Results 101 to 110 of about 1,834 (212)
The nitrogen‐heteroatom single bonds of 1,2‐azoles and isoxazolines underwent methylene insertion in the presence of CH2I2 (6 equiv.) and diethylzinc (3 equiv.) to produce a wide variety of the ring‐expanded six‐membered heterocycles.
Masato Tsuda +4 more
doaj +1 more source
Heterocyclic compounds are crucial starting reagents and intermediates, or they are direct precursors of target chemicals and/or bio-pharmacological active compounds. Today, they are used in the total synthesis of natural products, in drugs or herbicides,
Vitale P., Scilimati A.
core +1 more source
A completely regioselective approach to bicyclic isoxazolines has been found starting from 4-cyclopentene-1,3-dione or 2-cyclopentenones. 1,3-Dipolar cycloaddn. with nitrile oxides gave different semirigid bicyclic scaffolds with at least four points of
Giorgi, Gianluca +20 more
core +1 more source
PYRAZOLINES AND ISOXAZOLINES (I). SYNTHESIS AND ANTIMICROBIAL ACTIVITIES OF P-(1-ACYL-3-METHYL-5-ARYL-4 PYRAZOLINOYL / P-(3-METHYL-5-ARYL-4ISOXAZOLINOYL) ARSANILIC ACID [PDF]
4-(acetoacetamido) arsanilic acid (II), which was then condensed with aryl aldehydes. The resulting product on reaction with hydrazine hydrate and hydroxyl amine hydrochloride yielded Pyrazolines (IV) and Isoxazolines (V), respectively. The antimicrobial
doaj
P-37 Synthesis of Isoxazolines
Isoxazolines are organic molecules characterized by their five-membered ring heterocycles containing nitrogen and oxygen, and by their diverse synthetic and biological properties.
Thornhill, Rosanne
core
A practical metal-free and additive-free approach for the synthesis of 6/7/8-membered oxacyclic ketone-fused isoxazoles/isoxazolines tetracyclic or tricyclic structures is reported through Csp3–H bond radical nitrile oxidation and the intramolecular ...
Jian-Kang Cao +9 more
doaj +1 more source
Synthesis and reductive cleavage of 3-(2-flurophenyl) and 3-(4-flurophenyl)-cyclopent-5-en[d]isoxazolines by raney nickel in trifluroacetic acid [PDF]
3-Fluoro arylcycloopent-5-en[d]isoxazolines have been obtained via the 1,3-dipolar cycloaddition of cyclopentadiene to aromatic nitrile oxides. The reductive cleavage of these isoxazolines by Raney nickel in trifluoroacetic acid led to corresponding ...
Antonevich, I. P. +2 more
core
International audienceThe use N-sulfonyl-protected hydroxylamines as bi-nucleophiles in iron-catalyzed propargylic substitutions allows the selective one-pot synthesis of four classes of substituted isoxazoles or isoxazolines from the same propargylic ...
Olivier Debleds +9 more
core +1 more source
Background The occurrence of higher winter temperatures in Brazilian areas with tropical and highland climates may result in a fifth peak of tick populations during winter in addition to the four generations previously described.
Guilherme Henrique Reckziegel +12 more
doaj +1 more source

