Results 51 to 60 of about 70,860 (329)

Electrocatalytic Reduction of CO2 to Ethylene: Catalyst Design and Synchrotron‐Based Characterizations

Advanced Functional Materials, EarlyView.
This review evaluates strategies for electrochemical CO2 reduction to ethylene, focusing on copper‐based catalyst design and microenvironment modulation to achieve industrial‐grade performance. By leveraging operando synchrotron‐based characterizations, we provide a multiscale understanding of dynamic structural transformations and key reaction ...
Meng Zhang, Zuolong Chen, Yimin A. Wu
wiley   +1 more source

Syntheses and medicinal chemistry of spiro heterocyclic steroids

Beilstein Journal of Organic Chemistry
There is compelling evidence that incorporating a heterocyclic moiety into a steroid can alter its pharmacological and pharmacokinetic properties, driving intense interest in the synthesis of such hybrids among research groups. In this review, we present
Laura L. Romero-Hernández, Ana Isabel Ahuja-Casarín, Penélope Merino-Montiel, Sara Montiel-Smith, José Luis Vega-Báez, Jesús Sandoval-Ramírez   +5 more
doaj   +1 more source

Discovery of 4,5-Dihydro-1H-thieno[2′,3′:2,3]thiepino [4,5-c]pyrazole-3-carboxamide Derivatives as the Potential Epidermal Growth Factor Receptors for Tyrosine Kinase Inhibitors

Molecules, 2018
The epidermal growth factor receptors (EGFRs), in which overexpression (known as upregulation) or overactivity have been associated with a number of cancers, has become an attractive molecular target for the treatment of selective cancers. We report here
Jia Ke, Qi Lu, Xin Wang, Rui Sun, Zhe Jin, Xiaoyi Zhan, Jianshu Hu, David Chi-cheong Wan, Chun Hu   +8 more
doaj   +1 more source

Heterocyclic Electrochemistry: Renewable Electricity in the Construction of Heterocycles

ACS Omega, 2023
Numerous applications in the realm of biological exploration and drug synthesis can be found in heterocyclic chemistry, which is a vast subject. Many efforts have been developed to further improve the reaction conditions to access this interesting family to prevent employing hazardous ingredients.
Samina Aslam, Najoua Sbei, Sadia Rani, Manal Saad, Aroog Fatima, Nisar Ahmed   +5 more
openaire   +4 more sources

Heptazine‐Assisted Multi‐Resonance TADF Emitters With Fast Reverse Intersystem Crossing for Efficient Solution‐Processed OLEDs

Advanced Materials, EarlyView.
Heptazine‐assisted MR‐TADF emitters enable narrowband yellow emission with high efficiency at high luminance in solution‐processed OLEDs. In doped films, HAP‐3CzBN achieves a record‐fast kRISC of 1.19 × 106 s−1. The optimized HAP‐3CzBN devices deliver 15.5% EQEmax with negligible roll‐off at 1000 cd m−2, 11.2% at 10,000 cd m−2, and a benchmark 20.3 ...
Changfeng Si, Katrina Bergmann, Kunping Guo, Gert‐Jan A. H. Wetzelaer, Paul W. M. Blom, Zachary M. Hudson   +5 more
wiley   +1 more source

Convenient Synthesis of Thiohydantoins, Imidazole-2-thiones and Imidazo[2,1-b]thiazol-4-iums from Polymer-Supported α-Acylamino Ketones

Molecules, 2018
The preparation of 5-methylene-thiohydantoins using solid-phase synthesis is reported in this paper. After sulfonylation of immobilized Ser (t-Bu)-OH with 4-nitrobenzenesulfonyl chloride followed by alkylation with various bromoketones, the 4-Nos group ...
Petra Králová, Michal Maloň, Hiroyuki Koshino, Miroslav Soural   +3 more
doaj   +1 more source

Heterocycle-based bifunctional organocatalysts in asymmetric synthesis [PDF]

, 2016
Different chiral bifunctional organocatalysts derived from trans-cyclohexane-1,2-diamine bearing different types of guanidine units able to form-hydrogen bonding activation have been designed. Conformational rigid 2-aminobenzimidazoles bearing a tertiary
Gómez Bengoa, Enrique, Nájera, Carmen, Sansano, Jose M.   +2 more
core   +2 more sources

N‐heterocyclic Carbenes as Adhesion Promoters on Aluminum Alloy 6061

Advanced Materials Interfaces, EarlyView.
N‐heterocyclic carbenes as novel non‐toxic surface primers for aluminum alloys for better adhesive bonding, because strong adhesive bonding shouldn't come at the cost of poisoning the human body. The impact of NHC functionalization on adhesive joint strength and durability is also evaluated using a single‐lap‐shear test, following continuous exposure ...
Jashanpreet Kaur, Vikram Singh, Alban Morel, Amélie Ruest, Mark D. Aloisio, Cathleen M. Crudden, Janine Mauzeroll   +6 more
wiley   +1 more source

Toward Charge-neutral ‘soft scorpionates’: Coordination Chemistry and Lewis Acid Promoted Isomerization of tris(1-organo-imidazol-2-ylthio)methanes [PDF]

, 2009
Two tris(1-organo-imidazol-2-ylthio)methanes, HC(S-timR)3 (R = organo = methyl, tert-butyl), have been prepared by a triphasic reaction between chloroform, the appropriate heterocycle, and saturated aqueous solutions of Na2CO3, in the presence of a phase
Gardinier, James R., Gwengo, Chengeto, Lindeman, Sergey V., Silva, Rosalice M., Smith, Mark D.   +4 more
core   +1 more source

Light Switchable Ionic Conductivity of Arylazopyrazole Modified Polysiloxanes

Advanced Materials Technologies, EarlyView.
We present a polysiloxane functionalized with a novel arylazopyrazole dye that undergoes reversible photoisomerization. Upon lithium bis(trifluoromethanesulfonyl)imide addition and UV irradiation, the polymer exhibits a shift in tan(d) toward higher frequencies and enhanced ionic conductivity.
Malte S. Beccard, Thulasinath Raman Venkatesan, Michael Bauer, Valentin Razvan Lupu, Philipp Scheidegger, Francesco Taddei, Frank A. Nüesch, Dorina M. Opris   +7 more
wiley   +1 more source