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Determination of masked mycotoxins using HPLC–tandem mass spectrometry
Franz Berthiller+6 more
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Masked Mycotoxins and Mycotoxin Derivatives in Food: The Hidden Menace
2009Conjugated or masked mycotoxins first came to attention in the mid-1980s, mainly from clinical observations on animals affected by mycotoxicoses fed with apparently low-level mycotoxin-contaminated feed. The unexpected toxicity was attributed to the presence of conjugated forms of mycotoxins, possibly generated by the plant metabolism, which were ...
Stefano Sforza+4 more
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Chapter 1. Introduction to Masked Mycotoxins
2015Mycotoxins are toxic, secondary metabolites of moulds. They are produced by filamentous fungi on almost every agricultural commodity worldwide. After the infection of crop plants, mycotoxins are modified by plant enzymes and often conjugated to more polar substances, like sugars.
Berthiller F.+2 more
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Sterigmatocystin-a Masked Potent Carcinogenic Mycotoxin
Journal of Toxicology: Toxin Reviews, 1983AbstractSterigmatocystin (stg), a related compound of aflatoxin B1 (af B1) is a secondary metabolite of a wide variety of fungi species.Stg is a compound in which a substituted anthraquinone is fused to the bisdihydrofuran ring. An unsaturated 2, 3 bond in the bis-dihydrofuran ring is closely related to the biological activities of stg.
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Zearalenone-16-O-glucoside: A New Masked Mycotoxin
Journal of Agricultural and Food Chemistry, 2014This paper reports the identification of a barley UDP-glucosyltransferase, HvUGT14077, which is able to convert the estrogenic Fusarium mycotoxin zearalenone into a near-equimolar mixture of the known masked mycotoxin zearalenone-14-O-β-glucoside and a new glucose conjugate, zearalenone-16-O-β-glucoside. Biocatalytical production using engineered yeast
Elisabeth Varga+8 more
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Journal of Chromatography A, 2012
Mycotoxins are secondary metabolites produced by fungi that can contaminate a wide range of food and feed commodities and that are harmful to humans for their poisonous and toxic effects. An increasing amount of data have been accumulated in the last years, showing that mycotoxins may also occur in modified forms originating by plant, fungi or animal ...
CIRLINI, Martina+2 more
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Mycotoxins are secondary metabolites produced by fungi that can contaminate a wide range of food and feed commodities and that are harmful to humans for their poisonous and toxic effects. An increasing amount of data have been accumulated in the last years, showing that mycotoxins may also occur in modified forms originating by plant, fungi or animal ...
CIRLINI, Martina+2 more
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Cleavage of Zearalenone‐Glycoside, a “Masked” Mycotoxin, during Digestion in Swine
Journal of Veterinary Medicine, Series B, 1990SummaryComparative analyses of cereal samples pretreated with or without β‐glucosidase indicate the presence of zearalenone‐glycoside. To examine the stability of zearalenone‐glycoside during digestion, mixed feed was artificially contaminated with synthesized zearalenone‐4‐β‐D‐glucopyranoside (395 μg/kg) and fed to a pig over a period of 14 days.
G. Plank+5 more
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Masked Mycotoxins Are Efficiently Hydrolyzed by Human Colonic Microbiota Releasing Their Aglycones
Chemical Research in Toxicology, 2013Fusarium mycotoxins are secondary metabolites produced by Fusarium spp. in cereals. Among them, deoxynivalenol (DON) and zearalenone (ZEN) are widespread worldwide contaminants of cereal commodities and are ranked as the most important chronic dietary risk factors.
Dall'Erta A.+5 more
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A systematic review of plant-conjugated masked mycotoxins: Occurrence, toxicology, and metabolism
Critical Reviews in Food Science and Nutrition, 2019Masked mycotoxins are biologically modified phase II metabolites formed by plant defense mechanisms through glucosylation catalyzed by uridine diphosphate -glucosyltransferases. Most of the current reports focus on the occurrence of masked mycotoxins in Europe, America, Africa, and cover other geographic regions, e.g. China and Japan.
Zhiqi Zhang+7 more
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Environmental Toxicology and Pharmacology, 2015
The existing hazard of joint mycotoxin exposure of animals/humans and the significance of masked mycotoxins in foods or feeds and their respective contributions to the development of some food born mycotoxicoses is briefly reviewed. The importance of joint mycotoxin interaction in the complex etiology of some foodborn mycotoxicoses is covered in depth.
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The existing hazard of joint mycotoxin exposure of animals/humans and the significance of masked mycotoxins in foods or feeds and their respective contributions to the development of some food born mycotoxicoses is briefly reviewed. The importance of joint mycotoxin interaction in the complex etiology of some foodborn mycotoxicoses is covered in depth.
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