Results 81 to 90 of about 12,782 (291)

Solvent‐Free Thermal Defect Engineering in Molecular Frameworks With Volatile Linkers

open access: yesAdvanced Materials, EarlyView.
Thermal removal of neutral volatile linkers enables precise and solvent‐free generation of metal vacancies in MOFs. This strategy affords redox‐stable, coordinatively unsaturated FeII sites with tunable spin, ligand coordination, and catalytic behavior. The approach offers a general route to design defect‐functional materials through local coordination
Sonia Martínez‐Giménez   +9 more
wiley   +1 more source

Introduction of an isoxazoline unit to the β-position of porphyrin via regioselective 1,3-dipolar cycloaddition reaction

open access: yesBeilstein Journal of Organic Chemistry, 2019
Isoxazoline-linked porphyrins have been synthesized by a regioselective 1,3-dipolar cycloaddition reaction between vinylporphyrin 2 and nitrile oxides. The steric interaction directed the reaction trajectory, in which only the product with a link between
Xiujun Liu, Xiang Ma, Yaqing Feng
doaj   +1 more source

Synthesis of terephthalonitrile N,N-dioxide [PDF]

open access: yes
The preparation is described of terephthalonitrile N,N prime-dioxide by the chlorination of terephthalaldehyde dioxime to yield terephthalohydroximol chloride, to which absolute methynol was added to yield the ...
Vanburen, K. E.
core   +1 more source

Novel activities of 1-adamantylthiopyridines as antibacterials, antimalarials and anticancers [PDF]

open access: yes, 2009
To discover new bioactive lead compounds for medicinal purposes, herein, 2(1-adamantylthio)pyridine and derivatives (1-10) were prepared and tested for antibacterial (agar dilution method against 27 strains of microorganisms), antimalarial (against ...
Prachayasittikul, Supaluk   +3 more
core  

Electrically Assisted Thermal Stamping of Tunable Carbon‐Based Nanofilms for Direct Fabrication of Hydrophobic, Energy Harvesting, and Sensing Devices

open access: yesAdvanced Materials, EarlyView.
Schematic illustration of the electrically assisted thermal stamping (EATS) method for direct fabrication of carbon‐based nanofilms and their multifunctional applications. Localized Joule heating triggers simultaneous exfoliation, reduction, and fluoropolymer incorporation under ambient conditions, yielding tunable carbon‐based thin‐film coatings ...
Byungseok Seo   +9 more
wiley   +1 more source

Surface and lightning sources of nitrogen oxides over the United States: Magnitudes, chemical evolution, and outflow [PDF]

open access: yes, 2007
We use observations from two aircraft during the ICARTT campaign over the eastern United States and North Atlantic during summer 2004, interpreted with a global 3-D model of tropospheric chemistry (GEOS-Chem) to test current understanding of regional ...
Avery, M A   +22 more
core   +2 more sources

Scalable and Multifunctional PAN‐MXene Composite Fibers for Thermal Management, Photothermal Conversion, Energy Harvesting, and Sensing for Wearable Applications

open access: yesAdvanced Materials, EarlyView.
Electrospun PAN‐MXene nanofibers and yarns integrate enhanced thermal conductivity, photothermal conversion, and triboelectric energy harvesting within a flexible architecture. Interconnected MXene networks promote efficient phonon transport, while their surface chemistry strengthens tribo‐negative behavior, enabling a high power density of 432.7 mW m ...
Ahmadreza Moradi   +2 more
wiley   +1 more source

A divergent heritage for complex organics in Isheyevo lithic clasts [PDF]

open access: yes, 2017
Primitive meteorites are samples of asteroidal bodies that contain a high proportion of chemically complex organic matter (COM) including prebiotic molecules such as amino acids, which are thought to have been delivered to Earth via impacts during the ...
Alexander   +114 more
core   +3 more sources

Bioinspired, Mitochondria‐Targeted Single‐Atom Nanozyme Enhances Bone Regeneration by Reprogramming Stem Cell Energy Metabolism​

open access: yesAdvanced Materials, EarlyView.
A bioinspired nanozyme—triphenylphosphonium (TPP)‐dendritic mesoporous silica nanoparticle (DMSN)‐Fe/Cu—mimics mitochondrial complex IV and targets mitochondria to regulate cellular energy metabolism. This approach markedly boosts bone regeneration in vivo, as demonstrated by enhanced bone volume and mineral density in critical‐sized bone defects rat ...
Yuwen Wang   +16 more
wiley   +1 more source

Exploring the Potential of Zero‐Dimensional Carbon Nanomaterials in Photoluminescent, Electrochemiluminescent and Electrochemical Sensors

open access: yesAdvanced Materials Interfaces, EarlyView.
Zero‐dimensional carbon nanomaterials are presented as multifunctional platforms linking structure, property, and sensing performance. Surface engineering and heteroatom doping modulate electron‐transfer and luminescent behavior, enabling electrochemical, photoluminescent, and electrochemiluminescent detection. Fundamental design principles, analytical
Gustavo Martins   +8 more
wiley   +1 more source

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