Results 121 to 130 of about 3,191 (185)
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Synthesis of functionalised oxazoles and bis-oxazoles 1
Journal of the Chemical Society, Perkin Transactions 1, 1998A new method for the synthesis of oxazoles, and in particular chiral non-racemic oxazoles derived from amino acids, has been developed. Thus, rhodium(II) catalysed reaction of diazocarbonyl compounds 6 and 11 in the presence of amides 8 and 10 results in regioselective insertion of the carbenoid into the amide N–H bond with formation of the β-carbonyl ...
Mark C. Bagley +3 more
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Cycloaddition of Fluorinated Oxazoles.
ChemInform, 2005AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
N. V. Vasil'ev +5 more
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ChemInform Abstract: Synthesis of Functionalized Oxazoles and Bis‐Oxazoles.
ChemInform, 1998AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
M. C. BAGLEY +3 more
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New oxazole to oxazole recyclization
Chemistry of Heterocyclic Compounds, 2023Oleh V. Shablykin +3 more
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Imidazole, oxazole and thiazole alkaloids
Natural Product Reports, 2006AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
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Direct Arylation of Oxazoles at C2. A Concise Approach to Consecutively Linked Oxazoles
Organic Letters, 2008The synthesis of bis- and trisoxazoles via direct arylation is discussed. A variety of aryl groups can be installed at the 2-position of 5-aryl and 5-carboxy-substituted oxazoles under mild conditions using palladium catalysis on water. The direct arylation method can be extended to the synthesis of bis- and trisoxazoles if 2-triisopropylsilyl-4 ...
Flegeau, Emmanuel Ferrer +2 more
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Monosubstituted Oxazoles. 1. Synthesis of 5-Substituted Oxazoles by Directed Alkylation
The Journal of Organic Chemistry, 1998A general method is presented for synthesis of 2-(methylthio)-5-substituted oxazoles 2. Deprotonation of the readily available 2-(methylthio)oxazole (1) with n-BuLi occurs smoothly in the presence of TMEDA and regiospecifically at C5. The organometallic 1a added rapidly to aldehydes and other electrophiles to provide 5-substituted-2-(methylthio ...
Cynthia M., Shafer, Tadeusz F., Molinski
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Tetrahedron, 1994
Abstract Oxazole-4-sulfones, -phosphonates, and -nitriles are prepared by rhodium(II) catalysed addition of nitriles to the corresponding diazo compound. The effect of the ligand on rhodium was briefly investigated, with rhodium(II) trifluoroacetamide generally proving the most effective catalyst.
Kevin J. Doyle, Christopher J. Moody
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Abstract Oxazole-4-sulfones, -phosphonates, and -nitriles are prepared by rhodium(II) catalysed addition of nitriles to the corresponding diazo compound. The effect of the ligand on rhodium was briefly investigated, with rhodium(II) trifluoroacetamide generally proving the most effective catalyst.
Kevin J. Doyle, Christopher J. Moody
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