Results 11 to 20 of about 194,006 (386)
Horticulture Research, 2022 Flavonoids are the most widespread polyphenolic compounds and are important dietary constituents present in horticultural crops such as fruits, vegetables, and tea.
Yilong Liu +8 more
semanticscholar +1 more source
Electrochemical aromatic C–H hydroxylation in continuous flow
Nature Communications, 2022 The direct hydroxylation of arene C–H bonds is a highly sought-after transformation but remains an unsolved challenge due to the difficulty in efficient and regioselective C–H oxygenation and high reactivity of the phenolic products leading to ...
Hao Long +4 more
semanticscholar +1 more source
A tautomeric ligand enables directed C‒H hydroxylation with molecular oxygen
Science, 2021 Easing oxygen into arenes Although oxygen is all around us, it is often surprisingly difficult to use it for selective chemical oxidations, necessitating more expensive, wasteful alternatives. Li et al.
Zhen Li +8 more
semanticscholar +1 more source
Decarboxylative Hydroxylation of Benzoic Acids
Angewandte Chemie, 2021 Herein, we report the first decarboxylative hydroxylation to synthesize phenols from benzoic acids at 35 °C via photoinduced ligand‐to‐metal charge transfer (LMCT)‐enabled radical decarboxylative carbometalation.
Wanqi Su, P. Xu, T. Ritter
semanticscholar +1 more source
Nature Communications, 2020 mTORC1 is an important regulator of muscle mass but how it is modulated by oxygen and nutrients is not completely understood. We show that loss of the prolyl hydroxylase domain isoform 1 oxygen sensor in mice (PHD1KO) reduces muscle mass.
G. D’Hulst +13 more
semanticscholar +1 more source
Enzymatic functionalization of carbon-hydrogen bonds [PDF]
, 2011 The development of new catalytic methods to functionalize carbon–hydrogen (C–H) bonds continues to progress at a rapid pace due to the significant economic and environmental benefits of these transformations over traditional synthetic methods.
Arnold, Frances H. +2 more
core +1 more source
Bioresources and Bioprocessing, 2020 Steroids are the most widely marketed products by the pharmaceutical industry after antibiotics. Steroid hydroxylation is one of the most important functionalizations because their derivatives enable a higher biological activity compared to their less ...
Xiaodong Zhang +6 more
semanticscholar +1 more source
Catalysts on Demand: Selective Oxidations by Laboratory-Evolved Cytochrome P450 BM3 [PDF]
, 2009 Efficient catalysts for selective oxidation of C-H bonds using atmospheric oxygen are highly desirable to decrease the economic and environmental costs associated with conventional oxidation processes.
Arnold, Frances H., Lewis, Jared C.
core +2 more sources
Gibberellin Metabolism in Flowering Plants: An Update and Perspectives
Frontiers in Plant Science, 2020 In plants, gibberellins (GAs) play important roles in regulating growth and development. Early studies revealed the large chemodiversity of gibberellins in plants, but only GA1, GA3, GA4, and GA7 show biological activity that controls plant development ...
Juan He +8 more
doaj +1 more source
Peroxide-Mediated Oxygenation of Organic Compounds by Fungal Peroxygenases
Antioxidants, 2022 Unspecific peroxygenases (UPOs), whose sequences can be found in the genomes of thousands of filamentous fungi, many yeasts and certain fungus-like protists, are fascinating biocatalysts that transfer peroxide-borne oxygen (from H2O2 or R-OOH) with high ...
Martin Hofrichter +6 more
doaj +1 more source