Results 181 to 190 of about 1,413,381 (322)

Spontaneous conversion of pyridine <i>N</i>-oxide ylide covalent organic framework (COF) into biradical COF as an efficient catalyst in catalytic dehydrogenation of nitrogen heterocycles. [PDF]

Chem Sci
Ai W, Zou J, Cao Z, Cui K, Gu J, Du L, Peng X, Jiao M, Shen T, Qu L.   +9 more
europepmc   +1 more source

Multifunctional Design of Solid Polymer Electrolytes: Paving the Way for High‐Performance All‐Solid‐State Batteries

Carbon Energy, EarlyView.
This review provides a comprehensive and systematic overview of the multifunctional design strategies for solid polymer electrolytes (SPEs), a pivotal component for enabling high‐performance all‐solid‐state batteries (ASSBs). It begins with a detailed classification of SPE systems and elaborates on their respective molecular design principles. The work
Bin Man, Yuzhen Zhao, Bo Fu, Yulong Zeng, Yinwen Chen, Qingrui Liu, Wenjing Luo, Xin Li, Xuewei Li, Zikang Zhang, Yun Zheng, Sijie Liu   +11 more
wiley   +1 more source

Bis‐Dichlorosilyl Functionalized C4‐Cumulene With Unique Bonding Scenario

Chemistry – A European Journal, EarlyView.
Herein, we report a silylene‐functionalized C4‐cumulene (2) and investigate its bonding scenario employing computational methods such as NBO analysis, AIM, and energy decomposition analysis‐natural orbital for chemical valence (EDA‐NOCV). The EDA‐NOCV analysis showed that compound 2 prefers to possess electron‐sharing covalent sigma and dative covalent
Saroj Kumar Kushvaha, Harsha S. Karnamkkott, Sangita Mondal, Paula A. M. Stark, Selvakumar Arumugam, Prakash Chandra Joshi, Sai Manoj N. V. T. Gorantla, Regine Herbst‐Irmer, Kartik Chandra Mondal, Dietmar Stalke, Herbert W. Roesky   +10 more
wiley   +1 more source

Five-Membered Nitrogen Heterocycles Angiotensin-Converting Enzyme (ACE) Inhibitors Induced Angioedema: An Underdiagnosed Condition. [PDF]

Pharmaceuticals (Basel)
Papapostolou N, Gregoriou S, Katoulis A, Makris M.   +3 more
europepmc   +1 more source

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

Chemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Ring expansion of alumoles with organic azides: selective formation of six-membered aluminum-nitrogen heterocycles. [PDF]

Chem Sci, 2020
Drescher R, Lin S, Hofmann A, Lenczyk C, Kachel S, Krummenacher I, Lin Z, Braunschweig H.   +7 more
europepmc   +1 more source

Pd(II)‐Catalyzed Strategies for the β‐Arylation of α‐Amino Acids: An Overview

Chemistry – A European Journal, EarlyView.
The graphical abstract summarizes the review “Pd(II)‐Catalyzed Strategies for the β‐Arylation of α‐Amino Acids: An Overview”, highlighting representative Pd(II)‐catalyzed methods for the β‐arylation of α‐amino acids. Key mechanistic features, substrate diversity, and synthetic relevance of these transformations are showcased. Abstract Metal‐catalyzed C─
Davide Illuminati, Claudio Trapella, Vinicio Zanirato, Virginia Cristofori, Anna Fantinati   +4 more
wiley   +1 more source

Isomerization of N-acyl-1,2,5,6-tetrahydropyridines to N-acyl-enamines by palladium on carbon [PDF]

, 1987
Kärtner, Annerose, Wanner, Klaus Th.
core   +1 more source

Controlling Aggregation‐Induced Emission by Sterics in Nitrogen–Boron–Nitrogen (NBN)‐Doped Tetraphenylethylene‐Like Molecular Propellers

Chemistry – A European Journal, EarlyView.
Nitrogen–boron–nitrogen (NBN)‐substituted molecular propellers are presented as structural framework for aggregation induced emission (AIE) applications. Steric hindrance is revealed to steer maximum‐AIE behavior, leading to refined control over assembly‐induced luminescence.
Nico Groß, Bojan Tanović, Frank Hampel, Henry Dube, Ani Ozcelik   +4 more
wiley   +1 more source

Versatile Palladium‐Catalyzed C‐H Arylation of Fluoroarenes with 2‐Chloropyridine Derivatives

Chemistry – A European Journal, EarlyView.
Direct C─H arylation of fluoroarenes with 2‐chloropyridines is enabled by a simple Pd/SPhos system in isopropyl acetate. The method uses inexpensive reactants and shows broad scope and high yields. DFT computations explain reactivity and selectivity.
Federico Belnome, Péter P. Fehér, András Stirling, Csongor G. Németh, Tamás Hergert, György M. Keserű, Péter Ábrányi‐Balogh   +6 more
wiley   +1 more source