Results 41 to 50 of about 5,282 (198)
Chemistry – A European Journal, EarlyView.Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
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Organocatalyzed enantioselective desymmetrization of aziridines and epoxides
Beilstein Journal of Organic Chemistry, 2013 Enantioselective desymmetrization of meso-aziridines and meso-epoxides with various nucleophiles by organocatalysis has emerged as a cutting-edge approach in recent years.
Ping-An Wang
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Chiral Diol-Based Organocatalysts in Enantioselective Reactions
Molecules, 2018 Organocatalysis has emerged as a powerful synthetic tool in organic chemistry in the last few decades. Among various classes of organocatalysis, chiral diol-based scaffolds, such as BINOLs, VANOLs, and tartaric acid derivatives, have been widely used to ...
Truong N. Nguyen +3 more
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Frontiers in Chemistry, 2022 An unprecedented inactivation process of the indanol-derived NHC catalysts bearing N-C6F5 groups is reported. An unexpected multi-cyclic complex product is obtained from the 3-component reaction with the 1-methylcyclopropyl-carbaldehyde, the 2,2,2 ...
Yanling Chen +3 more
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Chemistry – A European Journal, EarlyView.The study of the Diels–Alder reaction of cinnamaldehyde and cyclopentadiene, catalyzed by chiral imidazolidine‐4‐thiones, led to the discovery of a highly regio‐ and stereoselective Michael‐addition and consecutive ring closure. Here, the imidazolidine‐4‐thione not only catalytically activates cinnamaldehyde but also participates as the nucleophile to ...
Marian S. R. Ebeling +5 more
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4-(Benzo[d]thiazol-2-yl)-1-(2-nitrophenyl)-1H-1,2,3-triazol-5-amine
Molbank, 2022 The protocol for the reaction of 2-nitrophenyl azide with 2-(benzo[d]thiazol-2-yl)acetonitrile has been selected. It was found that an optimal condition under which the target 4-(benzo[d]thiazol-2-yl)-1-(2-nitrophenyl)-1H-1,2,3-triazol-5-amine could be ...
Nazariy T. Pokhodylo, Mykola D. Obushak
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Acid‐Catalyzed Synthesis of Si‐Stereogenic Silanes
Chinese Journal of Chemistry, EarlyView.Si‐stereogenic silanes are important structural motifs in chemical synthesis, medicinal chemistry, and materials science. However, their catalytic enantioselective synthesis has largely relied on transition‐metal catalysts. Recently, Brønsted acids have been developed as promising alternatives.
Jung Tae Han, Benjamin List
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ORGANOCATÁLISE ENANTIOSSELETIVA: EVOLUÇÃO E ASPECTOS RECENTES
Química NovaIn the last two decades, enantioselective organocatalysis has established itself as one of the three pillars of asymmetric catalysis. The rapid growth in the area is due to the rationalization of organocatalysis based on the generic modes of catalyst ...
Fernanda G. Finelli +2 more
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(2R,4R)-2-Hydroxy-4-(2-methoxyphenyl)bicyclo[3.3.1]nonan-9-one
Acta Crystallographica Section E, 2009 The title compound, C16H20O3, contains a bicyclic ring system with two chiral centers. The crystal structure is stabilized by intermolecular O—H...O hydrogen bonds.
Shuping Luo +4 more
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Learning Strategies from Nature's Blueprint to Cyclic Carbonate Synthesis
ChemSusChem, Volume 18, Issue 6, March 15, 2025.The development of sustainable synthetic methods for cyclic carbonates draws inspiration from nature, focusing on eco‐friendly processes and renewable resources like CO2 and biomass. This review explore various CO2 activation mechanisms, green chemistry principles, and green catalysts.
Erika Saccullo +4 more
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