A new photochromic material was developed. Its on/off‐switchable absorption band is situated completely outside the human eye's visibility, in the near‐infrared (NIR) region, a feature never reported before. The photochromism mechanism in this aluminosilicate is elucidated by combining experimental as well as computational results, and the material's ...
Bettiina Muurinen +15 more
wiley +1 more source
Greening of Monocyclic N- and O‑Azole Synthesis through Sonochemistry. [PDF]
Hoffman GR, Saeed MM, Schoffstall AM.
europepmc +1 more source
Heterogeneous iron‐catalyzed environmentally benign and sustainable CH‐oxidative esterification methodology has been developed for the synthesis of esters. This challenging reaction has been achieved by the rational design of specific single atom iron‐based catalyst with Fe‐N4 active centers, which empowered the oxidative esterification of methyl and ...
Zhuang Ma +8 more
wiley +1 more source
Mechanochemistry to Form Substituted Imidazoles, Imidazolium Salts and NHC-Gold Complexes with Fluorine-Containing Groups. [PDF]
Salis C +7 more
europepmc +1 more source
Redirecting Excited‐State Proton Transfer Through Supramolecular Polymerization in Nanoconfinement
Supramolecular confinement redirects the excited‐state proton transfer pathway of an amphoteric emitter. In water, the molecule undergoes ESPD, whereas co‐assembly with γ‐cyclodextrin forms nanotubes that template slip‐stacked emitter pairs and enable ESIMPT. Structural and photophysical characterization of the assemblies shows that the preorganization
Luis C. Pantaleone +8 more
wiley +1 more source
Design, synthesis, anticancer properties, and molecular docking of imidazolone derivatives with lipophilic moiety. [PDF]
Fares O +10 more
europepmc +1 more source
Borylcyclopropanes: Synthetic Strategies and Applications
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley +1 more source
A retrospective 9-years overview of sulfated polyborate as a robust catalyst for organic transformations. [PDF]
Chhaperwal P +4 more
europepmc +1 more source
Electrochemically Triggered Supramolecular Polymerization Under Kinetic Control
Chemical and electrochemical stimuli enable controlled supramolecular polymerization of perylene diimide–histidine (PDI–His). Redox processes mediate the transformation of kinetically trapped aggregates into thermodynamically stable nanofibers, thereby supporting seeded growth. This approach provides a strategy for regulating self‐assembly pathways and
Eun Gyu Lee +6 more
wiley +1 more source
Cooperative photoredox and N-heterocyclic carbene-catalyzed formal C-H acylation of cyclopropanes via a deconstruction-reconstruction strategy. [PDF]
Gao F, Wang T, Yan X.
europepmc +1 more source

