Results 31 to 40 of about 86,737 (136)
EcoEnergy, EarlyView.This review summarizes a descriptor‐guided framework for linking theoretical calculations, in situ/operando characterization, synthesis regulation, and application screening in functional materials. Emphasis is placed on dynamic structure–property relationships that enable low‐cost material design with enhanced activity, stability, and environmental ...
Yanyu Jin +9 more
wiley +1 more source
Multigramme synthesis and asymmetric dihydroxylation of a 4-fluorobut-2E-enoate
Beilstein Journal of Organic Chemistry, 2013 Esters of crotonic acid were brominated on a multigramme scale using a free radical procedure. A phase transfer catalysed fluorination transformed these species to the 4-fluorobut-2E-enoates reproducibly and at scale (48–53%, ca. 300 mmol).
James A. B. Laurenson +4 more
doaj +1 more source
Small, EarlyView.An electroconductive MXene‐TFC membrane integrates osmotic dewatering with anodic oxidation to concentrate and mineralize PFOA at the membrane interface. The coupled AO‐PRO configuration accelerates degradation kinetics, achieves 99% rejection and up to 93% TOC removal, and lowers specific energy demand, offering a compact route for PFAS destruction ...
Afrouz Yousefi +9 more
wiley +1 more source
Elemental fluorine as a valid synthetic reagent [PDF]
, 1994 Chapter I Chapter I reviews the uses of elemental fluorine in selective organic synthesis and its use in the generation of selective electrophilic fluorinating agents.
Skinner, Christopher John
core
On the Ability of Bismuth to Couple Weakly Coordinating Anions
Angewandte Chemie, Volume 138, Issue 29, 13 July 2026.Motivated by the growing number of catalytic processes based on high‐valent Bi, we investigated in silico the reductive elimination step responsible for the coupling of weakly coordinating anions. Relativistic contributions appeared to be decisive to the electronic description of the intermediates involved in this process.
Lucas Mele +3 more
wiley +2 more sources
Crystal structure landscape of conformationally flexible organo-fluorine compounds
CrystEngComm, 2016 The crystal structure landscape of an unsubstituted benzanilide was generated and a number of hypothetical structures were accessed with experimentally obtained crystal structures of mono-, di-, tetra- and penta-fluorobenzanilides.
Pradip Kumar Mondal, Deepak Chopra
openaire +2 more sources
Electrochemical Properties of Nonflammable Organo-Fluorine Compounds for Lithium Ion Batteries [PDF]
, 2010 Electrochemical behavior of organo-fluorine compounds with high oxidation stability has been investigated. Oxidation currents of fluorine compound-containing EC/DEC solutions were much smaller than those of EC/DEC and EC/DEC/PC at the higher potentials ...
core
Organocatalytic asymmetric fluorination of α-chloroaldehydes involving kinetic resolution
Beilstein Journal of Organic Chemistry, 2014 In a previous study it was shown that the enantioselective α-fluorination of racemic α-chloroaldehydes with a chiral organocatalyst yielded the corresponding α-chloro-α-fluoroaldehydes with high enantioselectivity.
Kazutaka Shibatomi +5 more
doaj +1 more source
Beilstein Journal of Organic Chemistry, 2014 Background: 1,1-Difluoroalkenes cannot only be used as valuable precursors for organic synthesis, but also act as bioisosteres for enzyme inhibitors. Among various methods for their preparation, the carbonyl olefination with difluoromethylene phosphonium
Fei Wang +3 more
doaj +1 more source
Nickel‐Catalyzed Reductive Cross‐Coupling of Xanthate Esters With Aryl and Alkenyl Iodides
Chemistry – A European Journal, Volume 32, Issue 35, 19 September 2026.A nickel‐catalyzed reductive cross‐coupling of xanthate esters and aryl/alkenyl iodides is reported without the need for separate activators for the xanthate esters. The reaction utilizes a relatively low catalyst loading. Diarylmethanes with a good functional group variety can thus be synthesized indirectly from the corresponding benzylic alcohols ...
Felix Vöhringer +4 more
wiley +1 more source