Results 91 to 100 of about 25,988 (242)

Harnessing Free Radical Scavenging Potential of Caffeic Acid as a Nutraceutical—A Review

open access: yesFood Safety and Health, EarlyView.
Caffeic acid has emerged as a promising bioactive molecule with multiple pharmacological properties, including antioxidant, antimicrobial, anti‐inflammatory, organ protective properties and metal‐chelating ability. This review emphasizes the dietary sources, structural characteristic, molecular mechanism underlying health promoting effects of caffeic ...
Pavitra Behra   +2 more
wiley   +1 more source

Sulfur Ylides in Skeletal‐Editing—Ring Expansion Reactions

open access: yesHelvetica Chimica Acta, EarlyView.
Sulfur ylides (S‐ylides) are emergent diazo surrogates that enable skeletal editing and ring expansion with safer handling and broad functional group tolerance. This perspective covers pioneer works and highlights recent advances in the field, while outlining key challenges and future directions that may redefine the role of S‐ylides in modern ...
Arsala Kamal   +3 more
wiley   +1 more source

7-epi-griffonilide, a new lactone from Bauhinia pentandra: complete 1H and 13C chemical shift assignments

open access: yesAnais da Academia Brasileira de Ciências
A new lactone, 7-epi-griffonilide (1), and six known compounds, 2, 3a - 3c, 4a and 4b, were isolated from the leaves of Bauhinia pentandra (Fabaceae). The structures elucidation of 1 and 2 were based on detailed 2D NMR techniques and spectral comparison ...
MACIA C.S. DE ALMEIDA   +8 more
doaj   +1 more source

Photocaged and Water‐Soluble Glucose Functionalization for Spatiotemporal Acidification Pathways

open access: yesHelvetica Chimica Acta, EarlyView.
Light‐controlled glucose release from a water‐soluble coumarin photocage enables spatiotemporal acid generation in enzyme‐driven chemical reaction networks. ABSTRACT The spatiotemporal control of complex molecular systems, such as chemical reaction networks (CRNs), requires reagents and reactive species that can be activated both efficiently and ...
Nikolai Hempel   +2 more
wiley   +1 more source

Diterpenoid Diversity across Land Plants

open access: yesHelvetica Chimica Acta, EarlyView.
Here we bridge the knowledge of diterpene chemical diversity, biosynthesis, and evolution from nonvascular mosses and liverworts to that known from vascular plants. ABSTRACT The diverse array of diterpenoid natural products stems from the ease of manipulating the promiscuity of diterpene cyclases.
Anita Berg   +2 more
wiley   +1 more source

Synthesis of (+)-Marmelo Lacton A and (+)-Marmelo Lactone B [PDF]

open access: yesAgricultural and Biological Chemistry, 1983
Yoshihiro NISHIDA   +2 more
openaire   +2 more sources

Enzymatic Ring‐Opening Polymerization of ε‐Caprolactone in Novel Green Solvents: from Batch Systems to Continuous Flow Mesoreactors

open access: yesMacromolecular Materials and Engineering, EarlyView.
Multi‐gram synthesis of CaLB‐catalyzed ROP of ε‐CL in green organic media under flow conditions. ABSTRACT The transition toward sustainable alternatives in polymeric material production is a critical step in reducing the environmental impact of the traditional plastic industry.
Tullio Crovetto   +4 more
wiley   +1 more source

Constituintes químicos de Vernonia scorpioides (Lam) Pers. (Asteraceae) Chemical constituents of Vernonia scorpioides (Lam) Pers. (Asteraceae)

open access: yesQuímica Nova, 2013
The chemical investigation of hexane and ethanol extracts from the aerial parts of Vernonia scorpioides resulted in the isolation and characterization of a new polyacetylene lactone, rel-4-dihydro-4β-hydroxy-5a-octa-2,4,6-triynyl-furan-2-(5H)-one ...
Adalva Lopes Machado   +8 more
doaj  

FRET‐Based Investigation of the Dynamics of Peptide‐Folded Single Chain Nanoparticles Inside Cancer Cells

open access: yesMacromolecular Rapid Communications, EarlyView.
Little is known about the cellular uptake of single chain nanoparticles that are cross‐linked with dynamic bonds. Using Förster resonance energy transfer and fluorescence lifetime imaging microscopy (FRET‐FLIM) the dynamic nature of the bonds is seen, in which the interaction between two peptides, disassemble quickly, relatively.
Shegufta Farazi   +5 more
wiley   +1 more source

Nano Delivery Strategy Opens Effective Avenues for the Treatment of Colorectal Cancer

open access: yesMedicine Bulletin, EarlyView.
ABSTRACT Colorectal cancer (CRC) presents significant therapeutic challenges because of chemoresistance, systemic toxicity, and the complexity of the tumor microenvironment (TME). Nanodrug delivery systems (NDDS) have emerged as versatile platforms capable of overcoming these limitations by enhancing tumor accumulation, improving pharmacokinetics, and ...
Qiurong Wei   +7 more
wiley   +1 more source

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