Results 51 to 60 of about 7,575 (247)

An Organometallic [2]Catenane With Pt‒(di‐NHC)‒Pt Units: A Topology‐Driven Strategy for Enhanced Phosphorescence in Discrete Aggregates

Angewandte Chemie International Edition, EarlyView.
The mechanically interlocked Borromean rings are stabilized by π···π stacking interactions while the [2]catenane is stabilized by solvophobic effects. While the π···π interactions in the Borromean rings lead to severe luminescence quenching, the solvophobically assembled [2]catenane effectively circumvents these interactions, simultaneously restricting
Ye Lu, Xi‐Dong Wu, Zi‐Yan Min, Lu An, Shi‐Ping Yang, F. Ekkehardt Hahn   +5 more
wiley   +1 more source

Antitumor Pentamethylcyclopentadienyl Rhodium Complexes of Maltol and Allomaltol: Synthesis, Solution Speciation and Bioactivity [PDF]

, 2014
The reaction of the dimer [RhIII(pentamethylcyclopentadienyl)(m-Cl)Cl]2 ([RhIII(Cp*)(m- Cl)Cl]2) with the hydroxypyrone ligands maltol and allomaltol affords complexes of the general formula [RhIII(Cp*)(L)Cl] under standard and microwave conditions ...
Abbott, Aguirre, Alessio, Alexander Roller, Bernhard K. Keppler, Booth, Bíró, Bíró, Christian G. Hartinger, Cleare, Dolomanov, Dunham, Eisen, Enyedy, Enyedy, Enyedy, Farrugia, Fernandez, Gans, Geldmacher, Geldmacher, Hartinger, Hartinger, Heffeter, Hübschle, Irving, Jakupec, Jung, Kaluderovic, Kandioller, Kandioller, Kandioller, Katsaros, Kiss, Leung, Liu, Maria S. Novak, Melanie Schmidlehner, Melchart, Mestroni, Michael A. Jakupec, Nazif, Nutton, Orsolya Dömötör, Peacock, Pressprich, Sabine Aicher, Schwarz, Schäfer, Sheldrick, Taylor, Tönnemann, Wolfgang Kandioller, Zékány, Éva A. Enyedy   +54 more
core   +2 more sources

Arene Incorporation and Ring Expansion in the Thermal Decomposition of a Divanadium(III) Complex With Four Bridging Methyl Groups

Chemistry – A European Journal, EarlyView.
Thermolysis of [{VCp*(µ‐CH3)2}2] (Cp* = η5‐C5Me5) in hexane leads to a tetranuclear cube‐type methylidene complex [{VCp*(µ3‐CH2)}4], while in benzenic solvents C6H5R produces the formal insertion of a CH fragment into the six‐membered aromatic ring of a solvent molecule to give trovacene derivatives with η7‐cycloheptatrienyl ligands [VCp*(η7‐C7H6R ...
Adrián Calvo‐Molina, Rodrigo González‐Prieto, Jesús Jover, Adrián Pérez‐Redondo, José Luis Priego, Carlos Yélamos   +5 more
wiley   +1 more source

Triple-Decker Pentalene Complex of Iron and Cobalt [PDF]

, 1996
In [1(1,2,3,3a,6a-ƞ)-1,4-dihydropentalenyl][µ-1](1,2,3,3a,-6a-ƞ):2(3a,4,5,6,6a-ƞ)-pentalene][2(ƞ5)-pentamethylcyclopentadienyl]cobaltiron, [CoFe(C8H7)Cp*(C8H6)] (Cp*=C10H15), the Cp*-Co and (C8H7)-Fe moieties reside on opposite sides of the fused ...
Alvarez-Larena, Angel, Briansó, José Luis, Chávez, Ivonne, Maniukiewicz, Waldemar, Manríquez, Juan M., Mas Llorens, Montserrat, Miravitlles Torras, Carles, Molins i Grau, Elies, Oelckers, Beatriz   +8 more
core   +3 more sources

