Results 31 to 40 of about 4,972 (216)

Electrochemical Hydrogenation of N‐Heterocycles and Related Substrates: A Mini‐Review

open access: yesElectrochemical Science Advances, Volume 5, Issue 4, August 2025.
ABSTRACT Catalytic hydrogenation refers to the (often) metal‐mediated addition of dihydrogen (H2) equivalents to unsaturated compounds to form new element‐hydrogen bonds. This conceptually simple reaction is ubiquitous in the production of a vast number of essential chemicals.
Esteban Garcia‐Torres   +1 more
wiley   +1 more source

Studies on the electrochemical reactions of 1-amino phosphonates

open access: yesElectrochemistry Communications
Electrochemical direct conversion of 1-aminoalkylphosphonates into novel heteroaromatic compounds has been studied and described. Cyclicvoltametry analysis showed that 1-aminoalkylphosphonate was oxidized in the anode, followed by removing the phosphoryl
Babak Kaboudin   +3 more
doaj   +1 more source

Leveraging Tumor Microenvironment to Boost Synergistic Photodynamic Therapy, Ferroptosis Anti‐Tumor Efficiency Based on a Functional Iridium(III) Complex

open access: yesAdvanced Science, Volume 12, Issue 14, April 10, 2025.
Ingenious introduction of an imine bond into an Ir(III)‐ferrocene complex effectively disrupts the photoinduced electron transfer process. Allowing full use of the TME to boost the efficacy of PDT, the molecule releases the Ir(III) complex and ferrocene with synergistic enhanced therapeutic effects of PDT and ferroptosis.
Yu Pei   +10 more
wiley   +1 more source

Label‐Free 3D Cell Imaging Using Hydrogels Functionalized with Switchable Iridium Complexes

open access: yesChemistry – A European Journal, Volume 31, Issue 19, April 1, 2025.
A label‐free imaging of cells in a 3D scaffold was achieved using switchable Ir‐complexes, covalently linked to a hydrogel. The presence of unstained cells induces the “switch‐on” of the luminescence from the Ir‐complexes, allowing clear visualization of living cells.
Federica Fiorini   +7 more
wiley   +1 more source

Synthesis of Quinolino[4,3‐j]phenanthridines and their Photophysical Characterization

open access: yesEuropean Journal of Organic Chemistry, Volume 28, Issue 13, April 1, 2025.
Nine novel quinolino[4,3‐j]phenanthridines were successfully synthesized. UV/Vis and fluorescence spectroscopy revealed remarkable optoelectronic properties. Large Stokes shifts were especially observed for the protonated substrates. The experimental results were compared and complemented with quantum chemical calculations, providing further insights ...
Felix R. Schumann, Joachim Podlech
wiley   +1 more source

Mapping the Chemodiversity, Antioxidant and Enzyme Inhibitory Potential and In Silico Studies of Heliotropium europaeum

open access: yesFood Science &Nutrition, Volume 13, Issue 4, April 2025.
This study established a foundation for utilizing these results and compounds as drug leads ‐ for exploring the industrial applications of Heliotropium europaeum in developing products aimed at non‐communicable diseases. ABSTRACT The annual plant Heliotropium europaeum grows in waste ground next to agricultural land and along roadsides from June to ...
Shabnam Mustafa   +9 more
wiley   +1 more source

Covalent Organic Frameworks for Photocatalytic Hydrogen Peroxide Evolution

open access: yesChemistry – A European Journal, Volume 31, Issue 15, March 12, 2025.
Τhis Review presents a comprehensive overview of the very recent developments on COF‐based photocatalysts for H2O2 evolution. First, neat COFs with variable architecture are critically explored, followed by the presentation of the most promising hybrid COF‐based heterojunctions.
Andreas Katsamitros   +4 more
wiley   +1 more source

Ortho Arylation of N‐Aryl Amides and the Construction of Diagonal Tetraarylbenzenediamines and N‐Doped Fulminenes via BBr3‐Derived Dibromoboracycles

open access: yesChemistry – A European Journal, Volume 31, Issue 8, February 6, 2025.
We report the discovery of a boron‐driven ortho‐arylation reaction of N‐aryl amides and ureas. This novel method enables directed borylation of a wide range of substrates, leading to the synthesis of unique compounds such as N‐doped fulminene and diagonal tetraarylbenzenediamines.
Ganesh H. Shinde   +2 more
wiley   +1 more source

Diversified Fluoroalkylation of Alkenes Using Quaternary Fluoroalkyl Alcohols as the Fluoroalkylating Reagents

open access: yesAdvanced Science, Volume 12, Issue 6, February 10, 2025.
A universal photoredox‐catalyzed fluoroalkylation approach by utilizing new (fluoroalkyl)diaryl methanols as versatile fluoroalkylating reagents is developed. This protocol facilitates the synthesis of mono‐, di‐, tri‐, and even polyfluoroalkylation of a broad scope of alkenes.
Heng Lu   +3 more
wiley   +1 more source

Expeditious Synthesis of 6-Fluoroalkyl-Phenanthridines via Palladium-Catalyzed Norbornene-Mediated Dehydrogenative Annulation.

open access: yesOrganic Letters, 2018
A novel palladium-catalyzed, norbornene-mediated intermolecular dehydrogenative annulation approach for the synthesis of 6-fluoroalkyl-phenanthridines from aryl iodides and fluorinated imidoyl chlorides, which are important structural motifs for ...
Zhuo Wang   +7 more
semanticscholar   +1 more source

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