Results 311 to 320 of about 3,273,294 (390)

Circularly Polarized Luminescence in Rotaxanes and Catenanes

open access: yesChemistryEurope, EarlyView.
This review highlights the chiral rotaxanes and catenanes possessing static or stimuli‐responsive circularly polarized luminescence (CPL) activity both in solution and in the solid state. It also discusses macromolecular and supramolecular CPL‐emissive materials derived from these mechanically interlocked molecules.
Arthur H. G. David   +2 more
wiley   +1 more source

Palladium‐Catalyzed [3+2] Cycloadditions of Alkylidenecyclopropanes to Imines: A Direct Approach to Pyrrolidine Scaffolds

open access: yesChemistryEurope, EarlyView.
Pd‐catalyzed annulations of ACPs with different C=N partners in both inter‐ and intramolecular ways are described. The methods provide access to pyrrolidines and pyrrolidine‐fused polycyclic systems, featuring β‐exo‐methylene moieties. Preliminary enantioselective variant has been shown by using a chiral phosphoramidite ligand and DFT studies shed ...
Ricardo Rodiño   +3 more
wiley   +1 more source

Mechanochemical Enantiospecific Syntheses of Sulfonimidate Esters and Sulfonimidamides by Various S(VI) Exchange Reactions

open access: yesChemistryEurope, EarlyView.
Mechanochemical S(VI) exchange reactions enable the solvent‐free, enantiospecific synthesis of sulfonimidate esters and sulfonimidamides by substituting S(VI)F or S(VI)Cl with phenols and anilines. This further opens green chemistries to the field of asymmetric synthesis.
Shashank Tripathi   +5 more
wiley   +1 more source

Enantioselective synthesis of (<i>R</i>)-citronellal from geraniol with an immobilised copper alcohol oxidase and ene reductase.

open access: yesReact Chem Eng
Tagliabue B   +7 more
europepmc   +1 more source

Alcohol and Carbonyl Redox Reactions in Electrochemical Organic Synthesis

open access: yesChemistryEurope, EarlyView.
This review aims to provide the reader with a useful tool to deal with electrochemical redox reactions involving alcohols and carbonyl compounds. The review is organized in an accessible format and divided into sections that focus on key parameters of wide‐ranging electrosynthetic methods.
Fiammetta Vitulano   +5 more
wiley   +1 more source

Enantioselective synthesis of chiral α,α-dialkyl indoles and related azoles by cobalt-catalyzed hydroalkylation and regioselectivity switch. [PDF]

open access: yesNat Commun
Ren J   +11 more
europepmc   +1 more source

Fluorescent Probe for δ‐Cyclodextrin Enables Guest Encapsulation Studies via an Indicator Displacement Assay

open access: yesChemistryEurope, EarlyView.
A molecular probe that partially unfolds and exhibits fluorescence enhancement upon binding to δ‐cyclodextrin (δ‐CD) is presented. Its implementation in a fluorescence indicator displacement assay to test the binding of various guest to δ‐CD is demonstrated.
Mads G. Rasmussen   +7 more
wiley   +1 more source

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