Results 131 to 140 of about 41,075 (284)

Cu(OTf)2-Catalyzed Asymmetric Friedel-Crafts Alkylation Reaction of Indoles with Arylidene Malonates Using Bis(sulfonamide)-Diamine Ligands

open access: yes, 2013
Cu(OTf)2-Catalyzed Asymmetric Friedel-Crafts Alkylation Reaction of Indoles with Arylidene Malonates Using Bis(sulfonamide)-Diamine ...
吴凡, 王东平, 万伯顺, 吴静
core  

Three Component Thio‐ and Carboboration of Alkynes: A Modular Route to Functionalised Bicyclic Boronates

open access: yesAngewandte Chemie, EarlyView.
Three‐component thio‐ and carbo‐boration reactions to form functionalised benzoxaborinines and benzazaborinines are reported. The nucleophile scope includes thioethers, thiols, and (hetero)arenes. Mechanistic studies revealed a disparity between thioboration using thioethers and using thiols.
Laura Winfrey   +4 more
wiley   +2 more sources

Palladium-Catalyzed C3-Benzylation of Indoles

open access: yes, 2016
A general method for regioselective C3-benzylation of indoles has been developed. Various 3-substituted indoles and benzyl methyl carbonates with different electronic properties react under mild conditions to afford a diverse range of 3-benzylindolenine ...
Ye Zhu (646531)   +1 more
core   +1 more source

Carbonylated Indoles from PdII-Catalyzed Intermolecular Reactions of Indolyl Cores

open access: yes, 2019
International audienceThis review summarizes palladium-catalyzed carbonylation, transmetalation, and cross-coupling reactions that lead to carbonylated indoles from indoles and indolyl compounds.
Le Bras, Jean, Muzart, Jacques
core   +1 more source

Color‐Pure Organic Luminophores: Characteristics, Definitions, Physical Basis and Fundamental Design Principles

open access: yesAngewandte Chemie, EarlyView.
Color‐pure all‐organic emitters, i.e., with narrow spectral characteristics, are intensively studied for high‐definition organic LEDs and multi‐color bioimaging. In order to guide targeted materials design, this educative review discusses spectral characteristics, proper definitions and units, and the physical basis of spectral broadening, to distill ...
Johannes Gierschner   +6 more
wiley   +2 more sources

Regioselective hydrodebromination of polybrominated indoles

open access: yes, 2014
The mixture of sodium borohydride and N,N,N′,N′-tetramethylethylenediamine in combination with a palladium catalyst is a mild and efficient system for the regioselective hydrodebromination of polybrominated indoles with both N-donating and N-withdrawing ...
Giorgio Chelucci   +5 more
core   +1 more source

Electrophilic Substitutions of Indoles and Pyrroles:

open access: yes, 2007
The kinetics of the electrophilic substitutions of indoles and pyrroles have been investigated and new sythetic applications (i.e. electrophilic allylations and benzylations of indoles and regio- and stereoselective ring opening reactions of epoxides ...
Westermaier, Martin
core  

Novas metodologias eficientes para a reação de transferência de diazo: preparação de y-azido-a-diazo-b-ceto éster e aplicações na síntese de amidas e indóis [PDF]

open access: yes, 2015
Tese (doutorado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas, Programa de Pós-Graduação em Química, Florianópolis, 2015.Neste trabalho foram desenvolvidas novas metodologias para a obtenção de diazo compostos 1,3 ...
Dutra, Luiz Gustavo
core  

Radical intermediates in the peroxidation of indoles

open access: yes, 2001
2-Substituted and 1,2-disubstituted indoles react with m-chloroperbenzoic acid and hydrogen peroxide in the presence of acid or calcium chloride affording 2- and 3-(3-oxoindol-2-yl)indoles; whereas 2,3-disubstituted indoles, reacting with the same ...
P. ASTOLFI   +9 more
core   +1 more source

Ein Ruthenium‐(Ph‐BPE) Katalysator für die asymmetrische Alkinylierung von Fluoral: Enantioselektion aus einem von 12 fluxionalen Komplexen mit rutheniumzentrierter Stereogenität

open access: yesAngewandte Chemie, EarlyView.
Dies beschreibt die ersten enantioselektiven Alkinylierungen wässrigen Fluorals. Diese Prozesse werden durch einen Iodid‐gebundenen Ruthenium‐(Ph‐BPE)‐Komplex katalysiert, welcher als oktaedrischer Metallkomplex in 12 verschiedenen stereoisomeren Formen vorliegen kann.
Weijia Shen   +6 more
wiley   +1 more source

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