Results 21 to 30 of about 32,089 (279)

The Enantioselective Tsuji Allylation [PDF]

open access: yesJournal of the American Chemical Society, 2004
The first catalytic enantioselective examples of the Tsuji allylation using enol carbonates and enol silanes are described. The products possess a quaternary stereogenic center and are useful building blocks for synthetic chemistry.
Behenna, Douglas C., Stoltz, Brian M.
openaire   +3 more sources

Solvent Induced Enantioselectivity Reversal in a Chiral Metal Organic Framework [PDF]

open access: yes, 2020
Solvent induced enantioselectivity reversal is a rarely reported phenomenon in porous homochiral materials. Similar behaviour has been studied in chiral HPLC, where minor mobile phase modifications can induce elution order reversal.
Benjamin, Slater   +2 more
core   +2 more sources

Enantioselective Synthesis of N1999A2. [PDF]

open access: yesChemInform, 2006
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Nan, Ji   +3 more
openaire   +3 more sources

Understanding Nonlinear Composition Dependency of Enantioselectivity in Chiral Separation Using Mixed Micelle [PDF]

open access: yes, 2022
Hypothesis: Mixtures of chiral and achiral building blocks of supramolecules exhibit interesting cooperative phenomena, indicat-ed by the nonlinear composition dependence of the chiral properties.
Nozomu, Suzuki, Nozomu Suzuki
core   +2 more sources

Regular Solution Theory for Nonlinear Composition Dependency of Enantioselectivity by Mixed Micelle [PDF]

open access: yes, 2022
Mixtures of chiral and achiral building blocks of supramolecules exhibit interesting cooperative properties, as indicated by the nonlinear relationship between chiral properties and the mole fraction of chiral building blocks.
Nozomu, Suzuki
core   +2 more sources

Enantioselective Synthesis of (+)‐Majusculone (I). [PDF]

open access: yesChemInform, 2007
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Douglass F, Taber   +2 more
openaire   +2 more sources

Origin of Enantioselectivity Reversal in Lewis Acid-Catalysed Michael Additions Relying on the Same Chiral Source [PDF]

open access: yes, 2021
Enantiodivergence is an important concept in asymmetric catalysis that enables access to both enantiomers of a product relying on the same chiral source as reagent.
Alistair D., Richardson   +4 more
core   +1 more source

Enantioselective Synthesis of 2,2-Disubstituted Terminal Epoxides via Catalytic Asymmetric Corey-Chaykovsky Epoxidation of Ketones

open access: yesMolecules, 2012
Catalytic asymmetric Corey-Chaykovsky epoxidation of various ketones with dimethyloxosulfonium methylide using a heterobimetallic La-Li3-BINOL complex (LLB) is described.
Shigeki Matsunaga   +3 more
doaj   +1 more source

NiH-Catalyzed Enantio- and Regioselective Hydroselenylation of Unactivated Alkenes. [PDF]

open access: yesAdv Sci (Weinh)
Nickel‐hydride‐catalyzed enantio‐ and regioselective hydroselenylation of unactivated alkenes provides access to chiral organoselenium compounds. Enantiodetermining Ni–H insertion followed by single‐electron diselenide activation generates selenyl radical.
Kang HJ, Kim J, Hong S.
europepmc   +2 more sources

From Mechanistic Study to Chiral Catalyst Optimization: Theoretical Insight into Binaphthophosphepine-catalyzed Asymmetric Intramolecular [3 + 2] Cycloaddition

open access: yesScientific Reports, 2017
Density functional M11 was used to study the mechanism and enantioselectivity of a binaphthophosphepine-catalyzed intramolecular [3 + 2] cycloaddition reaction.
Meng Duan   +6 more
doaj   +1 more source

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