Synthesis of highly alkylated functionalized cyclopentadienes [PDF]
, 1988 Tetra- and pentaalkylated cyclopentadienyl ketones and carboxylic acids are prepared by electrophilic allylation of enolizible 1,3-dicarbonyl compounds and successive acid catalyzed ...
Koschinsky, Rainer +2 more
core +1 more source
Green Processing and Synthesis, 2019 Monoaldehydes and dialdehydes are parts of millions of compounds and are extremely versatile intermediates. For the synthesis of monoaldehydes, one impressive approach to date, because of its excellent selectivity, high yield and stability towards over ...
Faisal Muhammad +4 more
doaj +1 more source
Effects of insecticidal ketones present in mint plants on GABA A receptor from mammalian neurons [PDF]
, 2017 The genus Mentha, an important member of the Lamiaceae family, is represented by many species commonly known as mint. The insecticidal activity of Mentha oil and its main components has been tested and established against various insects/pests.
Delgado Marín, Leticia Ester +2 more
core +2 more sources
Selective oxidation of some primary and secondary benzylic alcohols to the corresponding carbonyl compounds with a Cu(III) complex [PDF]
Journal of the Serbian Chemical Society, 2005 The selective oxidation of benzylic alcohols to the corresponding carbonyl compounds is described. In alkaline solution, the oxidation reagent potassium tetrasodium diperiodatocuprate(III) dodecahydrate (KNa4[Cu(HIO6)2]×12H2O) reacts with primary and ...
VLADAN KOSTIC +2 more
doaj
A general deoxygenation approach for synthesis of ketones from aromatic carboxylic acids and alkenes
Nature Communications, 2018 The construction of an aryl ketone structural unit by means of catalytic carbon–carbon coupling reactions represents the state-of-the-art in organic chemistry.
Muliang Zhang, Jin Xie, Chengjian Zhu
semanticscholar +1 more source
Efficient and Practical Transfer Hydrogenation of Ketones Catalyzed by a Simple Bidentate Mn−NHC Complex [PDF]
, 2019 Catalytic reductions of carbonyl‐containing compounds are highly important for the safe, sustainable, and economical production of alcohols. Herein, we report on the efficient transfer hydrogenation of ketones catalyzed by a highly potent Mn(I)−NHC ...
Benschop, Joeri +6 more
core +1 more source
Oilseeds and fats, crops and lipids, 2018 Optimal brain performance is intimately linked to the brain’s Yin and the Yang − the balance between its structure and its energy metabolism. This relationship is clearly exemplified in infant brain development and in Alzheimer’s disease, and probably ...
Cunnane Stephen C.
doaj +1 more source
Reactive organoallyl species generated from aryl halides and allene: allylation of alpha,beta-unsaturated aldehydes and cyclic ketones employing Pd/In transmetallation processes [PDF]
, 2008 Allylation of α,β-unsaturated aldehydes and cyclic ketones promoted by Pd/In transmetallation processes has been studied. The unsaturated aldehydes underwent regioselective 1,2-addition to afford secondary homoally alcohols.
Anwar +56 more
core +2 more sources
Alkynes as Synthetic Equivalents of Ketones and Aldehydes: A Hidden Entry into Carbonyl Chemistry
Molecules, 2019 The high energy packed in alkyne functional group makes alkyne reactions highly thermodynamically favorable and generally irreversible. Furthermore, the presence of two orthogonal π-bonds that can be manipulated separately enables flexible synthetic ...
Igor V. Alabugin +4 more
doaj +1 more source
Iridium-Catalyzed and pH-Dependent Reductions of Nitroalkenes to Ketones
Molecules, 2022 A highly chemoselective conversion of α,β-disubstituted nitroalkenes to ketones is developed. An acid-compatible iridium catalyst serves as the key to the conversion.
Tingting Wang +4 more
doaj +1 more source