Results 21 to 30 of about 42,802 (288)

Kinetic resolution of racemates under chiral catalysis: connecting the dots [PDF]

open access: yes, 2012
The current theory of the titled phenomenon is apparently based on an inconsistent use of concentration units, as employed in the derivation of the fundamental equations. Thus, manifestly, whilst the relation between extent of conversion and e.e.
Sosale Chandrasekhar
core   +2 more sources

Catalytic Enantioselective Decarboxylative Protonation. [PDF]

open access: yesChemInform, 2006
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Mohr, Justin T.   +3 more
openaire   +4 more sources

Metal-mediated intramolecular hydroamination and hydro(acy)alkoxylation reactions [PDF]

open access: yes, 2012
This PhD thesis describes work undertaken to effect asymmetric catalysis in hydroamination and hydro(acy)alkoxylation reactions of allenes. The introductory Chapter provides an overview of recent advances in asymmetric heterofunctionalisation reactions ...
Arbour, Jannine Louise   +1 more
core   +1 more source

Enantioselective Synthesis of N1999A2. [PDF]

open access: yesChemInform, 2006
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Nan, Ji   +3 more
openaire   +3 more sources

From Mechanistic Study to Chiral Catalyst Optimization: Theoretical Insight into Binaphthophosphepine-catalyzed Asymmetric Intramolecular [3 + 2] Cycloaddition

open access: yesScientific Reports, 2017
Density functional M11 was used to study the mechanism and enantioselectivity of a binaphthophosphepine-catalyzed intramolecular [3 + 2] cycloaddition reaction.
Meng Duan   +6 more
doaj   +1 more source

Directed enzyme evolution: climbing fitness peaks one amino acid at a time [PDF]

open access: yes, 2009
Directed evolution can generate a remarkable range of new enzyme properties. Alternate substrate specificities and reaction selectivities are readily accessible in enzymes from families that are naturally functionally diverse.
Arnold, Frances H., Tracewell, Cara A.
core   +2 more sources

The Enantioselective Tsuji Allylation [PDF]

open access: yesJournal of the American Chemical Society, 2004
The first catalytic enantioselective examples of the Tsuji allylation using enol carbonates and enol silanes are described. The products possess a quaternary stereogenic center and are useful building blocks for synthetic chemistry.
Behenna, Douglas C., Stoltz, Brian M.
openaire   +3 more sources

Homochiral Metal-Organic Framework Based Mixed Matrix Membrane for Chiral Resolution

open access: yesMembranes, 2022
Efficient separation of enantiomers is critical in the chemical, pharmaceutical, and food industries. However, conventional separation methods, such as chromatography, crystallization, and enzymatic kinetic resolution, require high energy costs and ...
Hwa-Jin Choi, Dong-Yeun Koh
doaj   +1 more source

Organocatalytic synthesis of axially chiral atropisomers [PDF]

open access: yes, 2017
This review summarises the recent progress made in the organocatalytic synthesis of atropisomeric compounds. Methodologies based on dynamic kinetic resolution and direct access to BINOL-like biaryls are described.
Renzi, P.
core   +1 more source

Enantioselective Organocatalytic Allylic Amination [PDF]

open access: yesJournal of the American Chemical Society, 2005
AbstractFor Abstract see ChemInform Abstract in Full Text.
Poulsen, Thomas B.   +2 more
openaire   +3 more sources

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