An Update: Enzymatic Synthesis for Industrial Applications
Supported by rapid technological advancements, biocatalytic applications have matured into a sustainable, scalable, and cost‐competitive alternatives to established chemical catalysis. This review presents the most recent examples of enzyme‐based solutions for the manufacturing of molecules with extended carbon‐carbon frameworks and multiple ...
Thomas Bayer+4 more
wiley +1 more source
Organo NHC catalyzed aqueous synthesis of 4β-isoxazole-podophyllotoxins: in vitro anticancer, caspase activation, tubulin polymerization inhibition and molecular docking studies. [PDF]
Nagavath R+5 more
europepmc +1 more source
Solution-phase synthesis of a diverse library of benzisoxazoles utilizing the [3 + 2] cycloaddition of in situ-generated nitrile oxides and arynes. [PDF]
Dubrovskiy AV+6 more
europepmc +1 more source
Unveiling Hydrogen Bonding and Solvent Effects on Directed Nitrile Oxide [3 + 2] Cycloaddition Reactions: Selectivity of 2,2-Dimethylpropane Nitrile Oxide with Cyclopentenylbenzamide: An MEDT Study. [PDF]
Benmetir S+6 more
europepmc +1 more source
New Insights into Nuclear Magnetic Resonance (NMR) Spectroscopy. [PDF]
Gerothanassis IP, Kupka T.
europepmc +1 more source
Synthesis of benzisoxazoles by the [3 + 2] cycloaddition of in situ generated nitrile oxides and arynes. [PDF]
Dubrovskiy AV, Larock RC.
europepmc +1 more source
α‐Keto acids, such as pyruvate and glyoxylate, may have been critical in generating reaction networks at the origins of life due to their facile carbon‐carbon bond formation and their hydrolytic stability. However, demonstrated prebiotic sources of these small α‐keto acids have been limited by conditions required for their production which are not ...
Louis M.P. Ter-Ovanessian+5 more
wiley +1 more source
Generation of reactive intermediates from the thermolysis of furoxans and related heterocycles [PDF]
Mitchell, William Robertson
core
ABSTRACT This study investigates and compares the thermal stability of two 6FDA‐based thermosetting polyimide formulations with varied amounts of internal crosslinkers. The baseline formulation is a commercially available polyimide with good resin transfer molding processability and a high glass transition temperature, Tg, in the range of 340°C–466°C ...
Valeri Ivanov Petkov+3 more
wiley +1 more source
Electron Donor-Acceptor Complex-Enabled Autoinductive Conversion of Acylnitromethanes to Acylnitrile Oxides in a Photochemical Machetti-De Sarlo Reaction: Synthesis of 5-Substituted 3-Acylisoxazoles. [PDF]
Arunkirirote P+5 more
europepmc +1 more source