Results 81 to 90 of about 46,706 (268)

Coordinative Ring‐Opening Polymerization of Limonene Carbamate towards Phosgene‐ and Isocyanate‐Free Polyurethane

open access: yesAngewandte Chemie International Edition, Accepted Article.
This study presents a phosgene‐ and isocyanate‐free route for the synthesis of polyurethanes using (R)‐limonene as a bio‐based starting material. The synthesis of the cyclic limonene‐based carbamate monomer LU is achieved in high yields using dimethyl carbonate as a sustainable, less hazardous phosgene surrogate and is verified by NMR, SC‐XRD, ESI‐MS ...
Jonas Futter   +4 more
wiley   +1 more source

Optically Active Sulfoxides from 2(5H)-Furanone and Monoterpene Alcohols: Synthesis, Structure, and Antibacterial Activity

open access: yesУчёные записки Казанского университета: Серия Естественные науки
A series of optically active 5(S)-(l-bornyloxy)- and 5(S)-(l-menthyloxy)-2(5H)-furanones with an arylthio group at the C(4) position of the γ-lactone ring was synthesized and studied for its oxidation reactions with various reagents. Novel 2(5H)-furanone
A. M. Khabibrakhmanova   +7 more
doaj   +1 more source

Ruthenium Catalyzed Ortho‐Arylation Reaction of Benzoic Acids with Arylthianthrenium Salts

open access: yesAngewandte Chemie International Edition, EarlyView.
A catalytic ortho‐arylation method has been developed to convert arylthianthrenium salts into carboxylate‐functionalized biaryls, which can be removed in situ or used for further derivatization. This reaction is broadly applicable to (hetero)arenecarboxylic acids, with excellent functional group compatibility and orthogonality to cross‐couplings ...
Kaiping Wang   +9 more
wiley   +1 more source

Constituintes químicos de Vernonia scorpioides (Lam) Pers. (Asteraceae) Chemical constituents of Vernonia scorpioides (Lam) Pers. (Asteraceae)

open access: yesQuímica Nova, 2013
The chemical investigation of hexane and ethanol extracts from the aerial parts of Vernonia scorpioides resulted in the isolation and characterization of a new polyacetylene lactone, rel-4-dihydro-4β-hydroxy-5a-octa-2,4,6-triynyl-furan-2-(5H)-one ...
Adalva Lopes Machado   +8 more
doaj  

Changes in the Chemical Composition of Plum Distillate During Maturation with Oak Chips under Different Conditions

open access: yesFood Technology and Biotechnology, 2017
This study investigates the effect of ageing on the qualitative and quantitative composition of plum distillate in contact with oak wood chips. Maturation was performed with lightly toasted French oak (Quercus sessiflora and Quercus robur) chips or oak ...
Maria Balcerek   +4 more
doaj   +1 more source

Fe-MoS$_2$ nanoenzyme with photothermal enhanced enzyme activity for glucose colorimetric detection [PDF]

open access: yesarXiv
With the development of nanotechnology, it has been discovered that some nanomaterials have the activity of mimicking enzymes. This type of inorganic nanomaterial with characteristics similar to natural enzymes is called nanoenzyme. Compared with natural enzymes, nanoenzymes have advantages such as low deactivation, good stability, low production and ...
arxiv  

Biodegradable Polyesteramide Films for Pervaporative Dehydration of Isopropanol–Water

open access: yesJournal of Applied Polymer Science, EarlyView.
ABSTRACT Polyesteramides are biodegradable polymers possessing good mechanical properties with potential applicability in membrane separations. In this work, polymer films from ε‐caprolactam and ε‐caprolactone‐based polyesteramides were prepared at a ratio of monomer units set so that the resulting copolymer had a low crystalline phase content.
Marie Kolářová   +3 more
wiley   +1 more source

Factors Controlling Diastereoselectivity and Reactivity in the Catalytic Aerobic Carbooxygenation of (E)‐2‐Fluoro‐3‐aryl‐allyl Nitroacetates

open access: yesChemistry – An Asian Journal, EarlyView.
Experimental and computational methods reveal unique diastereoconvergency in radical‐based catalytic aerobic carbooxygenation of 2‐fluoro‐3‐aryl‐allyl nitroacetates. Both (E)‐ and (Z)‐isomers are converted into α,α,β,β‐tetrasubstituted γ‐lactones with high syn‐selectivity, even without E/Z isomerization of the alkene unit.
Yanzong Lyu   +4 more
wiley   +1 more source

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