The ammonolysis of esters in liquid ammonia [PDF]
, 2013 The rates of ammonolysis of alkyl benzoate and phenylacetate esters in liquid ammonia increase with the acidity of the leaving group alcohol and show relatively large Brønsted βlg values of −1.18 and −1.34, respectively, when plotted against the aqueous ...
Atherton, John +2 more
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Benzimidazolium 2-nitrobenzoate bis(2-nitrobenzoic acid)
Acta Crystallographica Section E Structure Reports Online, 2007 The title compound, C7H7N2+·C7H4NO4−·2C7H5NO4, consists of one benzimidazolium cation, one 2-nitrobenzoate anion and two 2-nitrobenzoic acid molecules. These ions and molecules build an infinite one-dimensional chain through hydrogen bonds.
Zi-Liang Wang, Lin-Heng Wei
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Synthesis and in vitro anticancer evaluation of some 4,6-diamino-1,3,5-triazine-2-carbohydrazides as Rad6 ubiquitin conjugating enzyme inhibitors [PDF]
, 2016 Series of 4-amino-6-(arylamino)-1,3,5-triazine-2-carbohydrazides (3a-e) and N'-phenyl-4,6-bis(arylamino)-1,3,5-triazine-2-carbohydrazides (6a-e), for ease of readership, we will abbreviate our compound names as “ new triazines”, have been synthesized ...
Kothayer, Hend +4 more
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Reactions of organoboranes with carbanions bearing three potential leaving groups: unusual processes, products and mechanisms [PDF]
, 2016 Known reagents that transfer three alkyl groups of a trialkylborane intramolecularly to a single carbon atom lack features to influence stereochemistry. We have investigated four reagents of type LiCCl2X, where X might be amenable to variation.
El Hiti, Gamal A. +5 more
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Bacterial degradation of m-nitrobenzoic acid [PDF]
Applied and Environmental Microbiology, 1995 Pseudomonas sp. strain JS51 grows on m-nitrobenzoate (m-NBA) with stoichiometric release of nitrite. m-NBA-grown cells oxidized m-NBA and protocatechuate but not 3-hydroxybenzoate, 4-hydroxy-3-nitrobenzoate, 4-nitrocatechol, and 1,2,4-benzenetriol. Protocatechuate accumulated transiently when succinate-grown cells were transferred to media containing m-
L J, Nadeau, J C, Spain
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Crystal structure and Hirshfeld surface analysis of 2-{[2,8-bis(trifluoromethyl)quinolin-4-yl](hydroxy)methyl}piperidin-1-ium 2-hydroxy-2-phenylacetate hemihydrate [PDF]
, 2016 The asymmetric unit of the title salt, C17H17F6N2O+·C8H7O3-·0.5H2O, comprises a pair of pseudo-enantiomeric (i.e. related by a non-crystallographic centre of symmetry) piperidin-1-ium cations, two carboxylate anions and a water molecule of ...
Jotani, Mukesh M. +2 more
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Pd-catalyzed decarboxylative Heck vinylation of 2-nitrobenzoates in the presence of CuF2
Beilstein Journal of Organic Chemistry, 2010 A new protocol for the decarboxylative Heck vinylation of benzoic acids is disclosed. In the presence of a catalyst system generated in situ from Pd(OAc)2 (2 mol %), CuF2 (2 equiv), and benzoquinone (0.5 equiv) in NMP, a wide range of olefins were ...
Lukas J. Gooßen +2 more
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2-{[2,8-Bis(trifluoromethyl)quinolin-4-yl](hydroxy)methyl}piperidin-1-ium trichloroacetate: Crystal structure and Hirshfeld surface analysis [PDF]
, 2018 The asymmetric unit of the centrosymmetric title salt, C17H17F6N2O+C2Cl3O2 , comprises a single ion-pair. The hydroxy-O and ammonium-N atoms lie to the same side of the cation, a disposition maintained by a charge-assisted ammonium-N—HO(hydroxy ...
Jotani, Mukesh M. +2 more
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Journal of Chemistry, 2018 Two new families of pyrazoline and thiadiazoline heterocycles have been developed. Their inhibitory activities against two different isoforms of nitric oxide synthase (inducible and neuronal NOS) are reported.
Fabio Arias +6 more
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Thermal Decomposition Mechanism of Silver Nitrobenzoates [PDF]
, 2014 The infra-red spectra of silver salts of 3-mono-, 3,5-di-and 2,4,6-tri-nitro-benzoic acids have been recorded at elevated temperatures in a fabricated high temperature cell. The thermogravimetry i.e. TG analysis has also been carried out.
Agrawal, A. P. +2 more
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