Molecules, 2011 Studies on the synthesis of macrosphelide B via an intramolecular nitrile oxide-olefin cycloaddition (INOC) is described. In particular, an asymmetric INOC approach using phase transfer catalysts seems to be a potentially efficient and versatile ...
Seung-Mann Paek, Young-Ger Suh
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Syntheses of Isoxazoline-Based Amino Acids by Cycloaddition of Nitrile Oxides and Their Conversion into Highly Functionalized Bioactive Amino Acid Derivatives [PDF]
, 2012 The present account illustrates the syntheses of isoxazoline- based amino acids by the cycloaddition of 1,3-dipolar nitrile oxides to the C–C double bond of unsaturated amino acid derivatives, with focus on the regio- and stereoselectivities of the ...
Fülöp, Ferenc +2 more
core +3 more sources
Unveiling Hydrogen Bonding and Solvent Effects on Directed Nitrile Oxide [3 + 2] Cycloaddition Reactions: Selectivity of 2,2-Dimethylpropane Nitrile Oxide with Cyclopentenylbenzamide: An MEDT Study [PDF]
ACS OmegaSofiane Benmetir +6 more
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A new approach to heterocycle-modified steroids via nitrile oxide intermediates
ARKIVOC, 2008 Alexander V. Baranovsky +3 more
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Synthesis of Functionalized 4,5-Dihydroisoxazoles Decorated with the Dimethylphosphinoyl Group
Журнал органічної та фармацевтичної хімії, 2023 Aim. To synthesize a hybrid molecular platform incorporating dimethylphosphinoyl and 4,5-dihydroisoxazole moieties suitable for the creation of focused combinatorial libraries of compounds. Results and discussion.
Andrii V. Fedyk, Bohdan A. Chalyk
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, 2020 The reaction mechanisms of [3+2] cycloaddition (32CA) between the α,β-unsaturated selenoaldehyde with nitrone and nitrile oxide were investigated theoretically using the molecular electron density theory (MEDT). Selenoaldehyde has two unsaturations which
Haydar A. Mohammad-Salim +3 more
semanticscholar +1 more source
Reaction kinetics of CN + toluene and its implication on the productions of aromatic nitriles in the Taurus molecular cloud and Titan's atmosphere [PDF]
, 2023 Reactions between cyano radical and aromatic hydrocarbons are believed to be important pathways for the formation of aromatic nitriles in the interstellar medium (ISM) including those identified in the Taurus molecular cloud (TMC-1). Aromatic nitriles might participate in the formation of polycyclic aromatic nitrogen containing hydrocarbons (PANHs) in ...
arxiv +1 more source
A Weinreb Nitrile Oxide and Nitrone for Cycloaddition. [PDF]
ChemInform, 2004 AbstractFor Abstract see ChemInform Abstract in Full Text.
Richard W. Franck, Ajit K. Parhi
openaire +4 more sources
Metal Catalysis Acting on Nitriles in Early Earth Hydrothermal Systems
Life, 2023 Hydrothermal systems are areas in which heated fluids and organic molecules rush through basaltic material rich in metals and minerals. By studying malononitrile and acetonitrile, we examine the effects of metal and mineral nanoparticles on nitrile ...
Miranda Sturtz, Christopher House
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Synthesis of Spiroisoxazolines by 1,3-Dipolar Cycloaddition
Molecules, 1997 The cycloaddition of the chiral nitrile oxide 1 to 1-R-substituted 3,3-methylene-5,5-dimethyl-2-pyrrolidinones 2 (where R is H, n-butyl-, 1,1-dimethylethoxycarbonyl-, 1-methylethenyl- and acetyl-) proceeds regioselectively under the formation of ...
Peter Ertl +3 more
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