Nitrobenzoates and Nitrothiobenzoates with Activity against M. tuberculosis [PDF]
Microorganisms, 2023 Esters of weak acids have shown improved antimycobacterial activity over the corresponding free acids and nitro benzoates in particular have previously shown to have a very intriguing activity. To expand the potential of nitro-derivatives of benzoic acid
João P. Pais +6 more
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Benzoic Acid Derivatives as Prodrugs for the Treatment of Tuberculosis [PDF]
Pharmaceuticals, 2022 One interesting approach to fight tuberculosis is the use of prodrugs that often have shown improved biological activities over drugs with poor absorption or difficulty to cross membranes. Previous studies demonstrate that weak acids such as benzoic acid,
João P. Pais +9 more
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Steric Effects on Reaction Rates Correlation Analysis of Solvolysis Data for Tertiary Carbon Substrates [PDF]
CHIMIA, 1987 Rate constants for solvolysis of tertiary chlorides and p-nitrobenzoates are compared and converted to Bentley’s unified reactivity scale. For the majority of structures consistent behavior is observed. Deviations are interpreted in terms of F-strain dr,
Paul Müller, Jacky Blanc, Jiri Mareda
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Stereoselective Solvolysis in the Synthesis of Dorzolamide Intermediates. [PDF]
ACS Omega, 2023 The key intermediate in the synthesis of dorzolamide,(4S,6S)-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-ol-7,7-dioxide,can beobtained in the diastereoisomerically pure form in two straightforwardsteps starting from diastereoisomeric mixtures of cis ...
Martinelli A +6 more
europepmc +3 more sources
3-Methylpyridinium 4-nitrobenzoate–4-nitrobenzoic acid (1/1) [PDF]
IUCrData, 2016 In the title compound, C6H8N+·C7H4NO4−·C7H5NO4, the cation is protonated at its pyridine N atom and makes a dihedral angle of 74.14 (12)° with the benzene ring of the anion. The benzene ring of the neutral molecule and the pyridine ring are inclined at an angle of 79.20 (12)°.
P. Sivakumar +3 more
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Degradation Pathways of 2- and 4-Nitrobenzoates in Cupriavidus sp. Strain ST-14 and Construction of a Recombinant Strain, ST-14::3NBA, Capable of Degrading 3-Nitrobenzoate. [PDF]
Appl Environ Microbiol, 2016 Basu S +3 more
europepmc +3 more sources
Magnetic, spectrochemical and thermal properties of the 2-chloro-5-nitrobenzoates of Co(II), Ni(II) and Cu(II) [PDF]
Journal of the Serbian Chemical Society, 2006 Some physico-chemical properties of the 2-chloro-5-nitrobenzoates of Co(II), Ni(II) and Cu(II) were studied. The complexes were obtained as hydrates with a metal ion to ligand ratio of 1:2. All the complexes were polycrystalline compounds.
AGNIESZKA WALKÓW-DZIEWULSKA +2 more
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Bacterial degradation of the nitrobenzoic acids [PDF]
Biochemical Journal, 1959 N J, CARTWRIGHT, R B, CAIN
core +4 more sources
The ammonolysis of esters in liquid ammonia [PDF]
, 2013 The rates of ammonolysis of alkyl benzoate and phenylacetate esters in liquid ammonia increase with the acidity of the leaving group alcohol and show relatively large Brønsted βlg values of −1.18 and −1.34, respectively, when plotted against the aqueous ...
Atherton, John +2 more
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Benzimidazolium 2-nitrobenzoate bis(2-nitrobenzoic acid)
Acta Crystallographica Section E Structure Reports Online, 2007 The title compound, C7H7N2+·C7H4NO4−·2C7H5NO4, consists of one benzimidazolium cation, one 2-nitrobenzoate anion and two 2-nitrobenzoic acid molecules. These ions and molecules build an infinite one-dimensional chain through hydrogen bonds.
Zi-Liang Wang, Lin-Heng Wei
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