Results 11 to 20 of about 7,061 (174)
Type II halogen···halogen contacts are halogen bonds [PDF]
IUCrJ, 2013 Cl/Br/I alternative substitutions in a series of dihalophenols indicate that type I and type II halogen···halogen contacts have different chemical nature. Only the latter ones qualify as true halogen bonds, according to the recent IUPAC definition.
METRANGOLO, PIERANGELO +1 more
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Mechanochemical halogenation of unsymmetrically substituted azobenzenes
Beilstein Journal of Organic Chemistry, 2022 The direct and selective mechanochemical halogenation of C–H bonds in unsymmetrically substituted azobenzenes using N-halosuccinimides as the halogen source under neat grinding or liquid-assisted grinding conditions in a ball mill has been described ...
Dajana Barišić +4 more
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Nature Communications, 2021 Organohalides are widely used as synthetic precursors and target products, but for various halogenation reactions there is a need for effective catalysts to activate commercially available haleniums.
Weijin Wang +6 more
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Visible-Light-Induced Catalytic Selective Halogenation with Photocatalyst
Molecules, 2021 Halide moieties are essential structures of compounds in organic chemistry due to their popularity and wide applications in many fields such as natural compounds, agrochemicals, and pharmaceuticals.
Truong Giang Luu +2 more
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Molecules, 2022 Prodigiosins (prodiginines) are a class of bacterial secondary metabolites with remarkable biological activities and color. In this study, optimized production, purification, and characterization of prodigiosin (PG) from easily accessible Serratia ...
Jelena Lazic +8 more
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Probing halogen–halogen interactions in solution [PDF]
Physical Chemistry Chemical Physics, 2017 Weak but measurable: a supramolecular balance detects interactions between CBr3groups in solution and estimates the corresponding free energy (0.2 kJ mol−1).
Ayzac, V. +9 more
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Technical Note: Reactivity of C1 and C2 organohalogens formation – from plant litter to bacteria [PDF]
Biogeosciences, 2012 C1/C2 organohalogens (organohalogens with one or two carbon atoms) can have significant environmental toxicity and ecological impact, such as carcinogenesis, ozone depletion and global warming.
J. J. Wang +6 more
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Intramolecular halogen–halogen bonds?
Physical Chemistry Chemical Physics, 2013 By analysing the properties of the electron density in the structurally simple perhalogenated ethanes, X3C-CY3 (X, Y = F, Cl), a previously overlooked non-covalent attraction between halogens attached to opposite carbon atoms is found. Quantum chemical calculations extrapolated towards the full solution of the Schrödinger equation reveal the complex ...
Johansson, Mikael P., Swart, Marcel
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Halogenation as a Strategy to Improve Antiplasmodial Activity: A Report of New 3-Alkylpyridine Marine Alkaloid Analogs [PDF]
International Journal of Travel Medicine and Global Health, 2019 Introduction: Due to the emergence of resistance to antimalarial drugs as well as the lack of vaccination for malaria, there is an urgent demand for the development of new antimalarial alternatives.
Camila Barbosa +6 more
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Synthesis and Reactions of 3-Halogenated 2-CF3-Indoles
Molecules, 2022 Halogenation of 2-trifluoromethylindole afforded 3-chloro-, 3-bromo- and 3-iodo derivatives in up to 98% yield. Methyl-, benzyl- and tosyl-groups can be installed at the nitrogen atom of prepared indoles in high yields by base catalyzed reaction with the
Vasiliy M. Muzalevskiy +2 more
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