Results 121 to 130 of about 98,587 (340)

Síntese e avaliação da atividade fitotóxica de lactonas derivadas do 2,4-dimetil-8-oxabiciclo[3.2.1]-oct-6-en-3-ona

open access: yesQuímica Nova, 2002
The alkene 2,4-dimethyl-8-oxabicyclo[3.2.1]-oct-6-en-3-one (3) was converted to 1,3,10-trimethyl-8-oxabicyclo[5.3.0]-dec-3-ene-2,9-dione (7) and 1,3-dimethyl-8-oxabicyclo[5.3.0]-dec-3-ene-2,9-dione (8) with a 55% overall yield in both cases. Lactones (7)
Barbosa Luiz Cláudio de Almeida   +2 more
doaj  

Sesquiterpene lactones isolated from a medicinal plant of the Venezuelan Andes [PDF]

open access: bronze, 2008
Jaime Delgado   +4 more
openalex   +1 more source

One‐Pot Transition‐Metal‐Free Methods for the Synthesis of All Three Bonds of the Alkyne's Triple Bond

open access: yesChemistry – A European Journal, EarlyView.
One‐pot transition‐metal‐free methods for the synthesis of all three bonds of the alkyne's triple bond are reviewed. After analysis of several named reactions and discussion of improvements, recent advances in the synthesis of alkynes are discussed. Each section contains a proposed reaction mechanism and analysis of the strengths and weaknesses of the ...
Eugene Kim   +4 more
wiley   +1 more source

In Vitro Metabolism of Helenalin Acetate and 11α,13-Dihydrohelenalin Acetate: Natural Sesquiterpene Lactones from Arnica [PDF]

open access: gold, 2022
Franziska M. Jürgens   +4 more
openalex   +1 more source

Photoinduced, Chemoselective γ‐Alkylation of 2‐Silyloxyfurans with α‐Bromoketones: A Rapid Entry to Chiral ε‐Keto‐γ‐Butenolides

open access: yesChemistry – A European Journal, EarlyView.
A photoinduced, regio‐ and chemoselective γ‐alkylation of 2‐silyloxyfurans with a‐bromoketones was achieved by exploiting a photoredox catalytic process promoted by blue light. This approach provides practical and efficient access to chiral, ε‐ketobutenolides, in one step and high yields.
Debora Guazzetti   +9 more
wiley   +1 more source

Production d'arômes de type lactone par des levures [PDF]

open access: yesBiotechnologie, Agronomie, Société et Environnement, 2010
Production of aroma lactones by yeasts. Lactones are widely distributed in foods and beverages as aroma compounds. Their extraction from natural products is very expensive.
Alchihab, M.   +3 more
doaj  

Synthesis and Glycosidase Inhibition Studies of Novel Exoglycals Targeting GH3 Family Enzymes: Insights from Comparative Analysis with Macrolide Antibiotics

open access: yesChemistry – A European Journal, EarlyView.
A series of structurally diverse exoglycals was synthesized using a modified Julia‐olefination approach from sugar‐derived precursors. These glycosidase transition‐state mimics were further diversified via CuAAC chemistry to yield triazole‐conjugated analogues.
Elisa Ospanow   +2 more
wiley   +1 more source

Cryptic post-transition state bifurcations that reduce the efficiency of lactone-forming Rh-carbenoid C-H insertions. [PDF]

open access: yes, 2017
Byproducts of chemical reactions are generally thought to result from the competition between two reaction pathways, each with its own rate-determining transition state structure.
Hare, Stephanie R, Tantillo, Dean J
core  

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