Results 81 to 90 of about 82,293 (280)

Effect of Regiochemistry on Doping and Thermoelectric Properties of n‐Doped Fullerene Derivatives

Advanced Electronic Materials, EarlyView.
Three fullerene derivatives doubly substituted with diethylene glycol chains (PDEG‐2) is presented. The different regiochemistry significantly affects the crystallinity and consequently the dielectric properties, electronic transport, and doping efficiency. By striking a balance between compatibility with the molecular dopant N‐DMBI and crystallinity a
Federico Ferrari, Sylvia Rousseva, Diego Rosas Villalva, Ewout Kessels, Jan C. Hummelen, Derya Baran, Ryan Chiechi, L. Jan Anton Koster   +7 more
wiley   +1 more source

Dual Chemical Looping/Catalytic Process for Alkylation of Benzene With Ethane and Propane Yielding Ethylbenzene and Cumene Over Copper‐Containing Mordenite

Angewandte Chemie, EarlyView.
We report a dual chemical looping/catalytic process coupling alkane dehydrogenation with aromatic alkylation over Cu‐mordenite, yielding up to 25% alkylated aromatics with >95% selectivity per cycle. In situ NMR, FTIR spectroscopy, and DFT show alkylation proceeds via a π‐bound Cu(I)–olefin intermediate and Brønsted acid sites.
Florent J. Dubray, Yu‐Hsun Wang, Mikalai A. Artsiusheuski, Jiawei Guo, Rene Verel, Ambarish Kulkarni, Jeroen A. van Bokhoven, Vitaly L. Sushkevich   +7 more
wiley   +2 more sources

Neuromorphic Motor Control with Electrolyte‐Gated Organic Synaptic Transistors

Advanced Electronic Materials, EarlyView.
Electrolyte‐gated organic synaptic transistor (EGOST)‐based neuromorphic motor control systems integrate sensing, processing, and actuation by mimicking biological synapses. With advantages such as low power consumption, tunable synaptic plasticity, and mechanical flexibility, they are emerging as next‐generation core technologies for real‐time ...
Sung‐Hwan Kim, Ju‐Hyeok Yun, Hea‐Lim Park, Sin‐Hyung Lee   +3 more
wiley   +1 more source

Tetraaza[7]–[15]helicenes Synthesized by Two‐Step Strategy: Length‐Controlled Chiral π‐Systems Exhibiting Amplified Circularly Polarized Luminescence

Angewandte Chemie, EarlyView.
A modular two‐step strategy provides tetraaza[n]helicenes (n = 7–15) as a homologous series with tunable photophysical and chiroptical properties. Extension beyond n = 11 induces pronounced through‐space π–π interactions, narrowing the energy gap and amplifying circularly polarized luminescence.
Takashi Otani, Yuchen Wu, Kohei Ueda, Yuki Ikeda, Yuna Tada, Natsuna Kinoshita, Takanori Shibata   +6 more
wiley   +2 more sources

A Solution to protodeborylation problem: weak base-promoted direct cross-coupling of naphthalene-1,8-diaminato-substituted arylboron compounds [PDF]

, 2023
Kazuki Tomota, Jialun Li, Hideya Tanaka, Masaaki Nakamoto, Takumi Tsushima, Hiroto Yoshida   +5 more
openalex   +1 more source

Aqueous Zinc‐Based Batteries: Active Materials, Device Design, and Future Perspectives

Advanced Energy Materials, EarlyView.
This review conducts a comprehensive analysis of aqueous zinc‐based batteries (AZBs) based on their intrinsic mechanisms, including redox reactions, ion intercalation reactions, alloying reactions, electrochemical double‐layer reactions, and mixed mechanisms, systematically discussing recent advancements in each type of AZBs.
Yan Ran, Fang Dong, Shuhui Sun, Yong Lei
wiley   +1 more source

Construction of a Two‐Dimensional Molecular Slab with a π‐Extended Hexaarylbenzene Molecule

Angewandte Chemie, EarlyView.
A 3D shape‐persistent molecule with a hexaarylbenzene structure consisting of six naphthothiophene diimide units enables the formation of a 2D molecular slab in the solid state, leading to a 2D interactive electronic structure suitable for application to n‐type organic field‐effect transistors.
Haruki Sanematsu, Rukiya Matsidik, Barun Dhara, Kazuo Takimiya   +3 more
wiley   +2 more sources

AI‐Enhanced Surface‐Enhanced Raman Scattering for Accurate and Sensitive Biomedical Sensing

Advanced Intelligent Discovery, EarlyView.
AI‐SERS advances spectral interpretation with greater precision and speed, enhancing molecular detection, biomedical analysis, and imaging. This review explores its essential contributions to biofluid analysis, disease identification, therapeutic agent evaluation, and high‐resolution biomedical imaging, aiding diagnostic decision‐making.
Seungki Lee, Rowoon Park, Ho Sang Jung
wiley   +1 more source

Host‐Guest Doping Enables Room Temperature Phosphorescence from Triarylboranes

Angewandte Chemie, EarlyView.
While pure triarylboranes show RTP in annealed PMMA films, they do not in crystalline form, contrary to our previous report. However, crystalline host‐guest triarylborane systems show persistent afterglow up to 8 s even at 1 ppb guest loading. Computations identify triplet‐triplet energy transfer as the mechanism governing this efficient RTP.
Zhu Wu, Katrina Bergmann, Todd B. Marder, Bin Liu, Zachary M. Hudson   +4 more
wiley   +2 more sources

Clar covering polynomials of polycyclic aromatic hydrocarbons

AIMS Mathematics
Polycyclic aromatic hydrocarbon (PAH) is a compound composed of carbon and hydrogen atoms. Chemically, large PAHs contain at least two benzene rings and exist in a linear, cluster, or angular arrangement.
Peirong Li , Hong Bian, Haizheng Yu, Yan Dou   +3 more
doaj   +1 more source