Molecules, 2020 Nitrile hydratases (NHase) catalyze the hydration of nitriles to the corresponding amides. We report on the heterologous expression of various nitrile hydratases.
Birgit Grill +7 more
doaj +1 more source
The Iron-Type Nitrile Hydratase Activator Protein Is A GTPase [PDF]
, 2017 The Fe-type nitrile hydratase activator protein from Rhodococcus equi TG328-2 (ReNHase TG328-2) was successfully expressed and purified. Sequence analysis and homology modeling suggest that it is a G3E P-loop guanosine triphosphatase (GTPase) within the ...
Bennett, Brian +3 more
core +1 more source
Hyperpolarization of Nitrile Compounds Using Signal Amplification by Reversible Exchange
Molecules, 2020 Signal Amplification by Reversible Exchange (SABRE), a hyperpolarization technique, has been harnessed as a powerful tool to achieve useful hyperpolarized materials by polarization transfer from parahydrogen.
Sarah Kim +6 more
doaj +1 more source
Analyzing the Catalytic Mechanism of the Fe-Type Nitrile Hydratase from \u3cem\u3eComamonas testosteroni\u3c/em\u3e Ni1 [PDF]
, 2008 In order to gain insight into the catalytic mechanism of Fe-type nitrile hydratases (NHase), the pH and temperature dependence of the kinetic parameters kcat, Km, and kcat/Km along with the solvent isotope effect were examined for the Fe-type NHase from ...
Holz, Richard C., Rao, Saroja
core +1 more source
2-Diphenylphosphanyl-4-pyridyl(dimethyl) amine as an effective ligand for the ruthenium(II) complex catalyzed homogeneous hydration of nitriles under neutral conditions [PDF]
, 2011 New homogeneous catalyst comprised of [Ru(methallyl)(2)(cod)] (cod = 1,5-cyclooctadiene) (1) and 2-diphenylphosphanyl-4-pyridyl(dimethyl) amine (2) is shown to efficiently catalyze the hydration of various nitriles under neutral conditions. The hydration
Akisanya +65 more
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Characterization of α-Nitrile Hydratase and Amidase of Rhodococcus aff. qingshengii from Indonesia
Hayati Journal of Biosciences, 2014 A study on biotransformation of acetonitrile using Gram-positive bacteria has been conducted. Two isolates of nitrile-degrading bacteria (strain 100A and 100D) were screened from sediments of a contaminated river in Cibinong, West Java.
AERMA HASTUTY +2 more
doaj +1 more source
Micellar electrokinetic capillary chromatography—Synchronous monitoring of substrate and products in the myrosinase catalysed hydrolysis of glucosinolates [PDF]
, 2006 A micellar electrokinetic capillary chromatography (MECC) method has been developed for monitoring the myrosinase catalysed hydrolysis of 2-hydroxy substituted glucosinolates and the simultaneous formation of the corresponding degradation products ...
Bellostas, Natalia +2 more
core +1 more source
Halogen Bonds Formed between Substituted Imidazoliums and N Bases of Varying N-Hybridization
Molecules, 2017 Heterodimers are constructed containing imidazolium and its halogen-substituted derivatives as Lewis acid. N in its sp3, sp2 and sp hybridizations is taken as the electron-donating base.
Steve Scheiner
doaj +1 more source
Unraveling the Catalytic Mechanism of Nitrile Hydratases [PDF]
, 2007 To elucidate a detailed catalytic mechanism for nitrile hydratases (NHases), the pH and temperature dependence of the kinetic constants kcat and Km for the cobalt-type NHase from Pseudonocardia thermophila JCM 3095 (PtNHase) were examined.
Holz, Richard C., Mitra, Sanghamitra
core +1 more source
X-ray structures of dinuclear copper(I) and polynuclear copper(II) complexes with the 2,4-bis(cyanamido)cyclobutane-1,3-dione dianion [PDF]
, 2006 From the 2,4-bis(cyanamido)cyclobutane-1,3-dione dianion (2,4-NCNsq2−), two copper complexes [Cu2(PPh3)4(PhCN)2(μ-2,4-NCNsq)] · PhCN (1) and [Cu(dien)(μ-2,4-NCNsq) · H2O]n (2) have been synthesized and characterized by IR and electronic absorption ...
Cortadellas, Olivier +4 more
core +2 more sources