Results 181 to 190 of about 21,344 (285)

Dynamic Polydisulfide Latex via Emulsion Ring‐Opening Polymerization of Cyclodisulfides

Journal of Polymer Science, EarlyView.
A polydisulfide latex with a high molar mass was achieved by emulsion polymerization process starting from a dithiol. The mechanism reveals an entropy‐driven ring‐opening polymerization involving disulfide macrocycle intermediates. The polydisulfide particles can be degraded by thiol‐disulfide exchange, and the disulfide fragments can be reengaged in a
Sandric Afonso, Pierre‐Louis Quentin, Marc Schmutz, Cécile Joyeux, Cuong Minh Quoc Le, Abraham Chemtob   +5 more
wiley   +1 more source

Targeting the H/KRAS α4-β6-α5 Allosteric Lobe with Macrocyclic Peptides. [PDF]

ACS Med Chem Lett
Tran K, Lavoie H, Wahhab A, Garrido D, Jo CH, Poupart MA, Arya T, Beautrait A, Killoran R, Dicaire-Leduc C, Bonneil É, Osborne M, Schuetz DA, Shaikh F, Thibault P, Smith MJ, Marinier A, Therrien M.   +17 more
europepmc   +1 more source

The continuing significance of chiral agrochemicals

Pest Management Science, Volume 81, Issue 4, Page 1697-1716, April 2025.
In the time frame 2018–2023, around 43% of the 35 chiral agrochemicals introduced to the market (herbicides, fungicides, insecticides, acaricides, and nematicides) contain one or more stereogenic centers in the molecule, and almost 69% of them have been marketed as racemic mixtures of enantiomers or stereoisomers.
Peter Jeschke
wiley   +1 more source

Macrocyclization and reaction of macrocyclic enolates

, 1992
openaire   +1 more source

Dynamic Covalent Platform for Chiroptically Tunable Figure-Eight Macrocycles from Preorganized Alkaloidal Scaffolds. [PDF]

JACS Au
Murakami S, Honda T, Fushiki T, Yoshida S, Sato S, Toriumi N, Uchiyama M, Oguri H.   +7 more
europepmc   +1 more source

Electrochemical investigation of radical‐radical recognition in viologen‐based ditopic structures

Responsive Materials, EarlyView.
The so‐called “blue box” is one of the most studied macrocycles. Yet, functionalized macrocycles of this type are rarely investigated. This work describes the radical‐radical recognition properties of ditopic structures, including functionalized blue‐box macrocycles.
Ahmad Bachir, Fabiana Ciocchetti, Caterina Baccini, Sayed Suliman Shah, Andrea Secchi, Cristian Pezzato, Giulio Ragazzon   +6 more
wiley   +1 more source

Synthesis of bacteriochlorophyll <i>a</i>. [PDF]

Chem Sci
Chung DTM, Nguyen KC, Liu Y, Lindsey JS.
europepmc   +1 more source

Outer‐Sphere Tuning of Synthetic Iron–Sulfur Clusters Within Nanoscale Cage Frameworks

Small, EarlyView.
Noncovalent encapsulation of a synthetic iron–sulfur cluster within hydrophobic, naphthalenediimide (NDI)‐paneled cages is shown to lead to dramatic changes in the electronic structure and covalency of the Fe─S core. ABSTRACT As atomic‐scale archetypes for multi‐electron transfer, iron–sulfur clusters are compelling candidates for the design of redox ...
Rupal Baliyan, Shelby T. Davis, Jan‐Niklas Boyn, Gwendolyn A. Bailey   +3 more
wiley   +1 more source

Carbene-catalytic enantioselective synthesis of chiral macrocycles. [PDF]

Chem Sci
Yan H, Zhu Y, Yang G, Gu S.
europepmc   +1 more source

Polysulfide Immobilization and Sulfur Conversion Kinetics Promotion via a Tetrathiafulvalene–Crown Ether COF@Graphene Layer for High‐Rate Lithium–Sulfur Batteries

Small, EarlyView.
A polysulfide‐regulating covalent organic framework (TUS‐44) integrating tetrathiafulvalene and crown‐ether linkers forms an electron‐delocalized, ion‐coordinative network that synergistically mediates Li–S redox chemistry. When interfaced with graphene, the TUS‐44@G layer functions as a catalytic and chemisorptive interface, enabling efficient ...
Kai Sun, Tsukasa Irie, Samim Reza, Kohki Sasaki, Mika Nozaki, Tokuhisa Kawawaki, Yujun Fu, Dequan Liu, Ranjit Thapa, Saikat Das, Deyan He, Yuichi Negishi   +11 more
wiley   +1 more source