Results 61 to 70 of about 128,452 (331)

Fused 1,5-Naphthyridines: Synthetic Tools and Applications

Molecules, 2020
Heterocyclic nitrogen compounds, including fused 1,5-naphthyridines, have versatile applications in the fields of synthetic organic chemistry and play an important role in the field of medicinal chemistry, as many of them have a wide range of biological ...
Carme Masdeu, Maria Fuertes, Endika Martin-Encinas, Asier Selas, Gloria Rubiales, Francisco Palacios, Concepcion Alonso   +6 more
doaj   +1 more source

Copper catalyzed late-stage C(sp3)-H functionalization of nitrogen heterocycles

Nature Communications, 2021
Late-stage C(sp3)-H bond functionalization of N-heterocycles with broad substrate scope remains a challenge and of particular significance to modern chemical synthesis and pharmaceutical chemistry. Here the authors show copper-catalysed late-stage C(sp3)-
Zhe Chang, Jialin Huang, Si Wang, Geshuyi Chen, Heng Zhao, Rui Wang, Depeng Zhao   +6 more
doaj   +1 more source

NH3‐Guided Low‐Temperature Nanostructural Refinement Boosts Visible‐Light‐Driven H2O2 Synthesis in Ionic Carbon Nitrides

Advanced Materials, EarlyView.
A nanostructural refinement strategy is reported for KPHI photocatalysts using NH4Cl in a molten salt environment to induce coherent domain fragmentation and controlled cyano defect formation. This dual modification promotes n→π* transitions, enhances charge separation, and accelerates ORR kinetics, yielding exceptional AQY values of 49% (410 nm) and 5%
Jaya Bharti, Jokotadeola Odutola, Zahra Hajiahmadi, Karlo Nolkemper, Zhihong Tian, Haijian Tong, Vitaliy Shvalagin, Thomas D. Kühne, Tero‐Petri Ruoko, Christian Mark Pelicano   +9 more
wiley   +1 more source

Heptazine‐Assisted Multi‐Resonance TADF Emitters With Fast Reverse Intersystem Crossing for Efficient Solution‐Processed OLEDs

Advanced Materials, EarlyView.
Heptazine‐assisted MR‐TADF emitters enable narrowband yellow emission with high efficiency at high luminance in solution‐processed OLEDs. In doped films, HAP‐3CzBN achieves a record‐fast kRISC of 1.19 × 106 s−1. The optimized HAP‐3CzBN devices deliver 15.5% EQEmax with negligible roll‐off at 1000 cd m−2, 11.2% at 10,000 cd m−2, and a benchmark 20.3 ...
Changfeng Si, Katrina Bergmann, Kunping Guo, Gert‐Jan A. H. Wetzelaer, Paul W. M. Blom, Zachary M. Hudson   +5 more
wiley   +1 more source

Vinylogous aldol reaction of heterocyclic silyloxy dienes. Application in synthesis [PDF]

, 2000
A versatile, readily accessible triad of 2-enoxy silane synthons derived from furan, pyrrole, and thiophene is presented. These heterocycles, in reacting with carbonyl and carbonyl- related acceptors, act as vinylogous nucleophile modules, giving rise ...
Casiraghi, Giovanni, Rassu, Gloria Maria Rita, Zanardi, Franca   +2 more
core  

N‐heterocyclic Carbenes as Adhesion Promoters on Aluminum Alloy 6061

Advanced Materials Interfaces, EarlyView.
N‐heterocyclic carbenes as novel non‐toxic surface primers for aluminum alloys for better adhesive bonding, because strong adhesive bonding shouldn't come at the cost of poisoning the human body. The impact of NHC functionalization on adhesive joint strength and durability is also evaluated using a single‐lap‐shear test, following continuous exposure ...
Jashanpreet Kaur, Vikram Singh, Alban Morel, Amélie Ruest, Mark D. Aloisio, Cathleen M. Crudden, Janine Mauzeroll   +6 more
wiley   +1 more source

Stereoselectively fluorinated N-heterocycles: a brief survey

Beilstein Journal of Organic Chemistry, 2013
The stereoselective incorporation of fluorine atoms into N-heterocycles can lead to dramatic changes in the molecules’ physical and chemical properties.
Xiang-Guo Hu, Luke Hunter
doaj   +1 more source

Photothermal Conversion Promotes Challenging S_NAr for Facile C─N Bond Formation. [PDF]

Angew Chem Int Ed Engl
Photothermal conversion enables facile aromatic C─N bond formation via red light irradiation. A variety of inter‐ and intramolecular SNAr transformations are achieved under mild, schematically simple conditions. Additionally, a thermally promoted halogen exchange mechanism provides access to aryl bromides, chlorides, and fluorides – making this ...
Matter ME, Devin RC, Stache EE.
europepmc   +2 more sources

Transfer of electrophilic NH using convenient sources of ammonia: direct synthesis of N–H sulfoximines from sulfoxides [PDF]

, 2016
The transfer of nitrogen atoms is extremely valuable in the preparation of medicinal compounds. Here, a new system for NH transfer is developed to prepare sulfoximines, which are emerging as valuable motifs for drug discovery.
Bentley, Bizet, Bizet, Buglioni, Carroccia, Cheng, Collins, Collins, Collins, Dauban, Degennaro, Dohi, Dong, Fiori, Goldberg, Gutmann, Iacobucci, Ivanov, Jat, Johnson, Langner, Lücking, Lücking, Mancheño, Mendiola, Miao, Miyasaka, Ochiai, Okamura, Rit, Roizen, Romero, Shen, Silva, Souto, Starkov, Tamura, Teng, Wang, Weber, Williamson, Zenzola, Zhu, Zou   +43 more
core   +1 more source

Light Switchable Ionic Conductivity of Arylazopyrazole Modified Polysiloxanes

Advanced Materials Technologies, EarlyView.
We present a polysiloxane functionalized with a novel arylazopyrazole dye that undergoes reversible photoisomerization. Upon lithium bis(trifluoromethanesulfonyl)imide addition and UV irradiation, the polymer exhibits a shift in tan(d) toward higher frequencies and enhanced ionic conductivity.
Malte S. Beccard, Thulasinath Raman Venkatesan, Michael Bauer, Valentin Razvan Lupu, Philipp Scheidegger, Francesco Taddei, Frank A. Nüesch, Dorina M. Opris   +7 more
wiley   +1 more source