Results 201 to 210 of about 30,850 (304)

Selective Nitrate Transmembrane Transport Through Adaptive Weak C─H Bonding Cyanostilbene Water Channels

open access: yesAngewandte Chemie, EarlyView.
Here we demonstrate that weak HB CH donor cyanostilbenes promote water/ion transport through their ability to form less‐ordered transient water channels within the lipid bilayer with increased water permeability and NO3−/ Cl− selectivity. ABSTRACT Transmembrane water transport strongly depends on how dynamic, translocating water clusters are stabilized
Ioan Stroia   +6 more
wiley   +2 more sources

Biological evaluation of amidine derivatives: In vitro cytotoxicity and cellular antioxidant capacity. [PDF]

open access: yesPLoS One
Pérez-Madrigal MM   +9 more
europepmc   +1 more source

Slowing Down Water: Enhanced and Cation‐responsive MRI Contrast

open access: yesAngewandte Chemie, EarlyView.
The controlled modification of mesoporous silica nanoparticle side walls with kosmotropic motifs supports an ability to reduce water diffusive mobility and dramatically increase MRI contrast to levels unprecedented for highly kinetically stable Gd‐DOTA configurations (both q = 1 and q = 0).
Connor M. Ellis   +5 more
wiley   +2 more sources

Katalysatoraktivierung als Schlüsselfaktor in Kreuzkupplungen: Raumtemperatur‐Kupplungen schwacher Nukleophile ermöglicht durch [Pd(1‐MeNAP)TFA]2 Präkatalysatoren

open access: yesAngewandte Chemie, EarlyView.
Bei vielen Pd‐katalysierten Kreuzkupplungen hat sich gezeigt, dass die Katalysatorleistung durch dessen Aktivierung begrenzt wird. Methylnaphthyl (MeNAP)‐Palladiumtrifluoracetat‐Dimere werden als leicht zu lagernde und handhabende Präkatalysatoren vorgestellt, die sich unter Reaktionsbedingungen schnell aktivieren, selbst wenn nur schwach ...
Sourav Manna   +6 more
wiley   +1 more source

Catalytic Enantioselective Intramolecular Aza‐Michael Addition to α,β‐Unsaturated Esters

open access: yesAngewandte Chemie, EarlyView.
A general method for accessing enantioenriched saturated N‐heterocycles via a catalytic enantioselective intramolecular aza‐Michael reaction to α,β‐unsaturated esters is described. A superbasic bifunctional iminophosphorane (BIMP) catalyst was key to enabling reactivity of the high pKa sulfonamide pronucleophile, whilst delivering good to excellent ...
Evan G. W. Rutter   +5 more
wiley   +2 more sources

Benzo[<i>d</i>]imidazole-Naphthalen-Arylmethanone Regioisomers as CB<sub>1</sub> Ligands: Evaluation of Agonism via an Indirect Cytotoxicity-Based Approach. [PDF]

open access: yesInt J Mol Sci
Hwa Cho AY   +8 more
europepmc   +1 more source

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