Results 11 to 20 of about 86,737 (136)
Hot-Carrier Stressing of NPN Polysilicon Emitter Bipolar Transistors Incorporating Fluorine [PDF]
The effects of fluorine on the hot-carrier induced degradation in low-thermal-budget polysilicon emitter NPN bipolar transistors have been examined. Forward Gummel plots, base emitter (BE) diode characteristics, and stress currents were measured during ...
Sheng, S R +5 more
core +2 more sources
Direct electrophilic N-trifluoromethylthiolation of amines with trifluoromethanesulfenamide
The CF3SN moiety is a substituent with interesting properties. However, there is no easy synthetic access to molecules bearing this group. The trifluoromethanesulfenamide is a new reagent for the electrophilic trifluoromethylthiolation which reacts ...
Sébastien Alazet +2 more
doaj +1 more source
Effects of water and fluorine on the viscosity of albite melt at high pressure: a preliminary investigation [PDF]
The viscosities of fluorine- and water-bearing melts based on albite composition have been determined at 7.5, 15 and 22.5 kbar by the falling-sphere method. All melt viscosities decrease isothermally with increasing pressure.
Mysen, Bjørn O., Dingwell, Donald B.
core +1 more source
Flavin Catalysts in Organic Synthesis
Flavins and their congeners are potent catalysts for organic synthesis inspired by enzymatic transformations. In addition to catalysis in the flavin ground state via covalent intermediates, the excited singlet and triplet states unlock applications including photooxidation, photoreduction, and energy transfer via sensitization.
Jan Freudenberg, Golo Storch
wiley +2 more sources
Cu-Mediated trifluoromethylation of benzyl, allyl and propargyl methanesulfonates with TMSCF3
A Cu-mediated trifluoromethylation of benzyl, allyl and propargyl methanesulfonates with TMSCF3 was developed for the first time. This method offers a convenient and economical approach to various trifluoroethyl-containing compounds.
Xueliang Jiang, Feng-Ling Qing
doaj +1 more source
This paper investigates how fluorine implantation can be used to suppress boron diffusion in the base of a double polysilicon silicon bipolar transistor and hence deliver a record fT of 110 GHz.
Messina, A. +8 more
core +2 more sources
The influence of the C-N⁺ ----- F-C charge dipole interaction in fluoro organic chemistry [PDF]
Chapter 1 introduces the discovery of elemental fluorine by H. Moissan and some uses of inorganic fluoride. Organo fluoro compounds and their place in pharmaceuticals and agrochemicals are also introduced.
Gooseman, Natalie Elizabeth Jane
core +2 more sources
A one-pot synthesis of 3-trifluoromethyl-2-isoxazolines from trifluoromethyl aldoxime
Functionalized 3-trifluoromethyl-2-isoxazolines and 3-trifluoromethylisoxazoles were easily prepared from trifluoromethyl aldoxime 2 under mild conditions by using DIB as oxidant.
Raoni S. B. Gonçalves +4 more
doaj +1 more source
Modulating NHC catalysis with fluorine
Fluorination often confers a range of advantages in modulating the conformation and reactivity of small molecule organocatalysts. By strategically introducing fluorine substituents, as part of a β-fluoroamine motif, in a triazolium pre-catalyst, it was ...
Yannick P. Rey, Ryan Gilmour
doaj +1 more source
Direct Regioselective para‐Fluorination via I(I)/I(III) Catalysis
A direct, para‐selective fluorination by I(I)/I(III) catalysis is disclosed that does not require substrate pre‐functionalization. This strategy leverages the Leonard link inherent to phenylpropanoate and phenylpropanamides to promote a spirocyclization/para‐selective sequence. The C3‐side chain maps onto a range of common drug scaffolds and allows the
Christoph Roblick +5 more
wiley +2 more sources

