Results 31 to 40 of about 120,160 (335)

Crystal structure of ruthenocenecarbonitrile

Acta Crystallographica Section E: Crystallographic Communications, 2015
The molecular structure of ruthenocenecarbonitrile, [Ru(η5-C5H4C[triple-bond]N)(η5-C5H5)], exhibits point group symmetry m, with the mirror plane bisecting the molecule through the C[triple-bond]N substituent.
Frank Strehler, Marcus Korb, Heinrich Lang   +2 more
doaj   +1 more source

Hepatotoxicity of Two Progoitrin-Derived Nitriles in New Zealand White Rabbits

Toxins, 2020
Cattle occasionally develop brassica-associated liver disease (BALD) and photosensitisation when grazing turnip or swede (Brassica spp.) forage crops. The liver toxin in these brassica varieties has yet to be discovered.
Mark Grey Collett, Zoe Maree Matthews, Kathleen Henry Parton   +2 more
doaj   +1 more source

Seasonal Variation of Glucosinolate Hydrolysis Products in Commercial White and Red Cabbages (Brassica oleracea var. capitata)

Foods, 2020
Brassica vegetables contain glucosinolates, which are well-known for their potential to form health-promoting isothiocyanates. Among those crucifers, white and red cabbage are commonly consumed vegetables, exhibiting different glucosinolate and ...
Nicole S. Wermter, Sascha Rohn, Franziska S. Hanschen   +2 more
doaj   +1 more source

Nitrile ylides: allenic and propargylic structures from pyrazinylnitrenes. Experimental and theoretical characterization [PDF]

, 2014
Matrix photolysis of 2-pyrazinyl azides/tetrazolo[1,5-a]pyrazines generates nitrile ylides 15 via pyrazinylnitrenes 13 and triazacycloheptatetraenes 14.
Addicott, Chris, Baraille, Isabelle, Bednarek, Pawel, Begue, Didier, Burgard, Riko, Guille, Emilie, Wentrup, Curt   +6 more
core   +2 more sources

Functional Expression and Characterization of a Panel of Cobalt and Iron-Dependent Nitrile Hydratases

Molecules, 2020
Nitrile hydratases (NHase) catalyze the hydration of nitriles to the corresponding amides. We report on the heterologous expression of various nitrile hydratases.
Birgit Grill, Maximilian Glänzer, Helmut Schwab, Kerstin Steiner, Daniel Pienaar, Dean Brady, Kai Donsbach, Margit Winkler   +7 more
doaj   +1 more source

The Active Site Sulfenic Acid Ligand in Nitrile Hydratases Can Function as a Nucleophile [PDF]

, 2014
Nitrile hydratase (NHase) catalyzes the hydration of nitriles to their corresponding commercially valuable amides at ambient temperatures and physiological pH.
Holz, Richard C., Liu, Dali, Martinez, Salette, Sanishvili, Ruslan, Wu, Rui   +4 more
core   +3 more sources

Determination of Phenethyl Isothiocyanate, Erucin, Iberverin, and Erucin Nitrile Concentrations in Healthy and Pieris rapae-Infected Broccoli Tissues Using Gas Chromatography-Mass Spectrometry

Chemosensors
Cruciferous vegetables (Brassicaceae family) are a rich source of phytochemicals, in particular glucosinolates (GLS) and their hydrolysis products, isothiocyanates and nitriles.
Irene-Dimitra Mesimeri, Panagiota-Kyriaki Revelou, Violetta Constantinou-Kokotou, Maroula G. Kokotou   +3 more
doaj   +1 more source

Swelling Properties of Nitrile-butadiene Rubber with Different Acrylonitrile Content in Isopropyl Nitrate

Chemical Engineering Transactions, 2017
Nitrile-butadiene rubber is the sealing material of isopropyl nitrate; however, leakage or vaporization phenomena frequently occur. In order to analyze the causes of leakage and volatilization and study on the various properties of nitrile-butadiene ...
Lili Wu, Yukui Ding, Jianwei Zhen, Qian Zhang, Siyang Chen   +4 more
doaj   +1 more source

Kinetic, Spectroscopic, and X-Ray Crystallographic Evidence for the Cooperative Mechanism of the Hydration of Nitriles Catalyzed by a Tetranuclear Ruthenium-μ-oxo-μ-hydroxo Complex [PDF]

, 2008
The tetranuclear ruthenium-oxo-hydroxo-hydride complex {[(PCy3)(CO)RuH]4(μ4-O)(μ3-OH)(μ2-OH)} (1) was found to be a highly cooperative catalyst for the nitrile hydration reaction. The cooperative mechanism of the hydration of benzonitrile was established
Lindeman, Sergey V., Yi, Chae S., Zeczycki, Tonya N.   +2 more
core   +1 more source

Cyclic Nitriles:  Diastereoselective Alkylations [PDF]

The Journal of Organic Chemistry, 2005
AbstractFor Abstract see ChemInform Abstract in Full Text.
Fraser F, Fleming, Subrahmanyam, Gudipati, Zhiyu, Zhang, Wang, Liu, Omar W, Steward   +4 more
openaire   +2 more sources