Results 161 to 170 of about 148,467 (378)

Design and Utilization of Stable Hydrofluoroolefin‐Based Trifluoropropynyl Surrogate for Sonogashira Coupling

Advanced Synthesis &Catalysis, EarlyView.
A novel methodology for the construction of aromatic and heteroaromatic trifluoropropynyl derivatives has been developed. The new protocol is based on a tandem Sonogashira cross‐coupling reaction between a bench‐stable trifluoropropynyl carbinol reagent, generated from the commercially available and inexpensive hydrofluoroolefin‐1234yf gas, and (hetero)
Emma Bodnár, Ferenc Béke, Klára Aradi, Zoltán Novák   +3 more
wiley   +1 more source

Realizing Two-Dimensional Spin Arrays on Surfaces via Halogen-Bonding Molecular Self-Assembly

, 2021
Dingguan Wang, Zishen Wang, Shaofei Wu, Arramel Arramel, Xinmao Yin, Chi Sin Tang, YUANPING FENG, Jishan Wu, Andrew T. S. Wee   +8 more
openalex   +1 more source

Exploring the Uncharted Indolizine Chemical Space: Construction of 5‐Acylindolizines via a Domino Aldol–Vinylogous Aldol Process

Advanced Synthesis &Catalysis, EarlyView.
A domino aldol condensation–intramolecular vinylogous aldol condensation process was implemented for the first time to enable access to a wide range of novel 5‐acylated indolizines with a hydrogen, an alkyl, an aryl, or an alkoxy moiety at the C7 site.
Dohui Ku, Sunhee Lee, Ikyon Kim
wiley   +1 more source

Nb2CBr2 MXene Monolayer as a Novel Material: A First Principle Study

Advanced Theory and Simulations, EarlyView.
Illustration of the monolayer cell, cell replicated in directions a and b, graph of optical absorption and thermodynamic potentials as a function of temperature. Abstract Niobium‐based MXenes show promising properties and applications, but have not yet been sufficiently investigated, especially with halogen surface terminations. This study investigates
Leonardo S. Barbosa, Willian O. Santos, Felix S. Costa, Edvan Moreira, David L. Azevedo   +4 more
wiley   +1 more source

Protein Language Model‐Guided Engineering of a 2,3‐Butanediol Dehydrogenase for the Enantioselective Synthesis of Cyclic α‐Hydroxy Ketones

Advanced Science, EarlyView.
A (2R,3R)‐butanediol dehydrogenase from Bacillus subtilis (BsBDH) is engineered for the enantioselective synthesis of 2‐hydroxycyclohexanone. A PASS computational design strategy is proposed to enhance the thermostability of BsBDH. Moreover, ESM‐1v combined with ISM is utilized for enhancing and inverting its stereoselectivity.
Haote Ding, Ling Jiang, Yijia Song, Zhongji Pu, Lirong Yang, Haoran Yu   +5 more
wiley   +1 more source

XIX.—Nitrogen halogen derivatives of the sulphonamides

, 1905
Frederick Daniel Chattaway
openalex   +2 more sources

Cinnamic‐Hydroxamic‐Acid Derivatives Exhibit Antibiotic, Anti‐Biofilm, and Supercoiling Relaxation Properties by Targeting Bacterial Nucleoid‐Associated Protein HU

Advanced Science, EarlyView.
Cinnamic‐hydroxamic‐acid derivatives (CHADs) are identified as novel inhibitors of the bacterial nucleoid‐associated protein HU, exhibiting potent antibacterial, anti‐biofilm (both inhibition and eradication), and DNA relaxation (anti‐supercoiling) activities. Moreover, CHADs demonstrate strong synergistic effects with multiple antibiotics.
Huan Chen, Yingqi Xu, Zhaoping Xiong, Hongliang Wang, Xin Wang, Yue Kang, Zhonglin Wang, Xiaoyan Zeng, Yahui Liu, Yehuan Zheng, Wei Chen, Mengzhe Li, Zhenyue Hu, Chi Xu, Yue Wu, Yawen Wang, Zuyi Yuan, Shuai Yuan, Huadong Liu, Steve Matthews, Nan Qiao, Yan Li, Bing Liu   +22 more
wiley   +1 more source

Klinischer Langzeiterfolg der Nanohybridkomposite Grandio® und Filtek™ Supremé in Klasse I und II Kavitäten in Abhängigkeit von dem verwendeten Lichthärtegerät (Halogen oder LED) [PDF]

, 2017
Torsten Pflaum
openalex  

Enhancing Cycling Stability of Aqueous Aluminum‐Metal Batteries via LaCl3‐Modulated Interfacial Reactions

Advanced Science, EarlyView.
In the aqueous AlCl3 electrolyte of aluminum‐metal batteries, the introduction of LaCl3 adjusts the solvation structure of Al3+ and enhances its diffusion level. The oxide precipitate formed by La3+ covers the aluminum metal anode and effectively alleviates corrosion reactions, thereby improving the cycling stability of the battery.
Yanshen Gao, Karol Załęski, Emerson Coy, Błażej Scheibe, Kacper Szymański, Qingshan Yang, Ewa Mijowska, Xianjie Liu, Ran Jia, Dariusz Moszyński, Linfeng Hu, Rudolf Holze, Xuecheng Chen   +12 more
wiley   +1 more source

Assessment of the atmospheric impact of volcanic eruptions [PDF]

The dominant global impact of volcanic activity is likely to be related to the effects of volcanic gases on the Earth's atmosphere. Volcanic gas emissions from individual volcanic arc eruptions are likely to cause increases in the stratospheric optical ...
Sigurdsson, H.
core   +1 more source