Results 171 to 180 of about 66,773 (266)

Inhalation of Isopropyl Alcohol Leading to Acute Severe Toxicity: A Case Report. [PDF]

Clin Case Rep
Thiravetyan B, Puchongmart C, Mathew J, Chaisrimaneepan N, Rodriguez C, Bueso A, Rielo D, Cruz D.   +7 more
europepmc   +1 more source

An NHC‐Coordinated Silicon/Sulfur Analogue of an Acyl Carbene

Angewandte Chemie, EarlyView.
An NHC complex of an Si/S analogue of an acyl carbene is synthesized by the reaction of a disilyne with a cyclic thiourea. The observed Si2S three‐membered ring with unsymmetrical Si─S distances and a Si─Si single bond is consistent with intramolecular coordination of the silathioacyl sulfur to the silylene center.
Takuto Toyooka, Shintaro Ishida, Takeaki Iwamoto   +2 more
wiley   +1 more source

Aldehyde-Olefin Couplings by Photoinduced Reduction of Electron-Deficient Olefins with Hantzsch Ester Anions. [PDF]

Angew Chem Int Ed Engl
Li Z, Noble A.
europepmc   +1 more source

Dyotropic Rearrangement of Hypervalent Iodine Species: Migrative Heterofunctionalization of Quaternary Carbons

Angewandte Chemie, EarlyView.
1,2‐Aryl migration involving in situ‐generated alkyl iodine(III) species proceeds through a previously unrecognized 1,2‐C/I(III) dyotropic rearrangement. Migratory aryl fluorination, acetoxylation, and alkoxylation of 2‐alkyl‐2‐aryl‐3‐iodopropanoates provide α‐heterofunctionalized products, accompanied by aryl migration from the α‐ to the β‐position ...
Chen‐Xu Liu, Qian Wang, Matthew D. Wodrich, Jieping Zhu   +3 more
wiley   +1 more source

Nitrosonium Tetrafluoroborate-Promoted α,α-Diacetoxylation of Aryl Methyl Ketones. [PDF]

J Org Chem
Li JJ, Hsiao CH, Hou DR.
europepmc   +1 more source

Photochemical Ring Opening of Cyclopropyl Silyl Ethers Enables β–β Coupling, Radical‐Polar Crossover and Annulation

Angewandte Chemie, EarlyView.
A photochemical platform enables β–β coupling of cyclopropyl silyl ethers with electron‐deficient alkenes. The resulting adducts serve as entry points into annulative and radical–polar crossover pathways, providing rapid access to fused, bridged, and spirocyclic architectures, including late‐stage scaffold diversification to diterpene‐like carbocyclic ...
Jacop Rydén, Eilidh Young, Wilma Olsson, Eskil Flodén, Mattias Tan, Sebastian Clementson   +5 more
wiley   +1 more source

Continuous flow unlocks modular ketones assembly enabled by dynamic orbital selection. [PDF]

Chem Sci
Wang J, Zhou S, Hu X, Pan S, Zhuang X, Li J, Tang R, Xie Y, Sun B, Jin C.   +9 more
europepmc   +1 more source

T‐Shaped Stibenium(III) Cation: Hydrostibination Without Sb─H Bond

Angewandte Chemie, EarlyView.
A cationic, structurally constrained stibenium platform mediates anti‐Markovnikov hydrostibination of alkenes via element–ligand cooperativity (ELC), thereby bypassing the need for weak Sb─H bonds. ABSTRACT The hydrostibination of alkenes represents a largely underdeveloped transformation, owing to the intrinsic lability of the required Sb─H reagents ...
Ekta Nag, Lars Ole Busse, Andreas Albers, Manuel Schmitt, Lutz Greb   +4 more
wiley   +1 more source

Ketones in Cardiovascular Health and Disease: An Updated Review. [PDF]

Cells
Shrestha S, Harrison I, Dosunmu A, Song P.   +3 more
europepmc   +1 more source

Water, Alcohols, Amines, and Amides as Formal Hydrogen‐Atom‐Transfer Reagents Through Activation With Redox‐Active Lewis Acids

Angewandte Chemie, EarlyView.
Protic molecules containing strong O─H or N─H bonds typically resist hydrogen‐atom abstraction because of the high reactivity of the resulting heteroatom‐centered radicals. However, association of the protic molecules with redox‐active Lewis acids can provide powerful hydrogen‐atom donors or proton‐coupled‐electron‐transfer reagents.
Petra Vojáčková, Armido Studer
wiley   +1 more source