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Catalytic Enantioselective Synthesis of Helicenes.

Chemistry, 2022
Helicenes and helicene-like molecules, usually containing multiple ortho -fused aromatic rings, possess unique helical chirality. These compounds have found a wide range of important applications in many research fields, such as asymmetric catalysis ...
W. Liu   +3 more
semanticscholar   +1 more source

Enantioselective Synthesis of Nitrogen-Nitrogen Biaryl Atropisomers via Copper-Catalyzed Friedel-Crafts Alkylation Reaction.

Journal of the American Chemical Society, 2021
Nitrogen-nitrogen bonds containing motifs are ubiquitous in natural products and bioactive compounds. However, the atropisomerism arising from a restricted rotation around an N-N bond is largely overlooked.
Xiao‐Mei Wang   +6 more
semanticscholar   +1 more source

Enantioselective Synthesis of Atropisomeric Biaryls by Pd-Catalyzed Asymmetric Buchwald-Hartwig Amination.

Angewandte Chemie, 2021
N-C Biaryl atropisomers are important because of their prevalence in natural products and bioactive drug molecules. However, the enantioselective synthesis of such molecules has not developed significantly. Particularly, the enantioselective synthesis of
Peng Zhang   +6 more
semanticscholar   +1 more source

Recent advances in organocatalytic asymmetric multicomponent cascade reactions for enantioselective synthesis of spirooxindoles

Organic Chemistry Frontiers, 2021
Catalytic asymmetric MCCRs for enantioselective synthesis of spirooxindoles by using chiral phosphoric acids, amines, bifunctional thiourea/squaramides and metal-based reagents as catalysts.
Yongchao Wang, Angel A. Cobo, A. Franz
semanticscholar   +1 more source

Enantioselective Synthesis of Euonyminol

Journal of the American Chemical Society, 2021
We describe an enantioselective total synthesis of the nonahydroxylated sesquiterpenoid euonyminol, the dihydro-β-agarofuran nucleus of the macrocyclic terpenoid alkaloids known as the cathedulins. Key features of the synthetic sequence include a highly diastereoselective intramolecular alkene oxyalkylation to establish the C10 quaternary center, an ...
Martin Tomanik, Zhi Xu, Seth B. Herzon
openaire   +3 more sources

Synthesis of Chiral Au Nanocrystals with Precise Homochiral Facets for Enantioselective Surface Chemistry.

Nano letters (Print), 2022
Metal surfaces with intrinsic chirality play an irreplaceable role in many significant enantioselective chemical processes such as enantioselective catalysis, sensing, and separation.
Fengxia Wu   +6 more
semanticscholar   +1 more source

Catalytic Enantioselective Synthesis of Axially Chiral Polycyclic Aromatic Hydrocarbons (PAHs) via Regioselective C-C Bond Activation of Biphenylenes.

Journal of the American Chemical Society, 2020
Chiral polycyclic aromatic hydrocarbons (PAHs) are expected to have unusual physical properties due to their chirality and extremely expanded π-conjugated system.
Hideaki Takano   +4 more
semanticscholar   +1 more source

Enantioselective Synthesis of and with Allenes.

ChemInform, 2002
AbstractFor Abstract see ChemInform Abstract in Full Text.
Norbert Krause, Anja Hoffmann‐Roeder
openaire   +4 more sources

Enantioselective synthesis of aminobenzazepinones [PDF]

open access: possibleTetrahedron Letters, 2007
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Stephen E. Mercer   +3 more
openaire   +2 more sources

Quinim: a New Ligand Scaffold Enabled Nickel-Catalyzed Enantioselective Synthesis of α-Alkylated γ-Lactam.

Journal of the American Chemical Society, 2020
Herein, we report a nickel-catalyzed reductive cross-coupling reaction of easily accessible 3-butenyl carbamoyl chloride with primary alkyl iodide to access the chiral α-alkylated pyrrolidinone with broad substrate scope and high ee.
Xianqing Wu, Jingping Qu, Yifeng Chen
semanticscholar   +1 more source

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