Results 111 to 120 of about 2,971,196 (335)

Acridine–Isoxazole and Acridine–Azirine Hybrids: Synthesis, Photochemical Transformations in the UV/Visible Radiation Boundary Region, and Anticancer Activity

Molecules
Easy-to-handle N-hydroxyacridinecarbimidoyl chloride hydrochlorides were synthesized as convenient nitrile oxide precursors in the preparation of 3-(acridin-9/2-yl)isoxazole derivatives via 1,3-dipolar cycloaddition with terminal alkynes, 1,1 ...
Ekaterina E. Galenko, Mikhail S. Novikov, Alexander S. Bunev, Alexander F. Khlebnikov   +3 more
doaj   +1 more source

Reactions of 5-Aroylmethylene-3-benzyl-4-oxo-2-thioxo-1,3-thiazolidines with Nitrile Oxides [PDF]

, 2001
Kamal A. Kandeel, Ahmed S. A. Youssef
openalex   +1 more source

Scalable Fabrication of Electrochemical Sensors Via Inkjet Printing of Functionalized Graphene for Pesticide Detection

Advanced Materials Technologies, EarlyView.
Inkjet printing enables uniform, reproducible, and stable deposition of nitrogen‐doped graphene acid (NGA) on screen‐printed electrodes, outperforming traditional drop‐casting. The resulting electrochemical sensor exhibits enhanced sensitivity, long‐term stability, and efficient imidacloprid detection.
Martin‐Alex Nalepa, Lueda Kulla, Petr Jakubec, Vítězslav Hrubý, David Panáček, Ivan Dědek, Majlinda Vasjari, Michal Otyepka   +7 more
wiley   +1 more source

Synthesis and Structure of Unsymmetrical Anthracenyl-Isoxazole Antitumor Agents Via the Diastereoselective Bromination of 3-(9′-Anthryl)-Isoxazole Esters

Crystals
In pursuit of unsymmetrical precursors for the novel series of anthracenyl-isoxazole amide (AIM) antitumor agents, a series of substituted anthracenes were subjected to bromination and re-aromatization in our study, during which we solved four single ...
Michael J. Campbell, Daniel A. Decato, Chun Li, Matthew J. Weaver, Nicholas R. Natale   +4 more
doaj   +1 more source

Synthesis of Chiral Isoxazoline Derivatives by Highly Diastereoface-Selective 1,3-Dipolar Cycloaddition of Nitrile Oxides Mediated by Magnesium Bromide and Ytterbium Trifluoromethanesulfonate [PDF]

, 2003
Hidetoshi Yamamoto, Sadaka Watanabe, Masayuki Hasegawa, Michihiko Noguchi, Shuji Kanemasa   +4 more
openalex   +1 more source

Applications of QSPR and Machine Learning in Molecular Photonics

Advanced Optical Materials, EarlyView.
Quantitative structureproperty relationships (QSPR) and machine learning (ML) are transforming photochemistry by enabling pre‐synthetic screening of photoactive molecules. This review outlines advances in data‐driven discovery of optical materials and functional dyes, identifies effective descriptors and models for photophysical processes, and provides
Andrey A. Buglak, Platon P. Chebotaev, Mikhail A. Filatov   +2 more
wiley   +1 more source

Influence of the Solvent on the stereoselectivity of 1,3-Dipolar cycloaddition of Nitrile Oxides on Several 4-Substituted 2-Cyclopentenones [PDF]

, 2003
G. ADEMBRI, M. Laura Paoli, Alessandro Sega   +2 more
openalex   +1 more source

Ruthenium‐Catalyzed Azide‐Selenoalkyne Cycloadditions: A Combined Synthetic–Computational Study into Reaction Scope, Mechanism, and Origins of Regioselectivity

Advanced Synthesis &Catalysis, EarlyView.
A ruthenium‐catalyzed azide–alkyne cycloaddition (RuAAC) reaction is reported for the synthesis of selenium‐substituted triazole products. Reaction regioselectivity is dependent on the identity of the non‐selenium substituent of the alkyne, which challenges the perceived understanding of RuAAC regioselectivity.
Frances E. Bugden, Andrew D. Bage, Ashima Bajaj, Bin Wang, Fiona J. Gibson, Henry Stone, Yingjian Xu, Frank De Proft, Mercedes Alonso, Mark D. Greenhalgh   +9 more
wiley   +1 more source

Cooperative Photocatalysis of 9,10‐Phenanthrenequinone and Sn(OTf)2 for Direct Mannich Reaction of Ethers via Hydrogen Atom Transfer Pathway

Advanced Synthesis &Catalysis, EarlyView.
A dual photocatalytic system of o‐PQ and Sn(OTf)2 enables visible light‐induced Mannich‐type addition of ethers to nitrones via Csp³–H activation. This oxidant‐free method offers broad scope and good yields. Mechanistic studies suggest that a photoexcited o‐PQ–Sn(II) complex mediates hydrogen atom transfer to form α‐oxy radicals for nitrone addition. A
Pradip Ramdas Thorve, Hun Young Kim, Kyungsoo Oh   +2 more
wiley   +1 more source

Fe‐Photocatalyzed Decarboxylative Giese‐Type Reaction of α‐N, O or S Carboxylic Acids: Insight into the Mechanism of the Radical Formation

Advanced Synthesis &Catalysis, EarlyView.
Electron‐deficient alkenes can be functionalized with α‐amino, α‐alkoxy and α‐alkylthio radicals formed by Fe‐photocatalyzed decarboxylation of the corresponding carboxylic acids. The reactions proceed under smooth ligandless conditions with inexpensive base and in the absence of oxidant. A mechanistic computational TD‐DFT study supports the occurrence
Fernando Pérez‐Maseda, María Martín, Jorge Labrador‐Santiago, Inés Corral, Diego J. Cárdenas   +4 more
wiley   +1 more source