Results 1 to 10 of about 111,305 (353)
Journal of the American Chemical Society, 2017 The ability of an FeIV═O intermediate in SyrB2 to perform chlorination versus hydroxylation was computationally evaluated for different substrates that had been studied experimentally.
Martin Srnec, Edward I Solomon
exaly +2 more sources
Horticulture Research, 2022 Flavonoids are the most widespread polyphenolic compounds and are important dietary constituents present in horticultural crops such as fruits, vegetables, and tea.
Yilong Liu +8 more
semanticscholar +1 more source
A tautomeric ligand enables directed C‒H hydroxylation with molecular oxygen
Science, 2021 Easing oxygen into arenes Although oxygen is all around us, it is often surprisingly difficult to use it for selective chemical oxidations, necessitating more expensive, wasteful alternatives. Li et al.
Zhen Li +8 more
semanticscholar +1 more source
Decarboxylative Hydroxylation of Benzoic Acids
Angewandte Chemie, 2021 Herein, we report the first decarboxylative hydroxylation to synthesize phenols from benzoic acids at 35 °C via photoinduced ligand‐to‐metal charge transfer (LMCT)‐enabled radical decarboxylative carbometalation.
Wanqi Su, P. Xu, T. Ritter
semanticscholar +1 more source
Frontiers in Catalysis, 2022 The use of water-miscible organic co-solvents in biocatalysis is a simple procedure for obtaining higher enzymatic activities toward hydrophobic substrates.
Thomas Hilberath +3 more
doaj +1 more source
Nature Communications, 2020 mTORC1 is an important regulator of muscle mass but how it is modulated by oxygen and nutrients is not completely understood. We show that loss of the prolyl hydroxylase domain isoform 1 oxygen sensor in mice (PHD1KO) reduces muscle mass.
G. D’Hulst +13 more
semanticscholar +1 more source
Frontiers in Chemistry, 2022 Dihydroartemisinin (DHA) is a sesquiterpene endoperoxide with prominent antimalarial efficacy, which was discovered by Professor Youyou Tu through the reduction of artemisinin in the 1970s.
Yue Bai +6 more
doaj +1 more source
Peroxide-Mediated Oxygenation of Organic Compounds by Fungal Peroxygenases
Antioxidants, 2022 Unspecific peroxygenases (UPOs), whose sequences can be found in the genomes of thousands of filamentous fungi, many yeasts and certain fungus-like protists, are fascinating biocatalysts that transfer peroxide-borne oxygen (from H2O2 or R-OOH) with high ...
Martin Hofrichter +6 more
doaj +1 more source
Catalytic Hydroxylation of Polyethylenes [PDF]
ACS Central Science, 2017 Polyolefins account for 60% of global plastic consumption, but many potential applications of polyolefins require that their properties, such as compatibility with polar polymers, adhesion, gas permeability, and surface wetting, be improved. A strategy to overcome these deficiencies would involve the introduction of polar functionalities onto the ...
Qian Li +4 more
openaire +5 more sources