Cu(OH)x-clay catalyst promoted synthesis of 4,5-dihydro-1,2,4-oxadiazole at room temperature
An easy and efficient scheme is described and designed for the preparation of 4,5-dihydro-1,2,4-oxadiazole using recyclable Cu(OH)x-clay heterogeneous catalyst at room temperature.
Dar Bashir Ahmad +3 more
doaj +1 more source
Asymmetric one-pot synthesis of cyclopropanes
Cycloaddition of the diazoalkanes to electron-deficient olefins (in situ) affords polysubstituted cyclopropanes in high yields (up to 85%). Deprotection of the ketal protecting group provided water-soluble cyclopropane-bearing carbohydrate in good yields.
Naoufel Ben Hamadi +2 more
doaj +1 more source
Взаимодействие (2-фторфенил)- и (4фторфенил)-(2-нитрометилциклопентил)метанона с фенилацетиленом [PDF]
В результате реакции 1,3-диполярного циклоприсоеднения фенилацетилена и нитрилоксидов, генерируемых из (2-фторфенил)или (4-фторфенил)-(2-нитрометилциклопентил)метанона под действием фенилизоцианата, осуществлен синтез соответствующих изоксазолов и ...
Антоневич, Инесса Петровна +2 more
core
Development of Simplified Heterocyclic Acetogenin Analogues as Potent and Selective Trypanosoma brucei Inhibitors [PDF]
This work was funded by the Leverhulme Trust (GJF), and the Wellcome Trust (TKS, WT 093228).Neglected tropical diseases caused by parasitic infections are an on-going and increasing concern and burden to human and animal health, having the most ...
Alali +28 more
core +2 more sources
Cycloaddition of Nitrile Oxides to Substituted Vinylphosphonates.
AbstractFor Abstract see ChemInform Abstract in Full Text.
Yong Ye +3 more
openaire +1 more source
Synthesis of novel chiral spiro-β-lactams from nitrile oxides and 6-(Z)-(benzoylmethylene)penicillanate: batch, microwave-induced and continuous flow methodologies. [PDF]
Alves AJS +2 more
europepmc +1 more source
Cycloaddition reactions of nitrosoalkenes, azoalkenes and nitrile oxides mediated by hydrotalcite [PDF]
Mg:Al 3:1 hydrotalcite (Ht), used in catalytic quantities, promotes the generation of nitrosoalkenes, azoalkenes and nitrile oxides. These can be intercepted in situ by heterocycles and olefins in [4+2] and [3+2] cycloaddition reactions, producing ...
Lemos, A., Lourenço, J. P.
core
Development of covalent triazine frameworks as heterogeneous catalytic supports [PDF]
Covalent triazine frameworks (CTFs) are established as an emerging class of porous organic polymers with remarkable features such as large surface area and permanent porosity, high thermal and chemical stability, and convenient functionalization that ...
Krishnaraj, Chidharth +3 more
core +1 more source
Does electrophilic activation of nitroalkanes in polyphosphoric acid involve formation of nitrile oxides? [PDF]
Aksenov AV +8 more
europepmc +1 more source
A competition between N---O and C---O through space interactions in the crystal structures of 3,3'-dinitro-2,2'-bipyridine N-oxides and N,N'-dioxides [PDF]
The crystal structures of a series of 3,3’-dinitro-2,2’-bipyridine N-oxides and N,N’-dioxides consistently show 1,5 interactions between nitro oxygen atoms and aromatic carbon atoms ((ON)O---C: 2.623(2)-2.839(2) Å) while there are also 1,6 interactions ...
O'Leary, J, Wallis, JD
core

