Results 101 to 110 of about 2,940,757 (378)
Laser‐Induced Plasma Effects on Bond Breaking in High‐Density Polyethylene Pyrolysis
Advanced Materials Interfaces, EarlyView.This study introduces a novel application of Laser‐Induced Breakdown Spectroscopy (LIBS) for bond breaking in high‐density polyethylene (HDPE), an area previously unexplored in laser‐plastic interactions. For the first time, a numerical model has been developed to differentiate between photon‐induced and laser field‐induced plasma, demonstrating the ...
Rao Adeel Un Nabi +5 more
wiley +1 more source
Advanced Synthesis &Catalysis, EarlyView.Abstract The demonstrated light‐initiated addition of radicals formed on an active methylene group to styrene derivatives exhibits a product selectivity influenced by the presence of a protic solvent. Under protic conditions, the predominant products are branched compounds with the alkene moiety attached to the methylene group.
Małgorzata Pałyga +2 more
wiley +1 more source
Isoxazole derivatives as new nitric oxide elicitors in plants
Beilstein Journal of Organic Chemistry, 2017 Several 3,5-disubstituted isoxazoles were obtained in good yields by regiospecific 1,3-dipolar cycloaddition reactions between aromatic nitrile oxides, generated in situ from the corresponding hydroxyimidoyl chlorides, with non-symmetrical activated ...
Anca Oancea +9 more
doaj +1 more source
Functionalisation of Artemisinin and Its Ring-contracted Derivatives
Molecules, 2007 Isoxazoline analogues of artemisinin were obtained in low yield and low diastereoselectivity from the 1,3-dipolar cycloaddition of nitrile oxides. Alternatively, starting from the aldehyde 7, a number of transformations - Wittig reaction and reduction ...
Wim Dehaen +2 more
doaj +1 more source
Continuous Flow Technology Enabling Photochemistry
Advanced Synthesis &Catalysis, EarlyView.Abstract The merger of continuous flow technology and modern photochemistry has enabled countless applications showcasing new opportunities for chemical synthesis demonstrating improvements in selectivity, safety, sustainability and scalability. This focused review aims to highlight a selection of recently published case studies from academic and ...
Ruairi Crawford, Marcus Baumann
wiley +1 more source
Nitrogen Incorporation in CH_4-N_2 Photochemical Aerosol Produced by Far Ultraviolet Irradiation [PDF]
, 2012 Nitrile incorporation into Titan aerosol accompanying hydrocarbon chemistry is thought to be driven by extreme UV wavelengths (λ120 nm is presently unaccounted for in atmospheric photochemical models.
Jimenez, Jose L. +4 more
core
Advanced Synthesis &Catalysis, EarlyView.Abstract Pd‐catalyzed reactions are among the most straightforward and efficient methods to proficiently build Csp2‐Csp2 bonds. Nevertheless, thermal activation remains mandatory in most cases, which may decrease the compatibility with sensitive functional groups.
Jenifer Sharshonov +7 more
wiley +1 more source
A two-component polymeric optode membrane based on a multifunctional ionic liquid [PDF]
, 2011 This work details the use of a 2-component optode membrane which is capable of generating three distinct colours in the presence of Cu2+ and Co2+ ions.
Byrne, Robert +3 more
core +1 more source
Chemical Communications, 2011 Rapid, catalyst free, solid phase modification of DNA by strain promoted cyclooctyne-nitrile oxide click chemistry is reported; the reaction is characterised by mild conditions, occurring in an aqueous environment under atmospheric conditions at room ...
I. Singh, F. Heaney
semanticscholar +1 more source
Advanced Science, EarlyView.A comprehensive understanding of hydrogenases' structures and catalytic mechanisms is crucial to replicate and exceed their performance. Computational modeling has proven to be a powerful tool for elucidating the reduction chemistry of [FeFe]‐hydrogenases. This review overviews recent computational and experimental efforts, focusing on DFT calculations
Chang‐Ah Kim +4 more
wiley +1 more source