Angewandte Chemie, EarlyView.Human H ferritin (HuHf) is a nanocarrier for anticancer metal drugs. By cryo‐EM, a 1.51 Å structure of its adduct with Au(NHC)Cl was solved, showing a novel tetranuclear gold(I) cluster bound to Cys90 and Cys102. Short inter‐metal distances indicate aurophilic interactions.
Lucrezia Cosottini +9 more
wiley +1 more source
Design of Highly Conductive PILs by Simple Modification of Poly(epichlorohydrin-co-ethylene oxide) with Monosubstituted Imidazoles. [PDF]
ACS Polym AuNosov DR +8 more
europepmc +1 more source
An Artificial Metal‐Free Peroxidase Designed Using a Ferritin Cage for Bioinspired Catalysis
Angewandte Chemie, EarlyView.Designing artificial enzymes remains challenging due to the need for precise active site control. Here, we present a simple strategy to create metal‐free artificial enzymes by engineering Histidine clusters inside a ferritin cage. The resulting catalyst mimics peroxidase activity, and its stable cage structure offers new insights into supramolecular ...
Jiaxin Tian +4 more
wiley +1 more source
On-Chip Electrochemical Sensor Based on 3D Graphene Assembly Decorated Ultrafine RuCu Alloy Nanocatalyst for In Situ Detection of NO in Living Cells. [PDF]
Nanomaterials (Basel)Liu H +5 more
europepmc +1 more source
Cyclo‐P5− neu betrachtet: Das erstaunlich stabile unkoordinierte Pentaphospholid‐Anion
Angewandte Chemie, EarlyView.Das faszinierende cyclo‐P5−‐Anion, das isolobal zum bekannten Cyclopentadienyl‐Anion ist, wurde erstmals kristallographisch in den Salzen [M([2.2.2]cryptand)][cyclo‐P5] (M = Na, K) charakterisiert. Die Verbindungen wurden ferner durch UV/Vis‐Spektroskopie in Lösung und im festen Zustand durch Raman‐ und 31P MAS NMR‐Spektroskopie charakterisiert ...
Moritz J. Ernst +4 more
wiley +1 more source
Amebicidal Activity of <i>Escherichia coli</i> Nissle 1917 Against <i>Entamoeba histolytica</i>. [PDF]
MicroorganismsMoura-Oliveira V +9 more
europepmc +1 more source
Update: Enzymatische Synthese für industrielle Anwendungen
Angewandte Chemie, EarlyView.Die Biokatalyse hat sich zu einer nachhaltigen und wettbewerbsfähigen Alternative zur herkömmlichen chemischen Synthese entwickelt und ermöglicht die enzymbasierte Herstellung nicht nur von chemischen Grundstoffen, sondern auch von (nicht natürlichen) Aminosäuren, (seltenen) Zuckern und synthetischen Nukleotiden.
Thomas Bayer +4 more
wiley +1 more source
Self‐Photosensitizing Cobalt Complexes for Photocatalytic CO2 Reduction Coupled with CH3OH Oxidation
Angewandte Chemie, EarlyView.Self‐photosensitizing non‐noble metal complexes achieve CO2 photoreduction coupled with CH3OH photooxidation, simultaneously synthesizing formic acid in the absence of any additional photosensitizers and electron sacrificial reductants. Abstract The use of metal complexes as homogeneous molecular catalysts has attracted considerable attention regarding
Ji‐Hong Zhang +5 more
wiley +1 more source
High-temperature water unlocks urea as nitrogen-source towards imidazoles.
Green ChemAmaya-García F +2 more
europepmc +1 more source
Angewandte Chemie, EarlyView.Mechanosynthesis of polyZIF overcomes MOF‐polymer phase incompatibility via in‐situ polymer‐Zn2+‐Im coordination networks. Pore architecture engineering yielded molecular‐sieving membrane transport channels that enhanced butadiene permeance to 332 GPU while maintaining outstanding selectivities against C4 hydrocarbons through the size‐exclusion ...
Ning Li +10 more
wiley +1 more source