Results 81 to 90 of about 78,167 (269)

New Discoveries in the Realm of Metal–Metal Multiple Bonds:[η5-(C5Me5)Co2], the First Organometallic Multiple-Bond Complex without Bridging Ligands [PDF]

, 1991
Double bond, yes or no? That is the poignant question in the case of the complex [Cp*CoCoCp*] prepared by J.J. Schneider et al. The Co-Co distance and the number of electrons suggest a double bond, while the H-1-NMR spectrum and the poor reactivity ...
Wachter, Joachim
core   +1 more source

High‐Throughput Screening of REBCO Superconducting Thin Films Fabricated Via Combinatorial Inkjet Printing and TLAG Process

Advanced Materials Technologies, EarlyView.
A methodological framework is presented for combinatorial REBCO thin films fabricated by drop‐on‐demand inkjet printing with controlled Rare Earth composition gradients. Automated, synchrotron‐based, and local characterization techniques produce comprehensive property maps that correlate composition and TLAG process parameters with superconducting ...
Emma Ghiara, Zeyu Wu, Mahel Voulhoux, Ona Mola Bertran, Vittorio Bertini, Carla Torres, Aiswarya Kethamkuzhi, Guilherme Theophilo Telles, Victor Fuentes, Elzbieta Pach, Cornelia Pop, Eduardo Solano, Kapil Gupta, Takanobu Kiss, Xavier Obradors, Teresa Puig   +15 more
wiley   +1 more source

Desymmetrization of Malonic Monoesters and Malonic Acids via Enantioselective Catalytic C(sp3)─H Oxidation

Angewandte Chemie, EarlyView.
Manganese‐catalyzed enantioselective C(sp3)─H lactonization with hydrogen peroxide enables the direct desymmetrization of malonic monoesters and malonic acids, providing highly enantioenriched γ‐ and δ‐lactones (up to >99% ee) ABSTRACT Malonate derivatives are readily available starting materials widely employed in the synthesis of bioactive compounds.
Nikos Siakavaras, Arnau Call, Massimo Bietti, Miquel Costas   +3 more
wiley   +2 more sources

Valencies of the lanthanides [PDF]

, 2017
The valencies of the lanthanides vary more than was once thought. In addition to valencies associated with a half-full shell, there are valencies associated with a quarter- and three-quarter-full shell.
Johnson, David A., Nelson, Peter G.
core   +1 more source

New Directions in Focused Ion Beam Induced Deposition for the Nanoprinting of Functional 3D Heterostructures

Advanced Materials Technologies, EarlyView.
Here, it is shown that focused ion beam induced deposition (FIBID) using helium and neon ions enables advanced high‐resolution 3D nanoprinting achieving precise multimaterial architectures and engineered internal voids. Thus, FIBID with finely focused noble gas ion species is presented as a unique platform for designing functional nanomaterials for ...
Frances Isabel Allen
wiley   +1 more source

Alkoxysulfonium Salts Unlock Access to New Aryl Sulfonium Salts for Cross‐Coupling

Angewandte Chemie, EarlyView.
Hard‐to‐access (hetero)aryl sulfonium salts are prepared using stable methoxysulfonium salts in combination with the magnesiation of (hetero)aryl bromides. The approach allows access to aryl sulfonium salts bearing electron‐deficient (hetero)aryl rings, or electron‐rich aryl motifs in which the sulfonium motif resides at an alternative position on the ...
Rachel E. Brown, Navpreet Kaur, Anne‐Chloe M. A. Nassoy, Ciro Romano, David J. Procter   +4 more
wiley   +2 more sources

Reactivity of polar organometallic compounds in unconventional reaction media : challenges and opportunities [PDF]

, 2015
Developing new green solvents in designing chemical products and processes or successfully employing the already existing ones is one of the key subjects in green chemistry and is especially important in organometallic chemistry, which is an ...
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core   +1 more source

TriCON: A Carbon‐Based Triple‐Modal Nanoplatform for Pancreatic Cancer Therapy

Advanced Science, EarlyView.
We developed TriCON, a triple‐modality nanotherapeutic platform, to treat pancreatic ductal adenocarcinoma (PDAC) by synergizing gene editing, chemotherapy, and immunotherapy. TriCON utilizes CRISPR/Cas9 to target the poliovirus receptor (PVR), combined with nano‐encapsulated doxorubicin and checkpoint blockade. This approach achieved significant tumor
Xinyu Peng, Jiaxing Huang, Shengnan Lv, Jian Zhang, Liangliang Zhang, Huan Liu, Yan Liu, Zhen‐An Qiao, Feng Wei, Bao‐Lian Su   +9 more
wiley   +1 more source

Iron Catalyzed Aryl–Aryl Kumada Cross‐Coupling: A Mechanistic and Computational Investigation

Angewandte Chemie, EarlyView.
Despite intense interest, the mechanism of iron‐catalyzed aryl–aryl cross‐coupling remains poorly understood. Combining Mössbauer spectroscopy, kinetics analysis, and DFT computations these studies reveal a novel Fe(I)/Fe(II)/Fe(III) catalytic for aryl–aryl cross‐coupling mediated by an Fe(II) PCNHCP Pincer complex. These findings close a key knowledge
Jatin Panda, Magali Gimeno, Amrita Gogoi, Zeqing Chen, Subhash Garhwal, Laura Levy, Alexander Kaushansky, Natalia Fridman, Jos Briggs‐Pritchard, Renana Gershoni‐Poranne, Michael L. Neidig, Graham de Ruiter   +11 more
wiley   +2 more sources

Fast Quantification of Lithium Concentration in Non-Compliant Materials Using Laser-Induced Breakdown Spectroscopy

Applied Sciences
Although approximately half of global lithium consumption is used in the rechargeable battery industry, lithium is also in demand for other specialized applications, such as high-temperature lubricants, ceramics, glass, and pharmaceuticals.
Simona Raneri, Vincenzo Palleschi, Francesco Poggialini, Beatrice Campanella, Giulia Lorenzetti, Pilario Costagliola, Valentina Rimondi, Guia Morelli, Stefano Legnaioli   +8 more
doaj   +1 more source