Correction: C-2 functionalization of indoles with xanthate-lactam derivatives by radical-oxidative coupling, an approach to <i>Aspidosperma</i> alkaloids. [PDF]
Pastrana M, Mijangos MV, Miranda LD.
europepmc +1 more source
Bifunctional Photocatalysts: Exploiting Proximity for Enhanced Reaction Performance
This review covers the application of the bifunctional approach to photocatalysis as a means to attain (enhanced) enantioselectivity, and, more in general, as a strategy to enhance the catalytic performance through an effective use of short‐lived reaction intermediates.
Luigi Dolcini +3 more
wiley +1 more source
Regioselective C2-Sulfonylation of Indoles and Pyrroles via SO<sub>2</sub> Insertions. [PDF]
Bai R +5 more
europepmc +1 more source
Synthesis of (E)‐β‐SF5‐Styrenes via a Heck Reaction of in situ Generated Vinylsulfur Pentafluoride†
A Heck cross‐coupling reaction between aryl(hetero)iodides and in situ generated vinylsulfur pentafluoride is reported. This reaction provides β‐SF5‐styrenes in one‐step as a single (E)‐stereoisomer and tolerates a broad range of functional groups. Comprehensive Summary The synthesis of (E)‐(1‐alken‐1‐yl)pentafluoro‐λ6‐sulfanes, a valuable class of ...
Nicolas DeGrâce +1 more
wiley +1 more source
2-Lithiomethylindoles: Untapped Anions for the Synthesis of 2-Functionalized Indoles. [PDF]
Gómez-Gil S +3 more
europepmc +1 more source
High atmospheric pressure (120 kPa) in deep underground counteracts humidity‐induced physiological stress in plants, stabilizing water balance and enhancing antioxidative defenses. This synergy boosts biomass despite elevated humidity, demonstrating sustainable deep underground agriculture potential under climate uncertainty.
Yuxin He +6 more
wiley +1 more source
Molecular iodine catalyzed C3-quaternization <i>via</i> oxidative dearomatization of indoles: direct access to 3,3-di(indolyl)indolin-2-ones. [PDF]
Singh N +3 more
europepmc +1 more source
Abstract The immune system has long been recognized as a key driver in the progression of heart failure (HF). However, clinical trials targeting immune effectors have consistently failed to improve patient outcome across different HF aetiologies. The activation of the immune system in HF is complex, involving a broad network of pro‐inflammatory and ...
Johann Roessler +4 more
wiley +1 more source
Oxidative Rearrangement of Indoles Enabled by Promiscuous Cryptic Halogenation with Vanadium-Dependent Haloperoxidases. [PDF]
Lee HJ +7 more
europepmc +1 more source
Organic azides are readily reduced to amines under mild conditions by ammonia borane complex, catalyzed by a low loading level of reusable Au nanoparticles supported on TiO2. We present the first protocol for the chemoselective reduction of organic azides to amines by ammonia borane complex. In the presence of a low catalytic amount of Au nanoparticles
Elisavet‐Maria Zantioti‐Chatzouda +5 more
wiley +1 more source