Crystal structure of μ-oxido-1,1′κ2O:O-bis{tetra-μ-oxido-1:2κ2O:O;1:3κ2O:O;2:3κ4O:O-tris[1,2,3(η5)-pentamethylcyclopentadienyl]-trianglo-trititanium(IV)}

Acta Crystallographica Section E: Crystallographic Communications, 2015
The title polynuclear organometallic titanium(IV) oxide, [{Ti3(η5-C5Me5)3(μ-O)4}2(μ-O)], exhibits two Ti3O4 cores bridged by an O atom located on a twofold axis.
Adrián Pérez-Redondo, Avelino Martín
doaj   +1 more source

Sustainable Hydrogen Production by Glycerol and Monosaccharides Catalytic Acceptorless Dehydrogenation (AD) in Homogeneous Phase

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
Sustainable hydrogen production can be obtained from hydogen‐rich biomass‐derived organic molecules through Acceptorless Dehydrogenation (AD) reactions. Glycerol and sugars are available in large quantities from industry and can be successfully used as substrates in AD protocols, in the presence of tailored, selective, easily tunable and thermally ...
Sylwia Kostera, Luca Gonsalvi
wiley   +1 more source

Direct protonation of the W–H bonds of Bis(pentamethylcyclopentadienyl)tungsten dihydride [PDF]

, 1989
Protonation of (C_5Me_5)_2 WH_2 to give [(C_5Me_5)_2WH_3]+ is proposed to occur by attack at both W–H bonds rather than by direct attack at the d^2 metal ...
Bercaw, John E., Parkin, Gerard
core   +1 more source

(Cyanido-κC)(2,2-diphenylacetamido-κ2N,O)bis(η5-pentamethylcyclopentadienyl)zirconium(IV)

Acta Crystallographica Section E, 2014
In the title compound, [Zr(C10H15)2(C14H12NO)(CN)], the ZrIV atom is coordinated by two pentamethylcyclopentadienyl ligands, the amidate ligand via the N and O atoms, and an additional C[triple-bond]N ligand.
Lisanne Becker, Anke Spannenberg, Perdita Arndt, Uwe Rosenthal   +3 more
doaj   +1 more source

Catalytic Hydrogenation of Lignin‐Derived Aromatics With Rhodium Oxide in Water

European Journal of Organic Chemistry, EarlyView.
The easily available, easy‐to‐handle rhodium(III) oxide, Rh2O3, is shown to be a competent catalyst for arene hydrogenation, including chemoselective reduction of α,β‐unsaturated aryl ketones. Catalytic arene hydrogenation offers a direct pathway to saturated carbocycles. It can also be exploited to upgrade lignin‐derived aromatics.
Zhenyu Chen, Leiming Qi, Sydney Williams, Ilkan Calisir, Shamsal Haq, Rasmita Raval, Changzhi Li, Tao Zhang, Jianliang Xiao   +8 more
wiley   +1 more source

Metallocene to metallocene conversion. Synthesis of an oxazoline-substituted pentamethyliridocenium cation from a ferrocenyloxazoline [PDF]

, 2016
Reaction of (S)-2-ferrocenyl-4-(1-methylethyl)oxazoline with [(CpIrCl2)-Ir-star](2) in benzonitrile with KPF6 and NaOH gave (eta(5)-(S)-2-(4-(1-methylethyl))oxazolinylcyclopentadienyl)(eta(5)-pentamethylcyclopentadienyl)-iridium(III) hexafluorophosphate (
Arrayás, Arthurs, Atkinson, Bildstein, Boyd, Christopher J. Richards, Ciancaleoni, Forissier, Gusev, Holland, Holtmann, Kang, Langheim, Long, McVey, Mohapatra, Moseley, Nishibayashi, Oxgaard, Peter N. Horton, Rausch, Reid, Richards, Ross A. Arthurs, Ruble, Sammakia, Schaarschmidt, Simon J. Coles, Stadlbauer, Struchkov, Suleimanov, Tenn, III   +31 more
core   +1 more source