Results 181 to 190 of about 16,360 (266)

Au(I) Complex With an Abnormal Carbene Ligand Shows Anti‐Kasha Dual Photoluminescence Emission

Angewandte Chemie, EarlyView.
Incorporation of an abnormal N‐heterocyclic carbene into a heteroleptic linear Au(I) complex induces anti‐Kasha dual emission responsive to biologically relevant phenyl sulfate. ABSTRACT We report the first photoactive linear Au(I) complex with an abnormal N‐heterocyclic carbene (aNHC) ligand, Au(aIm)(Cz).
Natesan Mannangatti Rajendran, Seung Beom Cheon, Jungbin Shin, Ye Bin Jang, Taeyoon Kim, Youngmin You   +5 more
wiley   +1 more source

Schleyer-type hyperconjugative aromaticity in CH isomers of diazoles revealed by DFT and NBO analysis. [PDF]

Sci Rep
Dehkordi PN, Saeidian H, Mirjafary Z, Rouhani M.   +3 more
europepmc   +1 more source

Harnessing the Reactivity of Sulfinate Salts With Cystine: An Umpolung Approach to Residue‐Specific Peptide Modification

Angewandte Chemie, EarlyView.
While cysteine is widely employed as a nucleophilic handle for peptide modification, the electrophilicity of the oxidized form, cystine, is rarely exploited. This study describes a mild, photochemical coupling of sulfinate salts with peptide disulfides.
Joshua M. Hammond, Esteban Suárez‐Picado, Lena von Sydow, Hanna Bruss, Laurent Knerr, Magnus Johansson, Anaïs Noisier, Lara R. Malins   +7 more
wiley   +1 more source

Magnetic BiFeO₃ nanoparticles as a sustainable and efficient catalyst for the green synthesis of highly substituted imidazole derivatives. [PDF]

Sci Rep
Hanifi S, Dekamin MG, Eslami M.
europepmc   +1 more source

Tailoring High‐Valent Iron‐Oxo Species Redox via Extended π‐Fe3d–O2p Orbital Overlapping Toward Chemical‐Efficient Water Purification

Angewandte Chemie, EarlyView.
We address the long‐standing challenge of reactivity–selectivity trade‐off by precisely tuning the redox properties of Fe(IV), rather than simply accelerating its formation, to enable chemically efficient and low‐emission water treatment. ABSTRACT High‐valent iron oxo species (Fe(IV)) are attractive for wastewater treatment because of their high ...
Hongyu Zhou, Junwen Chen, Jiuyi Wang, Xinhao Wang, Qiming Zhang, Shiying Ren, Xuning Li, Li Gao, Shaobin Wang, Xiaoguang Duan   +9 more
wiley   +1 more source

Chemoselective Cu-catalyzed acylsilylation of vinyl arenes using silylboronates and acyl fluorides. [PDF]

Chem Sci
Zhao Z, Zhou J, Ochiai S, Ikawa S, Shibata N.   +4 more
europepmc   +1 more source

Ein reversibler 900‐nm‐Nahinfrarot‐Photoschalter für unsichtbar lichtbeschreibbare 2D‐ und 3D‐Displays

Angewandte Chemie, EarlyView.
Der peri‐benzo[a]fluoranthenthioindigo (PBFT) Photoschalter kann direkt durch Nahinfrarot‐Licht mit Wellenlängen bis zu 900 nm angeregt werden. Er bietet ein hochperformantes Eigenschaftsprofil mit kontrastreichen Farbänderungen zwischen blassgrün und tiefblau.
Elias Ciekalski, Henry Dube
wiley   +1 more source

Synthesis of Fused sp³-Enriched Imidazoles. [PDF]

ChemistryOpen
Lysenko V, Portiankin A, Shvydenko T, Shishkina S, Nazarenko K, Kostyuk A.   +5 more
europepmc   +1 more source

Speciation‐Controlled C–F Bond Functionalization Enabled by Zwitterionic Pnictinidenes

Angewandte Chemie, EarlyView.
Zwitterionic pnictinidenes turn C–F activation into C–X bond construction, enabling broad defluorinative functionalization of polyfluoro(hetero)arenes under mild conditions. Rather than following a metallomimetic Sb(I)/Sb(III) redox turnover, catalysis is redirected by ligand scrambling into a redox‐neutral manifold, revealing catalyst speciation as a ...
Irene Sánchez‐Sordo, Sergio Fernandez, Selwin Fernando, Diego M. Andrada, Oriol Planas   +4 more
wiley   +1 more source

1-(4-Bromo-phen-yl)-4,5-diphenyl-2-(1<i>H</i>-pyrrol-2-yl)-1<i>H</i>-imidazole. [PDF]

IUCrdata
Nagaraj S, Loganathan N.
europepmc   +1 more source