Results 1 to 10 of about 5,053 (210)
Synthesis of chiral malonates by α-alkylation of 2,2-diphenylethyl tert-butyl malonates via enantioselective phase-transfer catalysis [PDF]
Frontiers in Chemistry, 2023 An efficient synthetic approach for chiral malonates was established via enantioselective phase transfer catalysis. The α-alkylation of 2,2-diphenylethyl tert-butyl α-methylmalonates with (S,S)-3,4,5-trifluorophenyl-NAS bromide as a phase-transfer ...
Zhibin Guo +5 more
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Synthesis and Anti-TMV Activity of Dialkyl/dibenzyl 2-((6-Substituted-benzo[d]thiazol-2-ylamino)(benzofuran-2-yl)methyl) Malonates [PDF]
Molecules, 2013 Starting from benzofuran-2-methanal, 6-substituted benzothiazole-2-amines and malonic esters, sixteen title compounds were designed and synthesized seeking to introduce anti-TMV activity.
Meichuan Li +8 more
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Dimerization/Elimination of β-Styrylmalonates under Action of TiCl4 [PDF]
Molecules, 2022 A new type of dimerization of dimethyl (β-styryl)malonates in the presence of TiCl4 accompanied by elimination of a methanol molecule was discovered.
D. D. Borisov +4 more
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Melaminium hydrogen malonate [PDF]
Acta Crystallographica Section E Structure Reports Online, 2012 The melaminium (2,4,6-triamino-1,3,5-triazin-1-ium) cation in the title compound, C3H7N6+·C3H3O4−, is essentially planar, with a r.m.s. deviation of the non-H atoms of 0.0085 Å. Extensive hydrogen bonding of the types N—H...N and N—H...O between cations and cations and between cations and hydrogen malonate (2-carboxyethanoate) anions leads to the ...
Barbara Froschauer, Matthias Weil
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Molbank, 2023 This paper presents the discovery and development of antifungal agents against Fusarium oxysporum (Fox), a devastating plant pathogen. Diethyl 2-((arylamino)methylene)malonates (DAMMs) were formed as side-products during the synthesis of polysubstituted ...
Willy-Fernando Cely-Veloza +2 more
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Probing the Binding Requirements of Modified Nucleosides with the DNA Nuclease SNM1A
Molecules, 2021 SNM1A is a nuclease that is implicated in DNA interstrand crosslink repair and, as such, its inhibition is of interest for overcoming resistance to chemotherapeutic crosslinking agents.
Eva-Maria Dürr, Joanna F. McGouran
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Malonates in Cyclocondensation Reactions
Molecules, 2001 The use of malonates such as diethyl malonates 9, (chlorocarbonyl)ketenes 15 and bis(2,4,6-trichlorophenyl) malonates 18 as reagents for cyclocondensation with 1,3-dinucleophiles to give six-membered heterocycles is described.
Thomas Kappe +4 more
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Effect of Microwaves in the Chiral Switching Asymmetric Michael Reaction
Molecules, 2003 Highly enantioselective Michael reactions of malonates with cyclic enones are achieved in remarkably less time under microwave irradiation using newly developed heterobimetallic catalysts.
S. Velmathi, S. Narasimhan
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Electrochemical Perspective on Hematite–Malonate Interactions
Colloids and Interfaces, 2021 Organic matter (OM) interactions with minerals are essential in OM preservation against decomposition in the environment. Here, by combining potentiometric and electrophoretic measurements, we probed the mode of coordination and the role of pH-dependent ...
Karolina Kędra +6 more
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The Allylic Alkylation of Ketone Enolates
ChemistryOpen, 2020 The palladium‐catalyzed allylic alkylation of non‐stabilized ketone enolates was thought for a long time to be not as efficient as the analogous reactions of stabilized enolates, e. g. of malonates and β‐ketoesters.
Dr. Lukas Junk, Prof. Dr. Uli Kazmaier
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