Results 41 to 50 of about 6,365 (202)

Metal-Free Synthesis of 2-Substituted Quinazolines via Green Oxidation of o-Aminobenzylamines: Practical Construction of N-Containing Heterocycles Based on a Salicylic Acid-Catalyzed Oxidation System

open access: yesFrontiers in Chemistry, 2022
Conventional quinazoline synthesis methods involve a highly multistep reaction, and often require excess amounts of substrate to control the product selectivity, leading to significant resource wastage.
Yuki Yamamoto   +7 more
doaj   +1 more source

Synthesis of D-Fructose-Based Bifunctional Primary Amine-Thiourea Organocatalysts and Their Applications in Asymmetric Reactions

open access: yesChemistry, 2023
The preparation of a new class of six bifunctional thiourea organocatalysts having a D-fructose scaffold and a primary amino group was demonstrated.
Samson Lalhmangaihzuala   +9 more
doaj   +1 more source

Electrogenerated NHC as an organocatalyst in the Staudinger reaction

open access: yes, 2010
Electrogenerated N-heterocyclic carbene can behave as an organocatalyst in the Staudinger reaction (from imine and acyl chloride) in a very polar solvent, such as an ionic ...
ORSINI, MONICA   +3 more
core   +2 more sources

Stereoselective Glycosylation of 2-Nitrogalactals Catalyzed by a Bifunctional Organocatalyst [PDF]

open access: yes, 2016
The use of a bifunctional cinchona/thiourea organocatalyst for the direct and α-stereoselective glycosylation of 2-nitrogalactals is demonstrated for the first time.
Coe, Diane M.   +14 more
core   +2 more sources

Bombyx Mori Silk Fibroin as a Sustainable Organocatalyst for Diastereoselective Michael Additions. [PDF]

open access: yesChemSusChem
Powdered silk fibroin (PSF) extracted from Bombyx mori cocoons is reported as a heterogeneous organocatalyst in the selective Michael 1,4 addition of nitromethane to α,β-unsaturated carbonyl compounds, affording Michael adducts in almost quantitative ...
Ricciardelli C   +8 more
europepmc   +2 more sources

Novel Imidazolidine-Tetrazole Organocatalyst for Asymmetric Conjugate Addition of Nitroalkanes

open access: yes, 2016
The Michael addition of nitroalkanes to α,β-unsaturated enones catalyzed by a novel chiral imidazolidine-2-yltetrazole organocatalyst has been investigated.
Nis Halland (1585213)   +2 more
core   +1 more source

Enantioselective Total Synthesis of Beraprost Using Organocatalyst

open access: yes, 2017
A convergent and enantioselective total synthesis of the most active isomer of beraprost was achieved in 17 pots. A unique tricyclic core in beraprost was synthesized efficiently by utilizing the asymmetric organocatalyst-mediated formal [3 + 2 ...
Shigenobu Umemiya (1548130)   +3 more
core   +1 more source

A Mild and Regioselective Ring-Opening of Aziridines with Acid Anhydride Using TBD or PS-TBD as a Catalyst

open access: yesMolecules, 2015
The ring-opening of N-tosylaziridines with various acid anhydrides catalyzed by 5 mol % of 1,5,7-triazabicyclo[4,4,0]dec-5-ene (TBD) afforded the corresponding β-amino esters in excellent yields under mild reaction conditions. Polymer-supported catalyst,
Satoru Matsukawa, Yasutaka Mouri
doaj   +1 more source

An efficient proline-based homogeneous organocatalyst with recyclability

open access: yes, 2018
A homogeneous organocatalyst for asymmetric reduction of imines can be reused for several cycles through a self-assembly method using MNPs.
Yaoxian Li   +8 more
core   +1 more source

Chemical signal activation of an organocatalyst enables control over soft material formation

open access: yes, 2017
Cells can react to their environment by changing the activity of enzymes in response to specific chemical signals. Artificial catalysts capable of being activated by chemical signals are rare, but of interest for creating autonomously responsive ...
Fanny Trausel   +6 more
core   +3 more sources

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