
Composite materials based on metal nanoparticles supported on a naturally occurring nanotubular clay, halloysite (HAL), led to the diastereoselective hydrogenation of tetra‐substituted alkenes under relatively smooth conditions, mainly oxazolidinone‐based heterocycles.
Rosa Pich   +9 more
wiley   +1 more source

Organocatalytic Enantioselective Friedel–Crafts Reaction of Phenanthrenequinones and Indoles

open access: yesMolecules
An efficient stereoselective synthesis of 10-hydroxy-10-(1H-indol-3-yl)-9-(10H)-phenanthrene derivatives was realized through an organocatalyzed Friedel–Crafts reaction of phenanthrenequinones and indoles using a (S,S)-dimethylaminocyclohexyl-squaramide ...
Yan Jin   +6 more
doaj   +1 more source

Better Material Properties and Faster Catalyzed Chemical Recycling for Poly(L‐Lactide) Using a Simple Commercial Glycerol Ethoxylate Additive

open access: yesChemistry – A European Journal, EarlyView.
Glycerol ethoxylate (GEO), a branched ethylene glycol derivative, both toughens commercial PLLA and accelerates its chemical recycling to L‐lactide. The lead sample, containing 10 wt.% GEO, shows 9x higher elongation at break and 6x higher tensile toughness than pure PLLA. The GEO–PLLA samples are efficiently chemically recycled to L‐lactide, even when
Madeleine L. Smith   +4 more
wiley   +1 more source

The Neglected Dimension in Pesticide Residues: Emerging Green and Enantioselective Strategies for the Analysis and Removal of Chiral Pesticides

open access: yesSeparations
Chirality remains the most neglected axis of pesticide residue science. Many active ingredients are sold as racemates although their enantiomers differ in potency, persistence, transport, and toxicology; as a result, total concentration is a poor ...
Binbin Liu, Ziyan Gong, Haixiang Gao
doaj   +1 more source

Bifunctional Photocatalysts: Exploiting Proximity for Enhanced Reaction Performance

open access: yesChemistry – A European Journal, EarlyView.
This review covers the application of the bifunctional approach to photocatalysis as a means to attain (enhanced) enantioselectivity, and, more in general, as a strategy to enhance the catalytic performance through an effective use of short‐lived reaction intermediates.
Luigi Dolcini   +3 more
wiley   +1 more source

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