Results 91 to 100 of about 21,344 (285)

Asararenes - A family of large aromatic macrocycles [PDF]

open access: yes, 2013
We announce the establishment of a new family of macrocycles - the asararenes, which are based on para-methylene linked "asarol methyl ether" (1,2,4,5-tetramethoxybenzene) units.
Sarjeant, Amy A.   +6 more
core   +1 more source

Tunable Oxygen Connectivity in Carbaporphyrinoid Polymers on Metal Surfaces

open access: yesAngewandte Chemie, EarlyView.
Hydroxyl‐functionalized dicarbaporphyrinoid polymers synthesized on Au(111) enable tunable oxygen‐mediated connectivity under UHV conditions. Thermal activation yields one‐dimensional hydroxyl‐terminated polymers that can selectively evolve into either covalently‐linked dibenzo‐p‐dioxane architectures through intermolecular C–O–C coupling or two‐fold ...
Alberto Martínez‐Bajo   +14 more
wiley   +2 more sources

Quartz Microbalance Sensor for the Detection of Acrylamide

open access: yesSensors, 2004
: Several macrocycles of the Hunter-Vögtle type have been identified as superior host compounds for the detection of small amounts of acrylamide. When coated onto the surface of a quartz microbalance, these compounds serve as highly sensitive and ...
Christoph A. Schalley   +4 more
doaj   +1 more source

One-Pot Formation of Aromatic Tetraurea Macrocycles [PDF]

open access: yes, 2016
Treating derivatives of m-phenylenediamine having different electron-richness and reactivities with triphosgene in the presence of triethylamine led to aromatic tetraurea macrocycles in high yields.
Ting Hu (110925)   +3 more
core   +1 more source

Reversible−Irreversible Approach to Schiff Base Macrocycles:  Access to Isomeric Macrocycles with Multiple Salphen Pockets [PDF]

open access: yes, 2016
We have developed methodology for the formation of a new family of metal-free Schiff base macrocycles utilizing the differential exchange rates of aldimines and ketimines.
Jian Jiang (566504)   +4 more
core   +3 more sources

Recent Advances in the Synthesis and Applications of Nitrogen-Containing Macrocyclic Arenes

open access: yesMolecules
Macrocyclic arenes are rich-electron macrocycles bridged by methylene or methyl groups from aromatic rings substituted by hydroxyl or alkoxy groups. It has attracted great interest in host–guest chemistry and supramolecular self-assembly due to its clear
Jianhang Hu, Wanhua Wu, Cheng Yang
doaj   +1 more source

De novo macrolide–glycolipid macrolactone hybrids: Synthesis, structure and antibiotic activity of carbohydrate-fused macrocycles

open access: yesBeilstein Journal of Organic Chemistry, 2014
Natural product-like macrocycles were designed as potential antibacterial compounds. The macrocycles featured a D-glucose unit fused into a 12- or 13-member macrolactone.
Richard T. Desmond   +5 more
doaj   +1 more source

Crystal structure of the N-benzyloxycarbonyl-Alanyl-Phenylalanyl-methyl ester: the importance of the H-bonding pattern [PDF]

open access: yes, 2011
Large crystals of the methyl ester of the N-a-benzyloxycarbonyl protected Ala-Phe dipeptide (Z-AF-OMe) were obtained after the very slow evaporation of a solution of the corresponding carboxylic acid (Z-AF-OH) in methanol containing an excess of HCl. The
Bolte, Michael   +9 more
core   +1 more source

A membrane permeability database for nonpeptidic macrocycles

open access: yesScientific Data
The process of developing new drugs is arduous and costly, particularly for targets classified as “difficult-to-drug.” Macrocycles show a particular ability to modulate difficult-to-drug targets, including protein-protein interactions, while still ...
Qiushi Feng   +3 more
doaj   +1 more source

High-Efficiency Non-Thermal Plasma Synthesis of Imine Macrocycles [PDF]

open access: yes
Macrocycles are candidates for wide-ranging applications, yet their synthesis can be low-yielding, poorly reproducible, and resource-intensive, limiting their use.
Timothy L, Easun   +4 more
core   +1 more source

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