Molecular Split-Ring Resonators Based on Metal String Complexes [PDF]
Metal string complexes or extended metal atom chains (EMACs) belong to a family of molecules that consist of a linear chain of directly bonded metal atoms embraced helically by four multidentate organic ligands. These four organic ligands are usually made up of repeating pyridyl units, single-nitrogen-substituted heterocyclic annulenes, bridged by ...
arxiv +1 more source
Electric deflection of imidazole dimers and trimers in helium nanodroplets: Dipole moments, structure, and fragmentation [PDF]
Deuterated imidazole (IM) molecules, dimers and trimers formed in liquid helium nanodroplets are studied by the electrostatic beam deflection method. Monitoring the deflection profile of (IM)D+ provides a direct way to establish that it is the primary product of the ionization-induced fragmentation both of (IM)2 and (IM)3.
arxiv +1 more source
Small N-heterocyclic molecules are important scaffolds in the pharmaceutical industry and most FDA-approved drugs are nitrogen-containing heterocycles.
Maria Sohail+8 more
doaj
Nitrogen heterocycles as potential monoamine oxidase inhibitors: Synthetic aspects
The present review highlights the synthetic methods of monoamine oxidase inhibitors (MAO) belonging to a group of nitrogen heterocycles such as pyrazoline, indole, xanthine, oxadiazole, benzimidazole, pyrrole, quinoxaline, thiazole and other related ...
Pravin O. Patil, Sanjay B. Bari
doaj +1 more source
A Brief Review on the Synthesis of the N-CF3 Motif in Heterocycles
The trifluoromethyl group is widely recognized for its significant role in the fields of medicinal chemistry and material science due to its unique electronic and steric properties that can alter various physiochemical properties of the parent molecule ...
Zizhen Lei+4 more
doaj +1 more source
Revisiting the structure and chemistry of 3(5)-Substituted Pyrazoles [PDF]
Pyrazoles are known as versatile scaffolds in organic synthesis and medicinal chemistry, often used as starting materials for the preparation of more complex heterocyclic systems with relevance in the pharmaceutical field.
Alam+34 more
core +2 more sources
Quantum Rate Electrodynamics and Resonant Junction Electronics of Heterocyclic Molecules [PDF]
Quantum rate theory encompasses the electron-transfer rate constant concept of electrochemical reactions as a particular setting, besides demonstrating that the electrodynamics of these reactions obey relativistic quantum mechanical rules. The theory predicts a frequency $\nu = E/h$ for electron-transfer reactions, in which $E = e^2/C_q$ is the energy ...
arxiv
N-tert-Butanesulfinyl imines in the asymmetric synthesis of nitrogen-containing heterocycles
The synthesis of nitrogen-containing heterocycles, including natural alkaloids and other compounds presenting different types of biological activities have proved to be successful employing chiral sulfinyl imines derived from tert-butanesulfinamide ...
Joseane A. Mendes+4 more
doaj +1 more source
ChemInform Abstract: Dibenzonaphthyridinones: Heterocycle‐to‐Heterocycle Synthetic Strategies and Photophysical Studies. [PDF]
AbstractThe two‐step preparation of dibenzonaphthyridinones via 3,5‐bis(2‐nitrophenyl)‐1,2‐oxazoles is described.
Palazzo, Teresa A+7 more
openaire +6 more sources
Synthesis of Medium-Sized Heterocycles by Transition-Metal-Catalyzed Intramolecular Cyclization
Medium-sized heterocycles (with 8 to 11 atoms) constitute important structural components of several biologically active natural compounds and represent promising scaffolds in medicinal chemistry.
Mickael Choury+3 more
semanticscholar +1 more source