Results 11 to 20 of about 412 (137)
This review highlights recent advances in integrating biocatalysis and chemocatalysis in continuous flow to create streamlined, sustainable processes. It examines chemo‐enzymatic cascades combining at least one enzymatic and one chemical step, discusses challenges such as enzyme immobilization, leaching, and reactor clogging, and presents solutions ...
Petros Siasiaridis +2 more
wiley +2 more sources
Ethyl 4-anilino-3-nitrobenzoate [PDF]
In the title compound, C(15)H(14)N(2)O(4), the aromatic rings are oriented at a dihedral angle of 78.33 (3)°. An intra-molecular N-H⋯O hydrogen bond results in a non-planar six-membered ring with a flattened-boat conformation. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules.
Hao-Yuan Li +3 more
openaire +3 more sources
Starting from carboxylic acids and Selectfluor‐derivatives, functionalized diazabicyclooctanes can be obtained via a novel Polonovski‐type rearrangement proceeding under mild reaction conditions. Besides their use in organic synthesis the unique structure and reactivity of the rearrangement products enables applications in medicinal chemistry ...
Jakob Kuhn +5 more
wiley +1 more source
ABSTRACT BorF is a short‐chain flavin reductase from a desert soil bacterium that uses NADH to reduce FAD to FADH2, which is used by the tryptophan‐6‐halogenase BorH to chlorinate tryptophan in the biosynthetic pathway of borregomycin A. The X‐ray crystal structure of BorF bound to FAD was solved to 2.37 Å by molecular replacement.
Zheng Ma +3 more
wiley +1 more source
Salt forms of the monoazo dye Mordant Orange 1
The crystal structures of eight salt forms of the carboxylate‐functionalized monoazo dye Mordant Orange 1 are presented and discussed, primarily in terms of their coordination behaviour.The crystal structures of eight salt forms of the carboxylate‐functionalized monoazo dye Mordant Orange 1 are presented and discussed, primarily in terms of their ...
Alan R. Kennedy +4 more
wiley +1 more source
In the title molecule, C8H7NO4, the non-H atoms are essentially coplanar. In the crystal structure, short intermolecular O⋯C (3.21 A) and O⋯N (3.17 A) contacts indicate the presence of π–π interactions.
Long-Fei Jin, Feng-Ping Xiao
openaire +1 more source
Recent Advances in Benzannulation Approaches to Aromatic Frameworks
This review summarizes benzannulation strategies reported over the past 5 years, highlighting recent advances that enable efficient access to structurally diverse and highly substituted arenes through both transition‐metal‐catalyzed and metal‐free approaches.
Heeeun Kim, Yonghoon Kwon
wiley +1 more source
3,4-Diaminopyridinium 4-nitrobenzoate–4-nitrobenzoic acid (1/1)
In the title compound, C5H8N3+·C7H4NO4−·C7H5NO4, the non-H atoms of the 3,4-diaminopyridinium cation are coplanar, with a maximum deviation of 0.022 (1) Å. The carboxylate and nitro groups of the 4-nitrobenzoate anion are twisted out of the attached ring planes by dihedral angles of 15.89& ...
Hoong-Kun Fun, Kasthuri Balasubramani
openaire +2 more sources
Twin natural products. This manuscript describes a concise biomimetic synthesis of twin abeo‐steroids bufogargarizins A and B with an unusual [7.5.6.5] and [5.7.6.5] skeletons in 19 steps (LLS). The described synthetic approach features the application of a bioinspired regiodivergent intramolecular aldol addition reaction and a selective singlet oxygen‐
Zoey J. Surma +7 more
wiley +2 more sources
Elimination of acrolein from cider by addition of sulphur dioxide
Abstract BACKGROUND Acrolein is a toxic substance that sometimes appears in ciders, imparting an unpleasant taste and odour, which spoils the beverage entirely. Based on the reaction between acrolein and sulphur dioxide to form adducts, some oenologists of the Basque Country and Navarre (Northern Spain) use sulphur dioxide to remove acrolein.
Enaitz de las Heras +4 more
wiley +1 more source

