Results 181 to 190 of about 205,384 (273)

Microwave-Assisted Deoxygenation of Substituted Aromatic Ketones over Commercial Pd/Al₂O₃ under Mild Conditions. [PDF]

ACS Omega
Bucciol F, C Vega I, Calcio Gaudino E, Manzoli M, Tabasso S, Cravotto G.   +5 more
europepmc   +1 more source

Aryl and Alkyl Radiotrifluoromethylation via Metallaphotoredox‐Mediated Radical Cross‐Coupling

Angewandte Chemie, EarlyView.
The metallaphotoredox‐mediated radiotrifluoromethylation of arenes and alkanes is described. The operationally simple protocols make use of substrates bearing thianthrenium salts (TT) or N‐hydroxyphthalimide (NHPI) esters and CF218FI. The reaction proceeds through a Ru‐mediated radical formation followed by a Cu‐mediated radical cross‐coupling step and
Lukas Veth, Albert D. Windhorst, Danielle J. Vugts   +2 more
wiley   +2 more sources

Iron-borane catalyzed carbonyl hydroboration and isolation of an iron(I)-ketyl radical. [PDF]

Nat Commun
Grose LA, Schwamm RJ, Brookfield A, Robinson D, Willcox D.   +4 more
europepmc   +1 more source

Bridged Pyrroloindole‐CAYC‐Gold Complexes: Harnessing Weak Secondary Intramolecular Au···H−C(sp3) Interactions in Gold(I) Catalysis

Angewandte Chemie, EarlyView.
We present a new class of electronically and sterically hindered N‐heterocyclic carbenes, referred to as bridged cyclic (amino)ylide carbene (bCAYC), where 9H‐pyrrolo[1,2‐a]indole acted as carbene core and diaryl sulfonium as ylide partner. Corresponding bCAYC‐Au(I) exhibits a weak secondary intramolecular Au···H−C(sp3) interaction as a secondary ...
Sourav Sekhar Bera, Anurag Kumar, Pengcheng Gao, Sanghamitra Das, Roger Lalancette, Roman Szostak, Michal Szostak   +6 more
wiley   +2 more sources

A ketogenic diet enhances aerobic exercise adaptation and promotes muscle mitochondrial remodeling in hyperglycemic male mice. [PDF]

Nat Commun
Pattamaprapanont P, Nava RC, Grover R, Formato M, Cooney EM, Pinto AP, Alves-Wagner AB, Das A, Guan Y, Annambhotla M, Acharya S, Rivas DA, Lessard SJ.   +12 more
europepmc   +1 more source

Navigating Nitration Chemistry: A Practical Guide to Reagents, Mechanisms, and Selectivity

Angewandte Chemie, EarlyView.
This review highlights key contributions of modern nitration chemistry, emphasizing sustainable mechanistic platforms and comparing the performance of both organic and inorganic reagents across aromatic, ipso‐, olefin, alkyne, and heteroatom nitration. It provides the community with a clearer, unified perspective on current advances and facilitates the
Harry Lecomte, Anthony J. Fernandes, Dmitry Katayev   +2 more
wiley   +2 more sources

Case Report: Bexagliflozin as an adjunct decongestive strategy in a cat with congestive heart failure and advanced chronic kidney disease. [PDF]

Front Vet Sci
Kim BJ, Song KH.
europepmc   +1 more source

Ketones

NIPPON KAGAKU KAISHI, 1930
openaire   +2 more sources

Hydrogen Atom Transfer Induces Photodegradation in Carbonyl‐Based Multi‐Resonance TADF Emitters

Angewandte Chemie, EarlyView.
Boosting triplet harvesting in N/C═O MR‐TADF emitters unexpectedly induces rapid photodegradation under oxygen‐free conditions. Spectroscopic studies reveal that triplet excited states trigger hydrogen‐atom transfer from solvent to the carbonyl unit, driven by triplet energetics and hydrogen electrophilicity.
Changfeng Si, Elvie F. P. Beaumont, Jenn Zi Yu Tan, Mitchell J. Demchuk, Zachary M. Hudson   +4 more
wiley   +2 more sources

Molecular sensory science elucidates the contribution of methyl ketones to the creamy aroma of <i>Monascus</i>-fermented cheese. [PDF]

Curr Res Food Sci
Wang Y, Wang Y, Meng T, Wang B, Wang Y.
europepmc   +1 more source