Results 81 to 90 of about 21,344 (285)
Macrocycles, Catenanes and Rotaxanes [PDF]
, 2021 Inspired by the myriad enzymes found in living organisms, supramolecular chemists have investigated the cavities of both macrocycles and the related interlocked molecules catenanes and rotaxanes as catalytic and non-catalytic sites of chemical reactions.
Evans, Nicholas H.
core
A Multi‐Stimuli Transformational Network of Benzil‐Based Pd(II) Assemblies
Angewandte Chemie, EarlyView.Incorporation of a flexible and chemically reactive benzil backbone into the ligand structure allows it to access multiple conformations, enabling the formation of diverse homo‐ and heteroleptic Pd(II) assemblies with different nuclearities and topologies.
Zhiwei Zeng +5 more
wiley +2 more sources
Recent advances in chirality sensing/recognition using supramolecular macrocycles
Supramolecular MaterialsChiral sensing is crucial for understanding and controlling the biological activity of chiral molecule such as carbohydrates, amino acids, and proteins.
Chunhong Liu +4 more
doaj +1 more source
Synthesis of Spiroligomer-Containing Macrocycles [PDF]
, 2015 We demonstrate the synthesis and characterization of the solution conformations of a collection of functionalized spiroligomer-based macrocycles. These macrocycles contain 14 independently controllable stereocenters and four independently controllable ...
Christian E. Schafmeister (127045) +1 more
core +1 more source
Rapidly Diversifying Hydrogen‐Bonded Organic Frameworks With Permanent Porosity
Angewandte Chemie, EarlyView.This article reviews diversifying hydrogen‐bonded organic frameworks (HOFs) with permanent porosity reported over the past 15 years, based on the molecular structures of their constituent tectons. Furthermore, several distinctive aspects and concepts are described, such as permanent porosity, isostructural (isoreticular) HOFs, and multicomponent mixed ...
Taito Hashimoto, Ichiro Hisaki
wiley +2 more sources
New Cleft-like Molecules and Macrocycles from Phosphonate Substituted Spirobisindanol
Molecules, 2008 We have synthetized medium-sized cyclophanes and macrocycles containingphosphonic groups, directly linked to the aromatic rings of the phanes or as pendant arms,for use as specific receptors for the selective complexation of neutral guests or ...
Paolo Finocchiaro +2 more
doaj +1 more source
42-and 46-membered phosphorus-based macrocycles [PDF]
, 2007 42- and 46-Membered phosphorus-based macrocycles were obtained in a [2+2] condensation of PhP(O)[N(Me)NH2]2 with dialdehydes. These macrocycles were isolated in a pure form after preparative thin layer chromatography and were characterized by ...
Pandian, Balasubramanian Murugesa +3 more
core +1 more source
Schiff base macrocycles containing pyrroles and pyrazoles [PDF]
, 2008 A double nucleophilic substitution reaction of 3,5-bis(chloromethyl)pyrazole with pyrroles generates a novel pyrrole-pyrazole hybrid building block, the pyrazole analogue to tripyrrane.
Katsiaouni, Stamatia +4 more
core +1 more source
Force‐Induced Control of Circularly Polarized Luminescence With Rotaxane Architecture
Angewandte Chemie, EarlyView.Force‐induced reversible on/off switching of circularly polarized luminescence is achieved with a rotaxane‐based supramolecular mechanophore. The mechanophore, featuring a chiral helicene luminophore, is incorporated as a first network cross‐linker into a double‐network organogel.
Keigo Nonaka +10 more
wiley +2 more sources
Creating molecular macrocycles for anion recognition
Beilstein Journal of Organic Chemistry, 2016 The creation and functionality of new classes of macrocycles that are shape persistent and can bind anions is described. The genesis of triazolophane macrocycles emerges out of activity surrounding 1,2,3-triazoles made using click chemistry; and the same
Amar H. Flood
doaj +1 more source