Results 121 to 130 of about 2,677,083 (277)

Enantioselective Total Synthesis of (−)‐Diversonol

open access: yesChemistry – A European Journal, 2013
AbstractFor the synthesis of (−)‐diversonol (ent‐1), an enantioselective domino‐Wacker/carbonylation/methoxylation reaction and an enantioselective Wacker oxidation were used to give the chroman in high yield and 96 % and 93 % ee, respectively. Dihydroxylation at the vinyl moiety using the Sharpless procedure and a Wittig–Horner reaction followed by ...
Tietze, Lutz Friedjan   +5 more
openaire   +3 more sources

First way of enantioselective synthesis of moxifloxacin intermediate

open access: yes, 2013
A new method of enantioselective synthesis of (S,S)-2,8-diazobicyclo [4.3.0] nonane was found by using (R)-2-amino-2- phenyl-ethanol as chiral induction reagent.
Tang, Z (reprint author), Chinese Acad Sci, Chengdu Inst Biol, Nat Prod Res Ctr, Chengdu 610041, Peoples R China   +5 more
core  

Enantioselective Total Synthesis of (+)-U-106305

open access: yes, 2016
Enantioselective Total Synthesis of (+)-U ...
André B. Charette (2445061)   +1 more
core   +2 more sources

Photocatalytic Enantioselective Radical Cascade Multicomponent Minisci Reaction of β‐Carbolines Using Diazo Compounds as Radical Precursors

open access: yesAdvanced Science
Here, a photocatalytic asymmetric multicomponent cascade Minisci reaction of β‐carbolines with enamides and diazo compounds is reported, enabling an effective enantioselective radical C─H functionalization of β‐carbolines with high yields and ...
Yi‐Jie Gu   +4 more
doaj   +1 more source

Total synthesis of 4-((3S,5R)-3,5- dihydroxynonadecyl)phenol

open access: yesResults in Chemistry
This communication describes a short and effective synthetic route for the enantioselective synthesis of 4-((3S,5R)-3,5-dihydroxynonadecyl)phenol. Key steps in this synthesis include the Wittig reaction, Barbier allylation, and Sharpless dihydroxylation.
Krishnaiah Kumari   +5 more
doaj   +1 more source

Enantioselective Synthesis of Substituted Indanones from Silyloxyallenes

open access: yes, 2016
Enantioselective Synthesis of Substituted Indanones from ...
Troy E. Reynolds (2319940)   +2 more
core   +2 more sources

Nickel(II)/BINOL-catalyzed enantioselective C–H activation via desymmetrization and kinetic resolution

open access: yesNature Communications
The field of nickel catalysis has witnessed remarkable growth in recent years. However, the use of nickel catalysts in enantioselective C–H activation remains a daunting challenge because of their variable oxidation states, intricate coordination ...
Qi-Jun Yao   +3 more
doaj   +1 more source

Cation-induced enhanced enantioselective recognition by a chiral covalent-organic framework

open access: yesCommunications Chemistry
Chirality plays a pivotal role in the properties of biologically active molecules, with enantiomers exhibiting divergent pharmacological and toxicological profiles.
Zongsu Han   +3 more
doaj   +1 more source

Asymmetric synthesis of chiral heterobenzylic amines via visible-light-induced enantioselective C(sp3)-H alkylation

open access: yesGreen Synthesis and Catalysis
The chiral heterobenzylic amines, such as α-alkyl substituted chiral oxadiazole methylamine skeletons are widely present in pesticides and pharmaceuticals, due to their unique biological activities.
Yumei Huo   +5 more
doaj   +1 more source

Enantioselective Total Synthesis of Shahamin K

open access: yes, 2016
Enantioselective Total Synthesis of Shahamin
Larry E. Overman (1264596)   +2 more
core   +1 more source

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