Hyperpolarization by parahydrogen‐induced polarization enhances the sensitivity of nuclear magnetic resonance spectroscopy of amino acids, peptides, mini‐proteins, and biopolymers using nonnatural amino acids with unsaturated side chains up to three orders of magnitude.
Gerd Buntkowsky
wiley +1 more source
Electric Field Enhancements and Hot Spots in Amorphous Carbon Materials
Amorphous carbon (a‐C) represents a broad and technologically relevant class of carbonaceous materials whose rich morphological diversity, characterized by nanoporosity and defective networks, endows them with unique electrical, chemical, and optical ...
Pablo Grobas Illobre +5 more
doaj +1 more source
Reactive force field simulations of silicon clusters
The fast and continuous growth of multidisciplinary approaches, consisting of the combination of various experimental techniques and computational methods tuned on purpose to depict and predict material properties and performance, is motivated by the ...
Giovanni Barcaro +3 more
doaj +1 more source
Bypassing the Resistance Mechanisms of the Tumor Ecosystem by Targeting the Endoplasmic Reticulum Stress Pathway Using Ruthenium- and Osmium-Based Organometallic Compounds: An Exciting Long-Term Collaboration with Dr. Michel Pfeffer. [PDF]
Gaiddon C +9 more
europepmc +1 more source
Covalent Attachment of a Platinum(II) Complex inside DNA Duplexes
Oxidative addition is used for the site‐specific incorporation of an organometallic PtII complex as an artificial nucleobase into a DNA duplex. The platination stabilizes the duplex and confers it with phosphorescence. An organometallic phosphorescent PtII complex is introduced into DNA duplexes via oxidative addition to a tailor‐made artificial ...
Tim Schäfer +6 more
wiley +1 more source
A NiII‐acetylide framework, H2TFPP‐Ni‐AF, demonstrates outstanding photocatalytic CO2 reduction performance: 13.16 mmol h−1 g−1 of CO with 97.9% selectivity. Synergistic interactions, including d‐p orbital hybridization within NiII‐bis(acetylide) moieties ( − C ≡ C−NiII(PBu3)2 − C ≡ C − ) and the efficient charge transport afforded by π‐conjugated ...
Lifen Chen +6 more
wiley +1 more source
Copper(I) hydride complexes often exhibit diverse aggregation behavior that can profoundly influence their structure and reactivity. In this study we use a combined experimental and computational approach to identify key structural an electronic factors that govern aggregation in PNNP dicopperhydride complexes.
Roel Laurentius Maria Bienenmann +5 more
wiley +1 more source
X‐ray magnetic circular dichroism
International Tables for Crystallography is the definitive resource and reference work for crystallography and structural science.
Each of the eight volumes in the series contains articles and tables of data relevant to crystallographic research and to applications of crystallographic methods in all sciences concerned with the ...
Gerrit van der Laan C. Chantler +2 more
wiley +1 more source
Potential of Organometallic Complex Compounds as Anticancer Drugs: A Review
Cancer is one of the deadliest diseases in the world. Currently, there are various types of anticancer drugs that are used to treat cancer, but they still have various side effects that can interfere with the quality of life of patients.
Zaliari Nafisa Ardhani +4 more
doaj +3 more sources
NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist [PDF]
Tables of ^1H and ^(13)C NMR chemical shifts have been compiled for common organic compounds often used as reagents or found as products or contaminants in deuterated organic solvents.
Bercaw, John E. +7 more
core +1 more source

